D1369 D RADIATION CURABLE SECONDARY COATING FOR OPTICAL FIBER

• US 20080226913A1
• Filed: 12/13/2007
• Published: 09/18/2008
• Est. Priority Date: 12/14/2006
• Status: Abandoned Application

• Current Assignee: DSM IP Assets BV (DSM-Firmenich AG)
• Original Assignee: DSM IP Assets BV (DSM-Firmenich AG)
• Inventors: Murphy, Edward J., Zimmerman, John M., Schmid, Steven R., Tortorello, Anthony Joseph, Cattron, Wendell Wayne
• Application Number:
  US11/955,604
• Publication Number:
  US 20080226913A1
• Time in Patent Office: Days
• US Class Current: 428/392
• CPC Class Codes: C03C 25/1065 Multiple coatings
• CPC Class Codes: C08G 18/6674 with compounds of group C08G18/3203
• CPC Class Codes: C08G 18/672 Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
• CPC Class Codes: C09D 175/16 having terminal carbon-to-carbon unsaturated bonds
• CPC Class Codes: G02B 6/02395 Glass optical fibre with a protective coating, e.g. two layer polymer coating deposited directly on a silica cladding surface during fibre manufacture G02B6/02052, G02B6/02057, G02B6/024, G02B6/032, G02B6/105, G02B6/14 take precedence; coating on fibre gratings G02B6/02104; multilayer core or cladding G02B6/036; reinforcing splice joints G02B6/2558; optical cables, i.e. comprising protective structures external to the protective coating such as a jacket or plural coated optical fibres G02B6/44; coating of glass to obtain optical fibres C03C25/104
• CPC Class Codes: Y10T 428/2964 Artificial fiber or filament

Abstract

A new radiation curable Secondary Coating for optical fibers is described and claimed wherein said composition comprises a Secondary Coating Oligomer Blend, which is mixed with a first diluent monomer; a second diluent monomer; optionally, a third diluent monomer; an antioxidant; a first photoinitiator; a second photoinitiator; and optionally a slip additive or a blend of slip additives; wherein said Secondary Coating Oligomer Blend comprises:

• • α) an Omega Oligomer; and
  • β) an Upsilon Oligomer;
  • wherein said Omega Oligomer is synthesized by the reaction of
  • α1) a hydroxyl-containing (meth)acrylate;
  • α2) an isocyanate;
  • α3) a polyether polyol; and
  • α4) tripropylene glycol; in the presence of
  • α5) a polymerization inhibitor; and
  • α6) a catalyst;
  • to yield the Omega Oligomer;
  • wherein said catalyst is selected from the group consisting of dibutyl tin dilaurate; metal carboxylates, including, but not limited to: organobismuth catalysts such as bismuth neodecanoate; zinc neodecanoate; zirconium neodecanoate; zinc 2-ethylhexanoate; sulfonic acids, including but not limited to dodecylbenzene sulfonic acid, methane sulfonic acid; amino or organo-base catalysts, including, but not limited to: 1,2-dimethylimidazole and diazabicyclooctane; triphenyl phosphine; alkoxides of zirconium and titanium, including, but not limited to Zirconium butoxide and Titanium butoxide; and Ionic liquid phosphonium salts; and tetradecyl(trihexyl)phosphonium chloride; and
  • wherein said Upsilon Oligomer is an epoxy diacrylate.

Claims

1. A Radiation Curable Secondary Coating Composition, wherein said composition comprises

A) a Secondary Coating Oligomer Blend, which is mixed with

B) a first diluent monomer;

C) a second diluent monomer;

D) optionally, a third diluent monomer;

E) an antioxidant;

F) a first photoinitiator;

G) a second photoinitiator; and

H) optionally a slip additive or a blend of slip additives;

wherein said Secondary Coating Oligomer Blend comprises;

α

) an Omega Oligomer; and

β

) an Upsilon Oligomer;

wherein said Omega Oligomer is synthesized by the reaction of

α

1) a hydroxyl-containing (meth)acrylate;

α

2) an isocyanate;

3) a polyether polyol; and

α

4) tripropylene glycol;

in the presence of

α

5) a polymerization inhibitor; and

α

6) a catalyst;

to yield the Omega Oligomer;

wherein said catalyst is selected from the group consisting of copper naphthenate, cobalt naphthenate, zinc naphthenate, triethylamine, triethylenediamine, 2-methyltriethyleneamine, dibutyl tin dilaurate;

metal carboxylates, including, but not limited to;

organobismuth catalysts such as bismuth neodecanoate;

zinc neodecanoate;

zirconium neodecanoate;

zinc 2-ethylhexanoate;

sulfonic acids, including but not limited to dodecylbenzene sulfonic acid, methane sulfonic acid;

amino or organo-base catalysts, including, but not limited to;

1,2-dimethylimidazole and diazabicyclooctane;

triphenyl phosphine;

alkoxides of zirconium and titanium, including, but not limited to Zirconium butoxide and Titanium butoxide; and

Ionic liquid phosphonium salts; and

tetradecyl(trihexyl)phosphonium chloride;

wherein said Upsilon Oligomer is an epoxy diacrylate.

2. A process for coating an optical fiber, the process comprising:

a) operating a glass drawing tower to produce a glass optical fiber; and

b) coating said glass optical fiber with a commercially available radiation curable Primary Coating composition;

c) optionally contacting said radiation curable Primary Coating composition with radiation to cure the coating;

d) coating said glass optical fiber with the radiation curable Secondary Coating composition of claim 1; and

e) contacting said radiation curable Secondary Coating composition with radiation to cure the coating.

3. The process of claim 2, wherein said glass drawing tower is operated at a line speed of between about 750 meters/minute and about 2100 meters/minute.

4. A wire coated with a first and second layer, wherein the first layer is a cured radiation curable commercially available Primary Coating that is in contact with the outer surface of the wire and the second layer is a cured radiation curable Secondary Coating of claim 1 in contact with the outer surface of the Primary Coating,

wherein the cured Secondary Coating on the wire has the following properties after initial cure and after one month aging at 85°

C. and 85% relative humidity;

wherein the cured Secondary Coating on the wire has the following properties after initial cure and after one month aging at 85°

C. and 85% relative humidity;

A) a % RAU of from about 80% to about 98%;

B) an in-situ modulus of between about 0.60 CPa and about 1.90 CPa; and

C) a Tube Tg, of from about 50°

C. to about 80°

C.

5. An optical fiber coated with a first and second layer, wherein the first layer is a cured commercially available radiation curable Primary Coating that is in contact with the outer surface of the optical fiber and the second layer is a cured radiation curable Secondary Coating of claim 1 in contact with the outer surface of the Primary Coating,

wherein the cured Secondary Coating on the optical fiber has the following properties after initial cure and after one month aging at 85°

C. and 85% relative humidity;

A) a % RAU of from about 80% to about 98%;

B) an in-situ modulus of between about 0.60 GPa and about 1.90 GPa; and

C) a Tube Tg, of from about 50°

C. to about 80°

C.

6. The Radiation Curable Secondary Coating of claim 1 in which said third diluent is present.