Fuel Cells

• US 20080274385A1
• Filed: 03/10/2006
• Published: 11/06/2008
• Est. Priority Date: 03/12/2005
• Status: Abandoned Application

• Current Assignee: ACAL Energy Ltd
• Original Assignee: ACAL Energy Ltd
• Inventors: Creeth, Andrew Martin
• Application Number:
  US11/911,945
• Publication Number:
  US 20080274385A1
• Time in Patent Office: Days
• US Class Current: 429/19
• CPC Class Codes: H01M 4/8652 as mixture
• CPC Class Codes: H01M 4/96 Carbon-based electrodes
• CPC Class Codes: H01M 8/1009 with one of the reactants being liquid, solid or liquid-charged H01M8/12 takes precedence
• CPC Class Codes: H01M 8/1053 consisting of layers of polymers with at least one layer being ionically conductive
• CPC Class Codes: H01M 8/188 by recharging of redox couples containing fluids; Redox flow type batteries
• CPC Class Codes: H01M 8/20 Indirect fuel cells, e.g. fuel cells with redox couple being irreversible H01M8/18 takes precedence
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

This invention concerns a redox fuel cell comprising an anode and a cathode separated by an ion selective polymer electrolyte-membrane, preferably a bi-membrane, the cathode comprising a cathodic material and a proton-conducting polymeric material; means for supplying a fuel to the anode region of the cell; means for supplying an oxidant to the cathode region of the cell; means for providing an electrical circuit between the anode and the cathode; a non-volatile redox couple in solution in flowing fluid communication with the cathode, the redox couple being at least partially reduced at the cathode in operation of the cell, and at least partially re-generated by reaction with the oxidant after such reduction at the cathode.

Claims

1-12. -12. (canceled)

13. A redox fuel cell comprising:

an anode and a cathode separated by an ion selective polymer electrolyte membrane, the cathode comprising a cathodic material and a proton-conducting polymeric material;

a fuel inlet to the anode region of the cell;

an oxidant inlet to the cathode region of the cell; and

a non-volatile redox couple in solution, in flowing fluid communication with the cathode, the redox couple being at least partially reduced at the cathode in operation of the cell, and at least partially re-generated by reaction with an oxidant after such reduction at the cathode.

14. A fuel cell according to claim 13, wherein the membrane comprises an anion selective membrane.

15. A fuel cell according to claim 14, wherein the membrane is a bi-membrane.

16. A fuel cell according to claim 15, wherein the bi-membrane comprises at least two discreet membranes.

17. A fuel cell according to claim 15, wherein the bi-membrane comprises an adjacent pairing of oppositely charge selective membranes.

18. A fuel cell according to claim 17, wherein the bi-membrane comprises at least two discreet membranes.

19. A fuel cell according to claim 18, wherein the discreet membranes are placed side-by-side with an optional gap therebetween.

20. A fuel cell according to claim 15, wherein the bi-membrane comprises a first cation selective membrane and a second anion selective membrane.

21. A fuel cell according to claim 20, wherein the cation selective membrane is positioned on the cathode side of the bi-membrane and the anion selective membrane is positioned on the anode side of the bi-membrane.

22. A fuel cell according to claim 21, wherein, the anion selective membrane is selective for hydroxyl ions.

23. A fuel cell according to claim 21, wherein the proton conducting material comprises the cation selective membrane.

24. A fuel cell according to claim 22, wherein the anion selective membrane is selective for hydroxyl ions.

25. A fuel cell according to claim 20, wherein the cation selective membrane is positioned on the anode side of the bi-membrane and the anion selective membrane is positioned on the cathode side of the bi-membrane.

26. A fuel cell according to claim 25, wherein means are provided for flushing cationic materials from an interstitial space of the bi-membrane.