Radiation-Curable Water-Emulsifiable Polyisocyanates
First Claim
1. A water-emulsifiable, radiation-curable polyisocyanate (A) comprising as synthesis componentsa) at least one organic di- or polyisocyanate,b) at least one compound having at least one isocyanate-reactive group and at least one free-radically polymerizable unsaturated group and/or at least one cationically polymerizable group selected from optionally substituted acryloyl groups and optionally substituted vinyl ether groups,c) optionally, at least one further organic di- or polyisocyanate, different than a)d) at least one compound having precisely one isocyanate-reactive group and at least one saturated dispersive group,e) optionally, at least one compound having at least two isocyanate-reactive groups, andf) optionally, compounds different than a) to d) and having at least one isocyanate-reactive group,wherefrom compounds carrying capped amino groups, carbamate end groups and/or urea end groups in combination with anionic dispersive compounds are excluded as synthesis components, andwherein the isocyanate content, calculated as NCO with the molecular weight 42 g/mol, is at least 3% by weight and up to 25% by weight.
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Abstract
The invention relates to radiation-curable, water-emulsifiable compounds containing isocyanate groups or capped isocyanate groups, and to their use.
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Citations
17 Claims
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1. A water-emulsifiable, radiation-curable polyisocyanate (A) comprising as synthesis components
a) at least one organic di- or polyisocyanate, b) at least one compound having at least one isocyanate-reactive group and at least one free-radically polymerizable unsaturated group and/or at least one cationically polymerizable group selected from optionally substituted acryloyl groups and optionally substituted vinyl ether groups, c) optionally, at least one further organic di- or polyisocyanate, different than a) d) at least one compound having precisely one isocyanate-reactive group and at least one saturated dispersive group, e) optionally, at least one compound having at least two isocyanate-reactive groups, and f) optionally, compounds different than a) to d) and having at least one isocyanate-reactive group, wherefrom compounds carrying capped amino groups, carbamate end groups and/or urea end groups in combination with anionic dispersive compounds are excluded as synthesis components, and wherein the isocyanate content, calculated as NCO with the molecular weight 42 g/mol, is at least 3% by weight and up to 25% by weight.
Specification