Functionalized nanoparticles and their use in particle/bulk material systems

• US 20080287586A1
• Filed: 03/22/2007
• Published: 11/20/2008
• Est. Priority Date: 03/22/2007
• Status: Abandoned Application

• Current Assignee: Milliken & Company
• Original Assignee: Milliken & Company
• Inventors: Neal, F. Brent, Wilson, Philip, Zhou, Hao, Jones, Jamie N.
• Application Number:
  US11/726,578
• Publication Number:
  US 20080287586A1
• Time in Patent Office: Days
• US Class Current: 524/430
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: C01P 2002/82 by IR- or Raman-data
• CPC Class Codes: C01P 2002/88 by thermal analysis data, e.g. TGA, DTA, DSC
• CPC Class Codes: C01P 2004/50 Agglomerated particles
• CPC Class Codes: C01P 2004/52 highly monodisperse size distribution
• CPC Class Codes: C01P 2004/53 bimodal size distribution
• CPC Class Codes: C01P 2004/62 Submicrometer sized, i.e. from 0.1-1 micrometer
• CPC Class Codes: C01P 2004/64 Nanometer sized, i.e. from 1-100 nanometer
• CPC Class Codes: C01P 2006/32 Thermal properties
• CPC Class Codes: C08K 3/22 of metals
• CPC Class Codes: C08K 9/04 Ingredients treated with organic substances treated with macromolecular compounds C08K9/08
• CPC Class Codes: C08K 9/06 with silicon-containing compounds
• CPC Class Codes: C09C 1/40 Compounds of aluminium C09C1/0009, C09C1/0015, C09C1/0078, C09C1/32 take precedence
• CPC Class Codes: Y02P 20/582 Recycling of unreacted starting or intermediate materials

Abstract

A process for creating readily or highly dispersible nanoparticles on which chemically reactive functional groups or ligands have been placed. An ultra-high shear fluidic processor is used to change the size distribution of nanoparticle agglomerations and facilitate the formation of stable dispersions of such nanoparticles, as well as the placement of various chemically reactive functional groups or ligands on exposed surface areas of such nanoparticles. Such functionalized nanoparticle agglomerations have a broader size distribution (with a substantial increase in the proportion of smaller agglomerations), can exhibit enhanced dispersion characteristics and, when dispersed in various bulk materials, can impart to such bulk materials the desirable physical or chemical properties associated with the selected chemically active functional groups that have been attached to the surface areas of such agglomerations.

Claims

1. A method for generating functionalized nanoparticles comprising the steps of:

(a) providing a source of at least partially agglomerated nanoparticles, wherein the nanoparticles have pre-existing exposed surface areas,

(b) providing a source of a first type of chemically functional group,

(c) subjecting the nanoparticles to ultra-high shear fluidic processing forming newly exposed surface areas of the nanoparticles, and chemically bonding the first type of chemically functional group to the newly exposed surface areas of the nanoparticles while the nanoparticles are being subjected to the ultra-high shear fluidic processing.

3. The method of claim 1, further comprising chemically bonding a chemically functional group selected from the group consisting of the first type of chemically functional group and a second type of chemically functional group to the newly exposed surface areas of the nanoparticles following subjecting said nanoparticles to ultra-high shear fluidic processing.

4. The method of claim 1, further comprising chemically bonding the first type of chemically functional group to the pre-existing exposed surface areas of the nanoparticles prior to subjecting said nanoparticles to ultra-high shear fluidic processing.

5. The method of claim 1, further comprising chemically bonding a second type of chemically functional group to the pre-existing exposed surface areas of the nanoparticles prior to subjecting said nanoparticles to ultra-high shear fluidic processing.

6. The method of claim 1, wherein the functionalized nanoparticles are combined with at least one polymer.

7. The method of claim 6, wherein the functionalized nanoparticles are localized on the surface of the polymer.

8. The method of claim 6, wherein the functionalized nanoparticles are distributed throughout at least portions of the polymer.

28. The method of claim 1, wherein a second type of chemically functional group is chemically bonded to the newly exposed surface areas of the nanoparticles while the nanoparticles are being subjected to the ultra-high shear fluidic processing.

29. The method of claim 1, wherein the ultra-high shear fluidic processing comprises turbulent hydrodynamic flow having a Reynolds number Re greater than about 2000.

2. (canceled)

9. A method for generating multi-functionalized nanoparticles comprising the steps of:

(a) providing a source of at least partially agglomerated nanoparticles having pre-existing exposed surface areas,

(b) providing a source of a first type of functional group and a source of a second type of functional group,

(c) chemically bonding at least a portion of the first type of chemically functional group to the pre-existing surface areas of said agglomerated nanoparticles,

(d) subjecting the nanoparticles to ultra-high shear fluidic processing forming newly exposed surface areas of the nanoparticles, and

(e) chemically bonding at least a portion of the second type of chemically functional group to the newly created surface areas of the nanoparticles.

11. The method of claim 9, wherein the first type of chemically functional group is chemically bonded to the pre-existing surface areas of the nanoparticles prior to the attachment of said second type of chemically functional group.

12. The method of claim 9 wherein at least a portion of the first type of chemically functional group and at least a portion of the second type of chemically functional group are chemically bonded to the newly exposed surface areas of the nanoparticle while the nanoparticles are being subjected to ultra-high shear fluidic processing.

13. The method of claim 9, wherein the second type of chemically functional group is chemically bonded to the newly exposed surface areas of the nanoparticles while the nanoparticles are being subjected to ultra-high shear fluidic processing.

15. The method of claim 9, wherein the second type of chemically functional group is chemically bonded to the newly exposed surface areas of the nanoparticles following the nanoparticles being subjected to ultra-high shear fluidic processing.

16. The method of claim 9, wherein the multi-functionalized nanoparticles are combined with at least one polymer.

17. The method of claim 16, wherein the multi-functionalized nanoparticles are distributed within the polymer.

18. The method of claim 16, wherein the multi-functionalized nanoparticles are localized on a surface of the polymer.

19. The method of claim 18, wherein the polymer surface is an interface between two polymers.

27. The method of claim 9, wherein the first chemically functional group and second chemically functional groups are segregated on the nanoparticles.

10. (canceled)

14. (canceled)

20-26. -26. (canceled)