Removal of a target gas from a mixture of gases by swing adsorption with use of a turboexpander

• US 20080314246A1
• Filed: 05/16/2008
• Published: 12/25/2008
• Est. Priority Date: 05/18/2007
• Status: Active Grant

• Current Assignee: ExxonMobil Research & Engineering Company (Exxon Mobil Corporation)
• Original Assignee: ExxonMobil Research & Engineering Company (Exxon Mobil Corporation)
• Inventors: Deckman, Harry W., Kelley, Bruce T., Chance, Ronald R., Northrop, Paul S., Corcoran, Edward W. JR., Thomas, Eugene R.
• Granted Patent: US 8,529,664 B2
• Time in Patent Office: Days
• US Class Current: 95/130
• CPC Class Codes: B01D 2253/108 Zeolites
• CPC Class Codes: B01D 2253/311 Porosity, e.g. pore volume
• CPC Class Codes: B01D 2253/342 Monoliths
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2259/4143 arranged as a mixture
• CPC Class Codes: B01D 53/02 by adsorption, e.g. preparative gas chromatography solid sorbent compositions B01J20/00, preparation of inorganic compounds or elements C01
• CPC Class Codes: B01D 53/0423 Beds in columns
• CPC Class Codes: B01D 53/0462 Temperature swing adsorption
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

The separation of a target gas selected from a high pressure gas mixture containing said target gas as well as a product gas using a swing adsorption process unit. A turboexpander is used upstream of the swing adsorber to reduce the pressure of the high pressure gas mixture. A compressor is optionally used downstream of the swing adsorber to increase the pressure of the target gas-containing stream for injecting into a subterranean formation.

Claims

1. A process for removing a target gas component from a gas mixture containing said target gas component and a product gas component, which process comprises:

a) conducting said gas mixture to a turboexpander wherein the volume of said gas mixture is expanded, thereby lowering its pressure;

b) conducting said lowered pressure gas mixture from said turboexpander to a swing adsorption gas separation unit wherein said gas separation unit contains an adsorbent contactor comprised of an effective microporous adsorbent material for removing at least a portion of said target gas component from said gas mixture by adsorbing at least a portion of said target gas component onto said adsorbent material;

c) producing a product gas stream with a lower mol % of said target gas component than said gas mixture and a higher mol % of said product gas component than said gas mixture;

d) collecting said the product gas stream;

e) desorbing at least a portion of the adsorbed target gas component from said adsorbent material, thereby resulting in a waste gas stream which has a higher mol % of said target gas component than said gas mixture; and

f) collecting said waste gas stream.

2. The process of claim 1 wherein the product gas component is CH₄ and the gas mixture is comprised of natural gas.

3. The process of claim 2 wherein greater than about 90 mol % of the CH₄ in the gas mixture is recovered in the product gas stream.

4. The process of claim 1 wherein the microporous adsorbent is comprised of an 8-ring zeolite.

5. The process of claim 4 wherein the 8-ring zeolite has a Si to Al molar ratio of about 1:

1 to about 1000;

1.

6. The process of claim 5 wherein the 8-ring zeolite is selected from DDR, Sigma-1 and ZSM-58.

7. The process of claim 4 wherein the 8-ring zeolite is in the form of zeolite crystals which are substantially uniform in size.

8. The process of claim 1, wherein the target gas component is CO₂.

9. The process of claim 2, wherein the target gas component is CO₂.

10. The process of claim 1 wherein the target gas component is H₂S and the microporous adsorbent is comprised of a stannosilicate.

11. The process of claim 1 wherein the adsorbent contactor is comprised of a first adsorption zone comprising a first microporous adsorbent material which is in fluid contact with a second adsorption zone comprising a second microporous adsorbent material, wherein the composition of the first microporous adsorbent material is different from the composition of a second microporous adsorbent material.

12. The process of claim 11 wherein the first microporous adsorbent material has a greater selectivity than the second microporous adsorbent material for a first target gas component over the product gas component of the gas mixture.

13. The process of claim 12 wherein the first microporous adsorbent material has a greater selectivity than the second microporous adsorbent material for the first target gas component of the gas mixture over the product gas component of the gas mixture, and the second microporous adsorbent material has a greater selectivity than the first microporous adsorbent material for a second target gas component over the product gas component of the gas mixture.

14. The process of claim 13 wherein the first target gas component is CO₂, the second target gas component is H₂S, and the product gas component is CH₄.

15. The process of claim 13 wherein the first target gas component is N₂, the second target gas component is H₂S, and the product gas component is CH₄.

16. The process of claim 14 wherein the first microporous adsorbent material is comprised of an 8-ring zeolite and the second microporous adsorbent material is comprised of a stannosilicate.

17. The process of claim 16 wherein the 8-ring zeolite has a Si to Al molar ratio of about 1:

1 to about 1000;

1.

18. The process of claim 17 wherein the 8-ring zeolite is selected from DDR, Sigma-1 and ZSM-58.

19. The process of claim 18 wherein the 8-ring zeolite is in the form of zeolite crystals which are substantially uniform in size.

20. The process of claim 1 wherein less than about 15 vol % of the open pore volume of the adsorbent contactor comprises pore sizes greater than about 20 angstroms.

21. The process of claim 1 wherein the adsorbent contactor is comprised of substantially parallel flow channels and the surfaces of said parallel flow channels contain an effective amount of particles of a thermal mass material having a higher capacity of heat adsorbtion than the microporous adsorbent material.

22. The process of claim 1 wherein the adsorbent contactor contains both mesopores and macropores and wherein at least some of the mesopores and macropores are occupied with a blocking agent of an effective size so that it is small enough to fit into a mesopore but too large to fit into a micropore.

23. The process of claim 22 wherein the blocking agent is selected from the group consisting of polymers, microporous materials, solid hydrocarbons, and liquids.

24. The process of claim 23 wherein the blocking agent is a liquid selected from the group consisting of amines, aromatics such as 1,3,5 trimethylbenzene, branched saturated hydrocarbons, and liquid hydrocarbons having carbon numbers in the about 5 to about 60 range.

25. The process of claim 1 wherein an electric generator is shaft coupled to the turboexpander.

26. The process of claim 1 wherein a compressor is shaft coupled to the turboexpander.

27. The process of claim 25 wherein at least a portion of the electrical energy produced by said electric generator is used to power a compressor.

28. The process of claim 27 wherein said compressor is used to compress at least a portion of said waste gas stream to a pressure of at least 1,000 psi.

29. The process of claim 1 wherein the gas mixture is comprised of an LNG boil-off gas.

30. The process of claim 1 wherein the gas mixture is comprised of an LNG flash gas.