Reducing gas generator and solid reductant SCR system having the generator

• US 20080260597A1
• Filed: 03/19/2008
• Published: 10/23/2008
• Est. Priority Date: 04/23/2007
• Status: Active Grant

• Current Assignee: DENSO Corporation
• Original Assignee: DENSO Corporation
• Inventors: Suzuki, Kazunori, Kuroyanagi, Masatoshi, Nishijima, Yoshiaki
• Granted Patent: US 8,088,336 B2
• Time in Patent Office: Days
• US Class Current: 422/148
• CPC Class Codes: B01B 1/005 Evaporation for physical or chemical purposes; Evaporation apparatus therefor, e.g. evaporation of liquids for gas phase reactions
• CPC Class Codes: B01D 2251/2067 Urea
• CPC Class Codes: B01D 2257/404 Nitrogen oxides other than dinitrogen oxide
• CPC Class Codes: B01D 7/00 Sublimation B01D8/00 takes precedence; freeze-drying F26
• CPC Class Codes: C01C 1/026 Preparation of ammonia from inorganic compounds
• CPC Class Codes: C01C 1/086 from urea

Abstract

A reducing gas generator generates reducing gas including ammonia. The generator includes a solid reductant and a heat-generating portion. The solid reductant is formed in a columnar shape. A cross-sectional surface of the solid reductant has a constant shape and is perpendicular to a central axis of the solid reductant. The heat-generating portion includes a heat-generating surface opposed to a lower surface of the solid reductant in a vertical direction thereof and in contact with an entire region of the lower surface, and a heating element that heats the heat-generating surface when energized, so that the solid reductant is heated and decomposed to generate the reducing gas.

Claims

1. A reducing gas generator for generating reducing gas including ammonia, the generator comprising:

a solid reductant formed in a columnar shape, wherein a cross-sectional surface of the solid reductant has a constant shape, the cross-sectional surface being perpendicular to a central axis of the solid reductant; and

a heat-generating portion that includes;

a heat-generating surface opposed to a lower surface of the solid reductant in a vertical direction thereof and in contact with an entire region of the lower surface; and

a heating element that heats the heat-generating surface when energized, so that the solid reductant is heated and decomposed to generate the reducing gas.

2. The reducing gas generator according to claim 1, further comprising a solid reductant receiving portion, which receives the solid reductant such that an axial direction of the solid reductant is perpendicular to the heat-generating surface and that a contact position between the solid reductant and the heat-generating surface is maintained.

3. The reducing gas generator according to claim 2, wherein the solid reductant receiving portion is formed in a based cylindrical shape, the reducing gas generator further comprising:

an airtight pressure vessel-shaped container that receives the solid reductant receiving portion therein, wherein the reducing gas, which is generated when the solid reductant is heated by the heat-generating portion, is stored in the container; and

a reducing gas lead-out hole conducting the reducing gas out of the container.

4. The reducing gas generator according to claim 3, further comprising:

a ventilation passage formed between the solid reductant receiving portion and an inner wall of the container for conducting the reducing gas into the reducing gas lead-out hole; and

a ventilation means for making the reducing gas, which is generated at a contact surface between the solid reductant and the heat-generating surface, flow into the ventilation passage.

5. The reducing gas generator according to claim 4, wherein the ventilation means is a wall surface of the solid reductant receiving portion formed from a porous body, through which the reducing gas permeates.

6. The reducing gas generator according to claim 4, wherein:

the heat-generating surface includes an inside surface of a bottom wall of the solid reductant receiving portion; and

the ventilation means includes;

at least one bottom wall groove portion formed on the bottom wall inside surface in a radially outward direction from a center of the bottom wall inside surface;

at least one side wall groove portion formed on an inner circumferential surface of a side wall of the solid reductant receiving portion in a direction from a lower end toward upper end of the side wall in the vertical direction so as to communicate with the at least one bottom wall groove portion, respectively; and

a side surface opening which is formed at an upper portion of the solid reductant receiving portion in the vertical direction and through which an inside and outside of the solid reductant receiving portion communicate, wherein the side surface opening communicates with one of the at least one side wall groove portion.

7. The reducing gas generator according to claim 1, further comprising a solid reductant pressing means for pressing the lower surface of the solid reductant on the heat-generating surface according to a volume decrease of the solid reductant due to the decomposition of the solid reductant.

8. The reducing gas generator according to claim 7, wherein the solid reductant pressing means is one of a spring gear and a hydraulic system disposed inside the container.

9. The reducing gas generator according to claim 7, wherein:

the inner wall of the container, an inner wall of the solid reductant receiving portion, and an upper surface of the solid reductant define a solid reductant back pressure space; and

the solid reductant pressing means presses the solid reductant using a pressure of gas in the solid reductant back pressure space including the reducing gas conducted into the solid reductant back pressure space by the ventilation means.

10. The reducing gas generator according to claim 1, further comprising:

a pressure meter for detecting a pressure of the reducing gas in the container;

a gas concentration meter for detecting a concentration of a specific gas component of the reducing gas in the container; and

a control means for calculating how much the solid reductant is heated based on the detected pressure and concentration of the specific gas component and controlling the energization of the heating element of the heat-generating portion.

11. The reducing gas generator according to claim 1, further comprising a solid reductant consumption monitor configured to monitor a consumed amount of the solid reductant.

12. The reducing gas generator according to claim 11, wherein:

the solid reductant consumption monitor includes a pair of electrodes consisting of an upper electrode in contact with the upper surface of the solid reductant and a lower electrode, which has the heat-generating surface and is in contact with a lower surface of the solid reductant receiving portion; and

the solid reductant consumption monitor outputs an alarm or stops a power supply to the heat-generating portion when one of resistance and capacitance between the pair of electrodes varying according to the consumed amount of the solid reductant is equal to or smaller than a predetermined threshold value.

13. The reducing gas generator according to claim 12, wherein the bottom wall of the solid reductant receiving portion is the lower electrode.

14. The reducing gas generator according to claim 1, wherein the solid reductant includes at least one of diammonium acid carbonate carbamate, ethyl carbamate, ammonium carbonate, ammonium hydrogencarbonate, ammonium phosphate, ammonium hydrogenphosphate, ammonium dihydrogenphosphate, ammonium acetate, ammonium stearate, and ammonium formate.

15. A solid reductant SCR system for reducing nitrogen oxide in exhaust gas flowing through an exhaust gas flow passage of an internal combustion engine using the reducing gas so as to remove the nitrogen oxide from the exhaust gas, the system comprising:

an SCR catalyst disposed in the exhaust gas flow passage;

the reducing gas generator recited in claim 1, wherein the reducing gas generated by the reducing gas generator is introduced to an upstream side of the SCR catalyst in the exhaust gas flow passage in a flow direction of the exhaust gas; and

a reducing gas introduced flow control means for controlling a flow of the reducing gas introduced to the upstream side of the SCR catalyst.

16. The solid reductant SCR system according to claim 15, wherein the reducing gas introduced flow control means includes:

a control valve configured to open and close the reducing gas lead-out hole; and

a press pump disposed between the reducing gas lead-out hole and the control valve for amplifying a pressure of the reducing gas, which is conducted out of the reducing gas generator by the reducing gas lead-out hole.

17. The solid reductant SCR system according to claim 15, further comprising:

a first gas concentration sensor disposed on the upstream side of the SCR catalyst for detecting a concentration of a specific gas component of the exhaust gas; and

a second gas concentration sensor disposed on a downstream side of the SCR catalyst in the exhaust gas flow passage in the flow direction of the exhaust gas and configured to detect a concentration of the specific gas component, wherein the control means corrects an amount of the reducing gas conducted out of the reducing gas generator via the reducing gas introduced flow control means based on the concentrations detected by the first and second gas concentration sensors.