ELECTROLUMINESCENT DEVICE HAVING IMPROVED LIGHT OUTPUT

• US 20080297029A1
• Filed: 05/31/2007
• Published: 12/04/2008
• Est. Priority Date: 05/31/2007
• Status: Active Grant

• Current Assignee: Global OLED Technology LLC (LG Display Co., Ltd.)
• Original Assignee: Global OLED Technology LLC (LG Display Co., Ltd.)
• Inventors: Cok, Ronald S.
• Granted Patent: US 7,902,748 B2
• Time in Patent Office: Days
• US Class Current: 313/498
• CPC Class Codes: B82Y 20/00 Nanooptics, e.g. quantum optics or photonic crystals
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: H10K 50/11 characterised by the electroluminescent [EL] layers
• CPC Class Codes: H10K 50/854 comprising scattering means
• CPC Class Codes: H10K 59/877 comprising scattering means

Abstract

An electroluminescent (EL) device that includes a light-emitting area formed over a substrate. First and second electrodes and one or more EL unit(s) are included along with at least one light-emitting layer formed between the electrodes, wherein at least one electrode is transparent. A cover is located over the light-emitting area, and a light-scattering layer is located between the substrate and cover. The light-scattering layer includes transparent, light-scattering particles, wherein the ratio of the volume of light-scattering particles to the volume of the light-scattering layer is greater than 0.55 over a majority of the light-emitting area, wherein either the substrate or cover is transparent and transmits light emitted from the EL unit(s).

Claims

1. An electroluminescent (EL) device, comprising:

a substrate;

a light-emitting area formed over the substrate and comprising first and second electrodes and one or more EL unit(s) comprising at least one light-emitting layer formed between the electrodes, wherein at least one electrode comprises a transparent electrode;

a cover located over the light-emitting area; and

a light-scattering layer located between the substrate and cover, comprising transparent, light-scattering particles, wherein the ratio of the volume of light-scattering particles to the volume of the light-scattering layer is greater than 0.55 over a majority of the light-emitting area, wherein either the substrate or cover is transparent and transmits light emitted from the EL unit(s).

2. The electroluminescent (EL) device of claim 1, wherein the light-scattering layer is located between the substrate and an electrode or between an electrode and the EL unit(s), or between an electrode and the cover.

3. The electroluminescent (EL) device of claim 1, wherein the light-scattering layer is adjacent to and in contact with an electrode.

4. The electroluminescent (EL) device of claim 1, wherein the first electrode is formed over the substrate and is reflective, and the second electrode is formed over the EL unit(s) and is transparent, and the light-scattering layer is located over the transparent second electrode on a side of the transparent electrode opposite the first reflective electrode.

5. The electroluminescent (EL) device of claim 1, wherein the first electrode is formed over the substrate and is transparent, and the second electrode is formed over the EL unit(s) and is transparent, and the light-scattering layer is between the first transparent electrode and the substrate.

6. The electroluminescent (EL) device of claim 1, wherein at least one electrode includes multiple layers having a transparent layer and a reflective layer, and wherein the light-scattering layer is formed between the transparent layer and the reflective layer.

7. The electroluminescent (EL) device of claim 1, wherein the light-scattering particles are non-spherical and randomly oriented.

8. The electroluminescent (EL) device of claim 1, wherein the majority of the light-scattering layer volume that is not occupied by light-scattering particles is occupied by a gas or vacuum.

9. The electroluminescent (EL) device of claim 1, wherein the light-scattering layer further comprises a binder having a refractive optical index less than the refractive index of the light-scattering particles and having a weight less than 10% of the weight of the light-scattering particles.

10. The electroluminescent (EL) device of claim 1, wherein the ratio of the volume of light-scattering particles to the volume of the light-scattering layer is between 0.55 and 0.75.

11. The electroluminescent (EL) device of claim 1, further comprising one or more protective layers formed between the light-scattering layer and the transparent electrode and/or over the light-scattering layer on the side of the light-scattering layer opposite the transparent electrode.

12. The electroluminescent (EL) device of claim 1, wherein the light-scattering particles have an average maximum diameter of less than 2 microns.

13. The electroluminescent (EL) device of claim 1, wherein the light-scattering particles have an average maximum diameter of between one half and two microns.

14. The electroluminescent (EL) device of claim 1, wherein the light-scattering particles comprise phosphorescent or fluorescent particles.

15. The electroluminescent (EL) device of claim 1, wherein the light-scattering particles comprise a metal oxide or metal nitride.

16. The electroluminescent (EL) device of claim 1, wherein the light-scattering layer is less than one micrometer thick.

17. A method of forming an electroluminescent (EL) device comprising the steps of:

a) providing an LED with a light-emitting area comprising a first electrode and a second transparent electrode and one or more EL unit(s) formed between the electrodes;

b) forming a solution comprising an evaporable solvent and a plurality of transparent light-scattering particles;

c) coating the solution on a side of the transparent electrode opposite the one or more EL unit(s); and

d) drying the solution to form a light-scattering layer on the transparent electrode, wherein the ratio of the volume of light-scattering particles to the volume of the light-scattering layer is greater than 0.55 over a majority of the light-emitting area.

18. An electroluminescent (EL) device, comprising:

a substrate;

a light-emitting area formed over the substrate and comprising first and second electrodes and one or more EL unit(s) comprising at least one light-emitting layer formed between the electrodes, wherein at least one electrode comprises a transparent electrode, the transparent electrode and EL unit(s) material having a first refractive index range;

a cover located over the light-emitting area having a second refractive index and through which light from the EL unit(s) is emitted;

a light-scattering layer located between the substrate and cover, comprising transparent, light-scattering particles, wherein the ratio of the volume of light-scattering particles to the volume of the light-scattering layer is greater than 0.55 over a majority of the light-emitting area, wherein either the substrate or cover is transparent and transmits light emitted from the EL unit(s); and

a transparent low-index element having a third refractive index lower than each of the first refractive index range and second refractive index and located between the light-scattering layer and the transparent substrate or cover.

19. The electroluminescent (EL) device of claim 18, wherein the cover is a transparent cover and wherein the transparent low-index element is adjacent to and in contact with the transparent cover or wherein the substrate is a transparent substrate and wherein the transparent low-index element is adjacent to and in contact with the transparent substrate.

20. The electroluminescent (EL) device of claim 18, wherein the first electrode is transparent and is formed over the substrate, and the second electrode is reflective and is formed over the one or more EL unit(s), and the light-scattering layer is located over the transparent low-index element and adjacent to and in contact with the first transparent electrode.