ELECTROPHORETIC PARTICLES AND PROCESSES FOR THE PRODUCTION THEREOF

• US 20090009852A1
• Filed: 08/08/2008
• Published: 01/08/2009
• Est. Priority Date: 05/15/2001
• Status: Abandoned Application

• Current Assignee: E Ink Corporation (E Ink Holdings Incorporated)
• Original Assignee: E Ink Corporation (E Ink Holdings Incorporated)
• Inventors: King, Matthew A., Walls, Michael D., Honeyman, Charles Howie, Whitesides, Thomas H., Oleson, Andrew Y., Gates, Elizabeth M.
• Application Number:
  US12/188,648
• Publication Number:
  US 20090009852A1
• Time in Patent Office: Days
• US Class Current: 359/296
• CPC Class Codes: G02F 1/167 by electrophoresis
• CPC Class Codes: G02F 2001/1678 characterised by the composition or particle type
• CPC Class Codes: Y10T 428/2998 including synthetic resin or polymer

Abstract

Polymer-coated pigment particles produced using atom transfer radical polymerization provide electrophoretic media having improved bistability without requiring addition to the electrophoretic fluid of additives which increase switching time.

Claims

1. A process for producing a polymer-coated pigment particle, which process comprises:

(a) reacting the particle with a reagent having a functional group capable of reacting with, and bonding to, the particle, and also having a group which provides an initiating site for atom transfer radical polymerization, thereby causing the functional group to react with the particle surface and attach the initiating site thereto; and

(b) reacting the product of step (a) with at least one monomer or oligomer capable of undergoing atom transfer radical polymerization under conditions effective to cause such polymerization, thereby causing the formation of polymer bonded to the particle.

2. A process according to claim 1 further comprising dispersing the polymer-coated pigment particle into a fluid to form an electrophoretic medium.

3. A process according to claim 1 wherein the reagent used in step (a) is an α

-halo carbonyl compound, or a benzylic or allylic halide.

4. A process according to claim 3 wherein the reagent is [2-(chloromethylphenyl)ethyl]-trimethoxylsilane or [3-(α

-bromoisobutyroyloxypropyl)]-trimethoxylsilane.

5. A process according to claim 1 wherein the reagent used in step (a) and having a group which provides an initiating site for atom transfer radical polymerization is used in admixture with a reagent which does not have an initiating site for atom transfer radical polymerization.

6. A process according to claim 5 wherein the two reagents are both silanes.

7. A process according to claim 1 wherein the pigment particle comprises titania.

8. A process according to claim 1 wherein the monomer used in step (b) comprises an alkyl acrylate or methacrylate.

9. A process according to claim 8 wherein the monomer comprises lauryl methacrylate.

10. An electrophoretic medium comprising a polymer-coated particle produced by a process according to claim 1.

11. An electrophoretic display comprising an electrophoretic medium according to claim 10 and at least one electrode arranged to apply an electric field to the electrophoretic medium.

12. An electronic book reader, portable computer, tablet computer, cellular telephone, smart card, sign, watch, shelf label or flash drive comprising a display according to claim 11.

13. A process for producing a polymer-coated pigment particle, which process comprises:

(a) reacting the particle with a reagent having a functional group capable of reacting with, and bonding to, the particle, and also having a polymerizable or polymerization-initiating group, thereby causing the functional group to react with the particle surface and attach the polymerizable group thereto; and

(b) reacting the product of step (a) with at least one monomer or oligomer under conditions effective to cause reaction between the polymerizable or polymerization-initiating group on the particle and the at least one monomer or oligomer, thereby causing the formation of polymer bonded to the particle, the at least one monomer or oligomer comprising at least one atom transfer radical polymerizable initiating monomer; and

(c) stopping the polymerization of step (a), and thereafter treating the particle with at least one monomer or oligomer capable of undergoing atom transfer radical polymerization under conditions effective to cause such polymerization, thereby causing the formation of additional polymer attached to the particle.

14. A process according to claim 13 further comprising dispersing the polymer-coated pigment particle into a fluid to form an electrophoretic medium.

15. A process according to claim 13 wherein the monomer used in step (b) is a halogenated alkene.

16. A process according to claim 15 wherein the monomer is (chloromethyl)styrene.

17. A process according to claim 13 wherein, in step (b), the at least one atom transfer radical polymerizable initiating monomer is used in admixture with a monomer or oligomer which does not have an initiating site for atom transfer radical polymerization.

18. A process according to claim 17 wherein the at least one atom transfer radical polymerizable initiating monomer comprises from about 0.1 to about 1 mole percent of the mixture of monomers and/or oligomers used in step (b).

19. A process according to claim 13 wherein the pigment particle comprises titania.

20. A process according to claim 13 wherein the monomer used in step (c) comprises an alkyl acrylate or methacrylate.

21. A process according to claim 20 wherein the monomer comprises lauryl methacrylate.

22. An electrophoretic medium comprising a polymer-coated particle produced by a process according to claim 13.

23. An electrophoretic display comprising an electrophoretic medium according to claim 22 and at least one electrode arranged to apply an electric field to the electrophoretic medium.

24. An electronic book reader, portable computer, tablet computer, cellular telephone, smart card, sign, watch, shelf label or flash drive comprising a display according to claim 23.

25. A process for producing a polymer-coated pigment particle, which process comprises:

(a) reacting the particle with a reagent having a functional group capable of reacting with, and bonding to, the particle, and also having a polymerizable or polymerization-initiating group, thereby causing the functional group to react with the particle surface and attach the polymerizable group thereto;

(b) reacting the product of step (a) with at least one monomer or oligomer under conditions effective to cause reaction between the polymerizable or polymerization-initiating group on the particle and the at least one monomer or oligomer, thereby causing the formation of polymer bonded to the particle;

(c) reacting the product of step (b) with at least one monomer or oligomer comprising at least one atom transfer radical polymerizable initiating monomer under conditions effective to cause attachment of the monomer or oligomer to the particle; and

(d) reacting the product of step (b) with at least one monomer or oligomer capable of undergoing atom transfer radical polymerization and different from the monomer or oligomer used in step (c), under conditions effected to cause the monomer or oligomer to undergo atom transfer radical polymerization and become attached to the particle.

26. A process according to claim 25 further comprising dispersing the polymer-coated pigment particle into a fluid to form an electrophoretic medium.

27. A process according to claim 25 wherein the monomer used in step (c) is (chloromethyl)styrene.

28. A process according to claim 25 wherein, in step (c), the at least one atom transfer radical polymerizable initiating monomer is used in admixture with a monomer or oligomer which does not have an initiating site for atom transfer radical polymerization.

29. A process according to claim 28 wherein the at least one atom transfer radical polymerizable initiating monomer comprises from about 0.1 to about 1 mole percent of the mixture of monomers and/or oligomers used in step (c).

30. A process according to claim 25 wherein the pigment particle comprises titania.

31. A process according to claim 25 wherein the monomer used in step (d) comprises an alkyl acrylate or methacrylate.

32. A process according to claim 31 wherein the monomer comprises lauryl methacrylate.

33. An electrophoretic medium comprising a polymer-coated particle produced by a process according to claim 25.

34. An electrophoretic display comprising an electrophoretic medium according to claim 33 and at least one electrode arranged to apply an electric field to the electrophoretic medium.

35. An electronic book reader, portable computer, tablet computer, cellular telephone, smart card, sign, watch, shelf label or flash drive comprising a display according to claim 34.