CARBON NANO-TUBE (CNT) THIN FILM COMPRISING AN AMINE COMPOUND, AND A MANUFACTURING METHOD THEREOF

• US 20080311424A1
• Filed: 02/20/2008
• Published: 12/18/2008
• Est. Priority Date: 06/12/2007
• Status: Abandoned Application

• Current Assignee: Samsung Electronics Co. Ltd.
• Original Assignee: Samsung Electronics Co. Ltd.
• Inventors: Choi, Seong Jae, Shin, Hyeon Jin, Yoon, Seonmi, Choi, Jaeyoung
• Application Number:
  US12/034,358
• Publication Number:
  US 20080311424A1
• Time in Patent Office: Days
• US Class Current: 428/688
• CPC Class Codes: B82Y 10/00 Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: B82Y 40/00 Manufacture or treatment of nanostructures
• CPC Class Codes: C01B 2202/28 Solid content in solvents
• CPC Class Codes: C01B 32/174 Derivatisation; Solubilisation; Dispersion in solvents
• CPC Class Codes: H01B 1/04 mainly consisting of carbon-silicon compounds, carbon or silicon
• CPC Class Codes: H10K 71/40 Thermal treatment, e.g. annealing in the presence of a solvent vapour
• CPC Class Codes: H10K 85/225 comprising substituents
• CPC Class Codes: H10K 85/631 Amine compounds having at least two aryl rest on at least one amine-nitrogen atom, e.g. triphenylamine

Abstract

A carbon nano-tube CNT thin film and a manufacturing method thereof are provided. In detail, the CNT thin film comprises a plastic substrate; and a CNT composition being coated over the plastic substrate, in which the CNT composition includes a CNT; and an amine compound of boiling point lower than 150° C. used as a dispersion solvent. When the CNT composition is coated over the plastic substrate, an amine compound is contained in its dispersion liquid. This amine compound is then removed after the CNT composition is coated over the plastic substrate.

Claims

1. A carbon nano-tube (CNT) composition, comprising:

a CNT; and

a dispersant capable of being removed from the composition through a heat-treatment.

2. The CNT composition of claim 1, wherein the dispersant includes an amine compound.

3. The CNT composition of claim 2, wherein the amine compound has a boiling point of 150°

C. or lower.

4. The CNT composition of claim 2, wherein the amine compound includes a cyclic, linear or branched amine compound.

5. The CNT composition of claim 2, wherein the amine compound has an alkyl chain having 3 to 7 carbon atoms.

6. The CNT composition of claim 4, wherein the amine compound selected from the group consisting of butylamine, hexylamine, octylamine, pyridine, pyrazine, pyrrole, methylpyridine, ethylpyridine, n-methylpyrrolidone, and a combination comprising at least one of the foregoing cyclic amine compounds.

7. The CNT composition of claim 1, wherein the heat treatment is carried out at a temperature of 150°

C. or lower.

8. A CNT thin film, comprising:

a substrate; and

a CNT composition disposed on the substrate, the CNT composition comprising a CNT and a dispersant capable of being removed from the CNT composition through a heat-treatment.

9. The CNT thin film of claim 8, wherein the substrate is a flexible transparent substrate.

10. The CNT thin film of claim 9, wherein the flexible transparent substrate includes a transparent plastic substrate.

11. The CNT thin film of claim 8, wherein the dispersant includes an amine compound.

12. The CNT thin film of claim 11, wherein the amine compound has a boiling point of 150°

C. or lower.

13. The CNT thin film of claim 12, wherein the amine compound includes a cyclic, linear or branched amine compound.

14. The CNT thin film of claim 12, wherein the amine compound selected from the group consisting of butylamine, hexylamine, octylamine, pyridine, pyrazine, pyrrole, methylpyridine, ethylpyridine, n-methylpyrrolidone, and a combination comprising at least one of the foregoing cyclic amine compounds.

15. The CNT thin film of claim 8, wherein the heat treatment is carried out at a temperature of 150°

C. or lower.

16. The CNT composition of claim 12, wherein the amine compound has an alkyl chain having 3 to 7 carbon atoms.

17. A method of manufacturing a CNT thin film, comprising the steps of:

mixing CNTs and a dispersant capable of being removed through a heat-treatment to form a CNT dispersed solution;

;

forming a CNT thin film by coating the CNT-dispersed solution on a plastic substrate; and

heating the CNT-dispersed solution.

18. The method of claim 17, wherein the dispersant includes an amine compound.

19. The method of claim 18, wherein the amine compound has a boiling point of 150°

C. or lower.

20. The method of claim 18, wherein the amine compound selected from the group consisting of butylamine, hexylamine, octylamine, pyridine, pyrazine, pyrrole, methylpyridine, ethylpyridine, n-methylpyrrolidone, and a combination comprising at least one of the foregoing cyclic amine compounds.

21. The method of claim 17, wherein the substrate includes a flexible transparent substrate.

22. The method of claim 21, wherein the flexible transparent substrate includes a plastic substrate.

23. The method of claim 17, wherein in the step of removing the dispersant, the heating is carried out at a temperature of 150°

C. or lower.

24. A CNT electrode comprising a CNT thin film according to claim 17.

25. A thin film transistor comprising a CNT thin film according to claim 17.