Acrylic Polymer Beads and Sol Composition Containing the Same

• US 20080268251A1
• Filed: 11/14/2006
• Published: 10/30/2008
• Est. Priority Date: 11/14/2005
• Status: Abandoned Application

• Current Assignee: Kolon Industries Incorporated
• Original Assignee: Kolon Industries Incorporated
• Inventors: Yoon, Young-Seo, Kim, Jong-Han, Kang, Chung-Seock
• Application Number:
  US12/093,421
• Publication Number:
  US 20080268251A1
• Time in Patent Office: Days
• US Class Current: 428/407
• CPC Class Codes: C08F 220/06 Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
• CPC Class Codes: C08F 265/04 on to polymers of esters
• CPC Class Codes: C08F 265/06 Polymerisation of acrylate or methacrylate esters on to polymers thereof
• CPC Class Codes: C08F 285/00 Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 51/003 grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds C08L51/04, C08L51/06 take precedence
• CPC Class Codes: C09D 151/003 grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds C09D151/04, C09D151/06 take precedence
• CPC Class Codes: C09J 151/003 grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds C09J151/04, C09J151/06 take precedence
• CPC Class Codes: Y10T 428/2998 including synthetic resin or polymer

Abstract

Acrylic polymer beads with excellent coating properties and storage stabilities, its preparation method and acrylic sol composition containing thereof are introduced.

Claims

1-15. -15. (canceled)

16. Acrylic polymer beads having a core/shell/outermost-layer structure, wherein the beads comprise:

a core formed by emulsion polymerization of the core-constituting monomer, the core-constituting monomer comprising 50 to 90 wt. % of the monomer having Tg of its homopolymer is not higher than 50°

C.;

a shell formed by emulsion polymerization of the shell-constituting monomer, the shell-constituting monomer comprising 60 to 90 wt. % of the monomer having Tg of its homopolymer is not lower than 50°

C.; and

an outermost layer formed by emulsion polymerization of acrylic acid and at least one monomer selected from the group consisting of the core-constituting monomer and the shell-constituting monomer.

17. The acrylic polymer beads as claimed in claim 16, wherein the weight ratio of monomer constituting the core/shell/outermost-layer is 50-80/10-40/10-20(wt. %/wt. %/wt. %).

18. The acrylic polymer beads as claimed in claim 16, wherein the average particle diameter of the acrylic polymer beads is 10-100 μ

um.

19. The acrylic polymer beads as claimed in claim 16, wherein the content of the acrylic acid is 5-20 wt. % based on the total weight of the monomer constituting the outermost layer.

20. The acrylic polymer beads as claimed in claim 16, wherein the weight average molecular weight (Mw) of the acrylic polymer beads is in a range of 100,000-2,000,000 g/mol.

21. The acrylic polymer beads as claimed in claim 16, wherein the monomer constituting the core is at least one selected from acrylic acid esters having C1-C8 alkyl groups, methacrylic acid esters having C1-C4 alkyl groups, and methacrylic acid hydoxyalkylesters having C1-C4 alkyl groups.

22. The acrylic polymer beads as claimed in claim 16, wherein the monomer constituting the shell is at least one selected from methacrylic acid esters having C1-C4 alkyl groups, and methacrylic acid hydoxyalkylesters having C1-C4 alkyl groups.

27. An acrylic sol composition for coating an automobile underbody comprising acrylic polymer beads as claimed in claim 16, filler, plasticizer, adhesion promoting agent, dye and pigment.

28. The acrylic sol composition for coating an automobile underbody as claimed in claim 27, wherein the composition comprises 100-200 parts by weight of plasticizer, 110-180 parts by weight of filler, 10-30 parts by weight of adhesion promoting agent and 0-10 parts by weight of dye, based on 100 parts by weight of acrylic polymer beads.

29. The acrylic sol composition for coating an automobile underbody as claimed in claim 27, wherein an initial viscosity is 30,000 to 80,000 cps as measured with a Brookfield Viscometer No. 7 Spindle at 20°

C. and 20 rpm.

30. The acrylic sol composition for coating an automobile underbody as claimed in claim 27, wherein the rate of viscosity is less than 50% with respect to the initial viscosity as measured with a Brookfield Viscometer No. 7 Spindle at 20°

C. and 20 rpm after 14 days of storage in a thermohydrostat at 40°

C., and 95% RH.

23. A method for preparing acrylic polymer beads through spray-drying or salting out of the emulsion obtained by emulsion polymerization, wherein the method comprises the following steps:

(a) adding ion-exchange water, 5 to 60 wt. % of the core-constituting monomer comprising 50 to 90 wt. % of the monomer having Tg of its homopolymer is not higher than 50°

C., and an emulsifier to a reactor, heating the reactor, adding an aqueous initiator, and performing polymerization for 1 to 4 hours to form seed;

(b) adding dropwise the rest of the core-constituting monomer and further performing polymerization for 1 to 6 hours to form core; and

(c) adding dropwise the shell-constituting monomer comprising 60 to 90 wt. % of the monomer having Tg of its homopolymer is not lower than 50°

C., and further performing the polymerization for 2 to 4 hours to form the shell,

wherein the method further comprises step (d) adding dropwise the mixture of an emulsifier, acrylic acid, and at least one monomer selected from the group consisting of the core-constituting monomer and the shell-constituting monomer, to the resultant of step (c), then adding initiator, and performing further polymerization for 2 to 4 hours to form an outermost-layer.

24. The method for preparing acrylic polymer beads as claimed in claim 23, wherein the average particle diameter of the emulsion containing acrylic polymer beads after step (d) is 0.4-0.7 μ

m.

25. The method for preparing acrylic polymer beads as claimed in claim 23, wherein the content of acrylic acid is 5-20 wt. % based on the total weight of the monomer constituting the outermost layer.

26. Acrylic polymer beads having a core/shell/outermost-layer structure obtained from the method as claimed in claim 23.

31. The acrylic sol composition for coating an automobile underbody comprising acrylic polymer beads as claimed in claim 26, filler, plasticizer, adhesion promoting agent, dye and pigment.