Process for Production of a Disinfectant Through the Electrochemical Activation (Eca) of Water, a Disinfectant Produced in this Way and the Use Thereof

• US 20090008268A1
• Filed: 02/14/2007
• Published: 01/08/2009
• Est. Priority Date: 02/17/2006
• Status: Abandoned Application

• Current Assignee: ActiDes GmbH
• Original Assignee: ActiDes GmbH
• Inventors: Fischer, Christian, Salathe, Peter, Schmidt, Volkmar, Jost, Bernd, Gross, Steven
• Application Number:
  US12/223,818
• Publication Number:
  US 20090008268A1
• Time in Patent Office: Days
• US Class Current: 205/746
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 25/00 Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application , e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
• CPC Class Codes: A01N 59/08 Alkali metal chlorides; Alkaline earth metal chlorides
• CPC Class Codes: A61L 2/186 Peroxide solutions
• CPC Class Codes: A61L 2202/11 Apparatus for generating biocidal substances, e.g. vaporisers, UV lamps
• CPC Class Codes: A61L 2202/23 Containers, e.g. vials, bottles, syringes, mail
• CPC Class Codes: C02F 1/32 with ultraviolet light
• CPC Class Codes: C02F 1/44 by dialysis, osmosis or reverse osmosis general membrane separation processes B01D61/00, membrane modules B01D63/00, electrodialysis C02F1/4693, combination of membrane modules and bioreactors C02F3/1268
• CPC Class Codes: C02F 1/4618 for producing "ionised" acidic or basic water
• CPC Class Codes: C02F 1/4674 with halogen or compound of halogens, e.g. chlorine, bromine
• CPC Class Codes: C02F 2001/46185 only anodic or acidic water, e.g. for oxidizing or sterilizing
• CPC Class Codes: C02F 2201/46115 Electrolytic cell with membranes or diaphragms
• CPC Class Codes: C02F 2201/46125 Electrical variables
• CPC Class Codes: C02F 2201/46145 Fluid flow
• CPC Class Codes: C02F 2209/05 Conductivity or salinity
• CPC Class Codes: C02F 2209/055 Hardness
• CPC Class Codes: C02F 2209/06 pH
• CPC Class Codes: C02F 2303/04 Disinfection

Abstract

A description is given of a process for the production of a disinfectant by electrochemical activation (ECA) of water, in that to the water to be disinfected is added an electrolytic solution, particularly a sodium or potassium chloride solution and the water to which the electrolytic solution has been added in the form of a dilute water/electrolytic solution is supplied with an electrical current in an electrolytic reactor with a cathode compartment having a cathode and with an anode compartment having an anode separated spatially from the cathode compartment by applying a d.c. voltage to the electrodes, in order to bring the water/electrolytic solution into a metastable state suitable for disinfection. To bring about a reliable disinfecting action of the electrochemically activated water and with high reproducibility, the invention proposes that the pH-value of the dilute water/electrolytic solution in the reactor anode compartment is controlled to a value between 2.5 and 3.5, particularly approximately 3, so that the potential of the anodic oxidation is controlled (potential-controlled anodic oxidation or PAO). The invention also relates to a disinfectant produced in this way and the use thereof.

Claims

1-47. -47. (canceled)

48. A method for the production of a disinfectant by electrochemical activation (ECA) of water, wherein an electrolytic solution or a sodium and/or potassium chloride solution is added to the water and the water to which the electrolytic solution has been added in the form of a dilute water/electrolytic solution is supplied with an electrical current in an electrolytic reactor having at least one cathode compartment with a cathode and at least one anode compartment with an anode, the anode being separated spatially from the cathode compartment or separated spatially from the cathode compartment by means of a diaphragm or membrane, wherein a d.c. voltage is applied to the electrodes in order to bring the dilute water/electrolytic solution into a metastable state suitable for disinfection, a pH-value of the dilute water/electrolytic solution in the anode compartment being controlled to a value between 2.7 and 3.5 and a redox potential of the dilute water/electrolytic solution in the anode compartment being controlled to a value between 1240 and 1360 mV, the method comprising the steps of:

a) determining, at a predetermined residence time (Tv) of the water/electrolytic solution in the electrolytic reactor and/or at a predetermined volumetric flow (V′

) of the water/electrolytic solution through the electrolytic reactor, a static desired current (Ides, stat) between the electrodes dependent on a composition of the water to be disinfected, the static desired current being determined as a function of a conductivity (κ

) and/or hardness (H) of the water according to a straight line equation of form;

Ides,stat=K1*κ

+K2

and/or

Ides,stat=K3*H+K4

 

K1, K2, K3, and K4 being reactor-specific constants; and

b) determining, at a predetermined static desired current (Ides,stat) between the electrodes of electrolytic reactor, a dynamic desired current (Ides, dyn) dependent on a residence time (Tv) of the water/electrolytic solution in the electrolytic reactor and/or a volumetric flow V′

of the water/electrolytic solution through the electrolytic reactor, the dynamic desired current being determined according to a straight line equation of form;

Ides,dyn=K5*Tv+K6

and/or

Ides,dyn=K7*V′

+K8

 

K5, K6, K7 and K8 being reactor-specific constants; and

c) applying a total desired current (Ides, tot) to the electrodes of the electrolytic reactor, which is formed from a sum of the static desired current (Ides, stat) and the dynamic desired current (I des, dyn);

Ides,tot=Ides,stat+Ides,dyn.

49. The method of claim 48, wherein the pH-value of the dilute water/electrolytic solution in the anode compartment is controlled to a value between 2.7 and 3.3 or between 2.8 and 3.2.

50. The method of claim 48, wherein the redox potential of the dilute water/electrolytic solution in the anode compartment is controlled to a value between 1280 and 1360 mV or to a value between 1320 and 1360 mV.

51. The method of claim 48, wherein the pH-value of the dilute water/electrolytic solution in the anode chamber is controlled by controlled addition of a corresponding electrolytic solution quantity.

52. The method of claim 48, wherein the pH-value of the dilute water/electrolytic solution in the anode compartment is controlled by controlling the current flowing between the electrodes.

53. The method of claim 48, wherein the pH-value of the dilute water/electrolytic solution in the anode compartment is controlled by controlling the residence time (Tv) and/or volumetric flow (V′

) thereof in or through the electrolytic reactor.

54. The method of claim 48, wherein, for controlling the pH-value of the dilute water/electrolytic solution in the anode compartment of electrolytic reactor to a pH-value between 2.7 and 3.5 at a predetermined desired current between the electrodes of electrolytic reactor, a residence time (Tv) dependent on a composition of the water to be disinfected and/or a volumetric flow (V′

) of the dilute water/electrolytic solution in or through electrolytic reactor is determined in dependence on a composition of the water.

55. The method of claim 54, wherein the residence time (Tv) and/or volumetric flow (V′

) in or through the electrolytic reactor is determined as a function of a conductivity (κ

) and/or hardness (H) of the water.

56. The method of claim 54, wherein the residence time (Tv) and/or volumetric flow (V′

) is determined according to a straight line equation of form;

Tv=k1*κ

+k2

and/or

V′

=k3*H+k4

in which k1, k2, k3 and k4 are reactor-specific constants.

57. The method of claim 54, wherein a quantity of dosed electrolytic solution is kept substantially constant.

58. The method of claim 48, wherein the electrolyte concentration of the dilute water/electrolytic solution added to the electrolytic reactor is controlled to a value of at most 20 g/l.

59. The method of claim 48, wherein a specific electrical conductivity of the water to be electrochemically activated is set to a value of at most 350 μ

S/cm prior to adding the electrolytic solution.

60. The method of claim 48, wherein control of an electrolyte concentration of an alkali metal chloride concentration of the dilute water/electrolytic solution or a dilute water/alkali metal chloride solution added to the electrolytic reactor takes place by controlling an electrolytic solution quantity added to the water to be electrochemically activated.

61. The method of claim 60, wherein control of the alkali metal chloride concentration of the dilute water/alkali metal chloride solution added to the electrolytic reactor is carried out as a function of a corresponding specific electrical conductivity of the water/alkali metal chloride solution added to the electrolytic reactor, a dependence of the alkali metal chloride concentration on the specific electrical conductivity of the dilute water/alkali metal chloride solution added to the electrolytic reactor being predetermined for the water to be electrochemically activated.

62. The method of claim 61, wherein a dependence of the alkali metal chloride concentration on the specific electrical conductivity of the dilute water/alkali metal chloride solution added to the electrolytic reactor is determined according to a calibration line of the form

κ

tot=κ

w+dκ

/d[MeCl]*[MeCl]

κ

tot being the specific electrical conductivity of the dilute water/alkali metal chloride solution added to the electrolytic reactor, κ

w the specific electrical conductivity of the water to be disinfected, [MeCl] the alkali metal chloride concentration of the dilute water/alkali metal chloride solution and dκ

/d[MeCl] the water-specific slope of the calibration line.

63. The method of claim 48, wherein only an electrochemically activated, dilute water/electrolytic solution produced in the anode compartment is used as a disinfectant.

64. The method of claim 48, wherein the method is used for disinfecting water.

65. The method of claim 64, wherein a partial flow is branched off from water to be disinfected, the partial flow is electrochemically activated, and at least the electrochemically activated partial flow in the anode compartment is added as disinfectant to the water to be disinfected.

66. The method of claim 48, wherein the disinfectant is used for disinfecting drinking and service water, rain water, swimming pool water, industrial water, or waste water.

67. The method of claim 48, wherein the disinfectant is used for disinfecting foods, cereals, spices, fruits, vegetables, ice cream, or animal products.

68. The method of claim 48, wherein the disinfectant is used for disinfecting seed.

69. The method of claim 48, wherein disinfectant is used for disinfecting packing containers or packs for hygienic products, foods, pharmaceuticals, or sterile articles.

70. The method of claim 48, wherein the disinfectant is used as an additive for paints, lacquers, varnishes or pigments.

71. The method of claim 48, wherein the disinfectant is used as an additive for coolants or lubricants.

77. The method of claim 48, wherein the disinfectant is used as an additive for fuels, propellants, heating oil, gasoline, or kerosene.