Electrochemical cell with thermal current interrupting switch

• US 20080254343A1
• Filed: 04/16/2007
• Published: 10/16/2008
• Est. Priority Date: 04/16/2007
• Status: Abandoned Application

• Current Assignee: Eveready Battery Company Incorporated (Energizer Holdings, Inc.)
• Original Assignee: Eveready Battery Company Incorporated (Energizer Holdings, Inc.)
• Inventors: Wu, James X., Kaplin, David A.
• Application Number:
  US11/787,436
• Publication Number:
  US 20080254343A1
• Time in Patent Office: Days
• US Class Current: 429/53
• CPC Class Codes: H01M 10/052 Li-accumulators
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 10/30 Nickel accumulators H01M10/34 takes precedence
• CPC Class Codes: H01M 2200/00 Safety devices for primary or secondary batteries
• CPC Class Codes: H01M 2200/10 Temperature sensitive devices
• CPC Class Codes: H01M 2200/101 Bimetal
• CPC Class Codes: H01M 2200/20 Pressure-sensitive devices
• CPC Class Codes: H01M 50/317 Re-sealable arrangements
• CPC Class Codes: H01M 50/325 comprising deformable valve members, e.g. elastic or flexible valve members
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

An electrochemical cell having a current interrupting switch as an internal component of the cell that is thermally responsive and breaks an electrical path within the cell thereby preventing current flow when temperature within the cell is at or above an activating temperature. The switch is reversible and current flow and a closed circuit is re-established when temperature within the cell returns below the activating temperature.

Claims

1. An electrochemical cell, comprising:

a container having a closed end and an open end;

an electrode assembly disposed within the container and including a negative electrode, a positive electrode, an electrolyte, and a separator disposed between the negative electrode and positive electrode, wherein one of the electrodes is electrically connected to the container;

an internal seal plate located inside the container and providing a seal between the open end of the container and the electrode assembly, the seal plate being in contact with the container and being electrically non-conductive or having a polarity the same as the container;

an electrically conductive contact member extending through the seal plate; and

an end assembly covering the seal plate and having a terminal cap with a conductive terminal, wherein the contact member provides a portion of an electrical path between the electrode not electrically connected to the container and the conductive terminal, wherein an insulating gasket is present between the seal plate and the contact member when the seal plate is the same polarity as the container, wherein a temperature responsive current interrupting switch is present in the end assembly and operatively connected between the contact member and the conductive terminal so that below an activating temperature the current interrupting switch is at least part of an electrical path between the contact member and the conductive terminal, and at or above the activating temperature the current interrupting switch is out of electrical contact with one or more of the contact member and conductive terminal, and a circuit between the contact member and conductive terminal is opened, and wherein the current interrupting switch is capable of re-establishing a closed circuit between the contact member and conductive terminal when the temperature in the cell is below the activating temperature.

2. The electrochemical cell according to claim 1, wherein the current interrupting switch includes a switch member that comprises one or more of a shape memory alloy and a bimetal.

3. The electrochemical cell according to claim 2, wherein the switch member is a spring having a first end connected to either the contact member or the conductive terminal and a second end disposed in contact with the contact member or conductive terminal not connected to the first end of the spring and capable of moving out of electrical contact therewith at or above the activating temperature.

4. The electrochemical cell according to claim 3, wherein a non-conductive guide rod extends between the conductive terminal and the contact member, and wherein the non-conductive guide rod is disposed within the spring and is a guide for the spring.

5. The electrochemical cell according to claim 2, wherein the switch member has a first end portion fixedly connected to either the contact member or the conductive terminal and a second end disposed against the contact member or conductive terminal that is not fixedly connected to the first end below the activating temperature and capable of breaking contact with the contact member or conductive terminal at or above the activating temperature.

6. The electrochemical cell according to claim 5, wherein the switch member first end is connected to the contact member and the second end below the activating temperature is in contact with an underside of the conductive terminal or a side of the conductive terminal.

7. The electrochemical cell according to claim 2, wherein the switch member is a spring, wherein a first end of the spring is connected to the contact member and a second end of the spring is connected to a conductive portion of a lead, wherein the conductive portion of the lead is in contact with the conductive terminal below the activating temperature and is out of electrical contact at or above the activating temperature due to movement of the switch member, and wherein a non-conductive portion of the lead is connected to either (a) the contact member, (b) the insulating gasket between the contact member and the seal plate or (c) the seal plate, or combinations thereof.

8. The electrochemical cell according to claim 1, wherein the terminal cap has a portion that is non-conductive and having a periphery in contact with a portion of the container, and wherein the conductive terminal is a substantially cylindrical protrusion which extends outwardly from a central portion of the terminal cap.

9. The electrochemical cell according to claim 2, wherein the conductive terminal includes a conductive cover contact connected to an inner surface of the terminal cap, and wherein below the activating temperature the switch member is in contact with the cover contact and the contact member and at or above the activating temperature the switch member is out of electrical contact with one or more of the cover contact and contact member.

10. The electrochemical cell according to claim 2, wherein the switch member is a disk having a periphery in contact with the conductive terminal and one or more arms in contact with the contact member below the activating temperature and which are capable of breaking contact with the contact member at or above the activating temperature.

11. The electrochemical cell according to claim 10, wherein an insulating washer having an aperture is present between the seal plate and the disk, and wherein the one or more disk arms extend through the aperture and contact the contact member below the activating temperature.

12. The electrochemical cell according to claim 2, wherein the container is a cylindrical container, wherein the electrode assembly is a jelly-roll electrode assembly, and wherein the negative electrode comprises lithium.

13. The electrochemical cell according to claim 12, wherein the positive electrode is operatively electrically connected to the conductive terminal and the negative electrode is electrically connected to the container, wherein the positive electrode includes a current collector, wherein a contact spring is connected to the contact member, and wherein one or more of the positive electrode current collectors are in contact with the contact spring.

14. The electrochemical cell according to claim 12, wherein the activating temperature is from about 70°

C. to about 110°

C.

15. The electrochemical cell according to claim 14, wherein the activating temperature is from about 85°

C. to about 100°

C.

16. The electrochemical cell according to claim 2, wherein the cell includes a pressure relief vent.

17. The electrochemical cell according to claim 16, wherein the pressure relief vent is operatively connected to the seal plate and comprises a ball vent, a coined vent, or a rupture membrane.

18. An electrochemical cell, comprising:

a container having a closed end and an open end;

an electrode assembly disposed within the container and including a negative electrode, a positive electrode, an electrolyte, and a separator disposed between the negative electrode and positive electrode, wherein one of the electrodes is electrically connected to the container; and

an end assembly sealing the open end of the container and having a terminal cap with a conductive terminal, and a temperature responsive current interrupting switch operatively connected between the conductive terminal and the electrode of the electrode assembly not electrically connected to the container so that below an activating temperature the current interrupting switch is part of an electrical path between the terminal and the electrode not electrically connected to the container, and at or above the activating temperature the current interrupting switch is switched and the electrical path is interrupted, wherein the current interrupting switch is capable of re-establishing the electrical path when the temperature in the cell is below the activating temperature, wherein an insulating gasket is provided between the terminal cap and the open end of the container, and wherein the terminal cap extends over the open end of the container and has a perimeter that terminates outside of the container and seals the open end.

19. The electrochemical cell according to claim 18, wherein the current interrupting switch includes a switch member in electrical contact with a current collector of the electrode not electrically connected to the container and a segment including one or more of a shape memory alloy and bimetal that is in contact with a portion of the conductive terminal below the activating temperature and is capable of moving out of contact with the portion of the conductive terminal at or above the activating temperature and opening the circuit and interrupting the electrical path.

20. The electrochemical cell according to claim 19, wherein an insulating material is disposed between the container and the switch member, wherein the insulating material is one or more of a tube and a cone-shaped insulation member.

21. The electrochemical cell according to claim 20, wherein the switch member is cone-shaped and has two or more arms which each contact a portion of the conductive terminal and are non-articulatingly movable away from the conductive terminal at or above the activating temperature.

22. The electrochemical cell according to claim 21, wherein the insulating material is a cone-shaped insulation member which includes an annular seat on an inner surface of the member in which a portion of the switch member is positioned.

23. The electrochemical cell according to claim 18, wherein the container is a cylindrical container, wherein the electrode assembly is a jelly-roll electrode assembly, and wherein the negative electrode comprises lithium.

24. The electrochemical cell according to claim 23, wherein the positive electrode includes one or more current collectors, and wherein one or more of the current collectors are in contact with the switch member.

25. The electrochemical cell according to claim 18, wherein the activating temperature is from about 70°

C. to about 110°

C.

26. The electrochemical cell according to claim 25, wherein the activating temperature is from about 85°

C. to about 100°

C.

27. The electrochemical cell according to claim 22, wherein the container is a cylindrical container, wherein the electrode assembly is a jelly-roll electrode assembly, and wherein the negative electrode comprises lithium.

28. An electrochemical cell, comprising:

a cylindrical container having a closed end and an open end;

a jelly-roll electrode assembly disposed within the container and including a negative electrode, a positive electrode, an electrolyte, and a separator disposed between the negative electrode and positive electrode, wherein one of the electrodes is electrically connected to the container;

an end assembly having a conductive terminal and a non-articulating temperature-responsive switch, wherein the switch changes shape to selectively control current flow between the electrode not electrically connected to the container and the conductive terminal based upon a pre-determined temperature; and

an internal seal plate and optionally a gasket providing a seal between the open end of the container and the electrode assembly, and wherein the switch is operatively located between the conductive terminal and the seal member within the cell.

29. The electrochemical cell according to claim 28, wherein the switch includes a switch member comprises one of more of a shape memory alloy and a bimetal.

30. The electrochemical cell according to claim 29, wherein a contact member extends through the seal plate to form an electrical connection between the switch and the electrode not electrically connected to the container of the electrode assembly below the predetermined temperature.

31. The electrochemical cell according to claim 30, wherein an insulating gasket is positioned between the seal plate and the contact member.

32. The electrochemical cell according to claim 30, wherein the predetermined temperature is from about 70°

C. to about 110°

C.,

33. The electrochemical cell according to claim 32, wherein the predetermined temperature is from about 85°

C. to about 100°

C.

34. The electrochemical cell according to claim 30, wherein the switch has a first end portion fixedly connected to either the contact member or the conductive terminal and a second end disposed against the contact member or conductive terminal that is not fixedly connected to the first end below the predetermined temperature and capable of breaking contact with the contact member or conductive terminal at or above the predetermined temperature.

35. The electrochemical cell according to claim 30, wherein the switch member is a spring, wherein a first end of the spring is connected to the contact member and a second end of the spring is connected to a conductive portion of a lead, wherein the conductive portion of the lead is in contact with the conductive terminal below the predetermined temperature and is out of electrical contact at or above the predetermined temperature due to movement of the switch member, and wherein a non-conductive portion of the lead is connected to either (a) the contact member, (b) the insulating gasket between the contact member and the seal plate or (c) the seal plate, or combinations thereof.

36. The electrochemical cell according to claim 30, wherein the switch member is a disk having a periphery in contact with the conductive terminal and one or more arms in contact with the contact member below the predetermined temperature and which are capable of breaking contact with the contact member at or above the predetermined temperature.

37. The electrochemical cell according to claim 35, wherein an insulating washer having an aperture is present between the seal plate and the disk, and wherein one or more arms extend through the aperture and contact the contact member below the predetermined temperature.

38. The electrochemical cell according to claim 30, wherein the negative electrode comprises lithium, wherein the positive electrode is operatively connected to the conductive terminal and the negative electrode is electrically connected to the container, wherein the positive electrode includes a current collector, wherein a contact spring is connected to the contact member, and wherein one or more of the positive electrode current collectors are in contact with the contact spring.

39. The electrochemical cell according to claim 36, wherein the activating temperature is from about 70°

C. to about 110°

C.

40. The electrochemical cell according to claim 39, wherein the activating temperature is from about 85°

C. to about 100°

C.

41. The electrochemical cell according to claim 28, wherein the cell includes a pressure relief vent.

42. The electrochemical cell according to claim 41, wherein the pressure relief vent is operatively connected to the seal plate and comprises a ball vent, a coined vent, or a rupture membrane.

43. The electrochemical cell according to claim 28, wherein at or above the predetermined temperature the switch is switched and an electrical path is opened, whereby current cannot flow between the electrode not electrically connected to the container and the conductive terminal, wherein the switch is capable of re-establishing the electrical path when the temperature of the switch returns below the predetermined temperature.

44. The electrochemical cell according to claim 29, wherein the seal plate and gasket provide a seal between the open end of the container and the electrode assembly, wherein the seal plate has the same polarity as the switch member.

45. The electrochemical cell according to claim 44, wherein the switch member comprises is a disk in contact with the conductive terminal and one or more arms in contact with the seal plate below the predetermined temperature and which are capable of breaking contact with the seal plate at or above the predetermined temperature.

46. The electrochemical cell according to claim 45, wherein an insulating washer having an aperture is present between the seal plate and the disk, and wherein one or more arms of the disk extend through the aperture and contact the seal plate below the predetermined temperature.

47. The electrochemical cell according to claim 45, wherein a spring contact is connected to the seal plate and one or more current collectors of the electrode not electrically connected to the contact spring.

48. The electrochemical cell according to claim 46, wherein the cell includes a ball vent.