SUPERHYDROPHOBIC SURFACE AND METHOD FOR FORMING SAME

• US 20090011222A1
• Filed: 12/13/2006
• Published: 01/08/2009
• Est. Priority Date: 03/27/2006
• Status: Abandoned Application

• Current Assignee: Georgia Tech Research Corporation (University System of Georgia)
• Original Assignee: Georgia Tech Research Corporation (University System of Georgia)
• Inventors: Xiu, Yonghao, Hampton, Robert N., Xiao, Fei, Lambert, Franklin C., Hess, Dennis W., Zhu, Lingbo, Wong, Ching Ping
• Application Number:
  US11/610,111
• Publication Number:
  US 20090011222A1
• Time in Patent Office: Days
• US Class Current: 428/323
• CPC Class Codes: C23C 18/00 Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
• CPC Class Codes: C23C 24/00 Coating starting from inorganic powder spraying of the coating material in molten state C23C4/00; solid state diffusion C23C8/00 - C23C12/00
• CPC Class Codes: Y10T 428/25 Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
• CPC Class Codes: Y10T 428/31504 Composite [nonstructural laminate]

Abstract

The present invention is a method of applying Lotus Effect materials as a (superhydrophobicity) protective coating for various system applications, as well as the method of fabricating/preparing Lotus Effect coatings.

Claims

1. An inorganic, stable superhydrophobic surface, wherein stable is defined as the surface maintaining a contact angle of greater than 150 degrees after 1,000 hours of multi factor ageing tests.

2. The superhydrophobic surface of claim 1, the surface being upon a dielectric substrate.

3. The superhydrophobic surface of claim 1, the surface being upon a semiconductor substrate.

4. The superhydrophobic surface of claim 1, the surface being upon an insulator substrate.

5. The superhydrophobic surface of claim 1, the surface being upon a conductor substrate.

6. The superhydrophobic surface of claim 1, the surface being UV-stable, wherein UV-stable is defined as the surface maintaining a contact angle of at least 150 degrees after 1,000 hours of a UV weathering test according to ASTM D 4329.

7. The superhydrophobic surface of claim 1, the surface maintaining a contact angle of greater than 150 degrees after 5,500 hours of multi factor ageing tests.

8. The superhydrophobic surface of claim 1, the surface maintaining a contact angle of greater than 162 degrees after 1,000 hours of multi factor ageing tests.

9. The superhydrophobic surface of claim 1, the surface maintaining a contact angle of greater than 162 degrees after 5,500 hours of multi factor ageing tests.

10. The superhydrophobic surface of claim 1, the surface being at least one coating upon a substrate, the coating comprising particles having multi-modal size distributions.

11. The superhydrophobic surface of claim 10, wherein the at least one coating comprises at least two primary-sized particles, a first particle size greater than a second particle size, and wherein the ratio of the mean particle size of the first particle size to the mean particle size of the second particle size is greater than approximately 2.4.

12. The superhydrophobic surface of claim 11, wherein the ratio of the mean particle size of the first particle size to the mean particle size of the second particle size is greater than approximately 8.

13. The superhydrophobic surface of claim 11, wherein the ratio of the mean particle size of the first particle size to the mean particle size of the second particle size is greater than approximately 40.

14. The superhydrophobic surface of claim 1, the surface being at least one coating upon a substrate, the coating comprising single species particles.

15. The superhydrophobic surface of claim 1, the surface being at least one coating upon a substrate, the coating comprising multi-species particles.

16. The superhydrophobic surface of claim 15, wherein the particles have uni-modal size distribution.

17. The superhydrophobic surface of claim 15, wherein the particles have multi-modal size distribution.

18. The superhydrophobic surface of claim 15, wherein the at least one coating comprises at least two primary-sized particles, a first particle size greater than a second particle size, and wherein the ratio of the mean particle size of the first particle size to the mean particle size of the second particle size is greater than approximately 2.4.

19. The superhydrophobic surface of claim 18, wherein the ratio of the mean particle size of the first particle size to the mean particle size of the second particle size is greater than approximately 8.

20. The superhydrophobic surface of claim 18, wherein the ratio of the mean particle size of the first particle size to the mean particle size of the second particle size is greater than approximately 40.

21. A method of forming an inorganic, stable superhydrophobic surface comprising the following steps:

mixing one or more precursors and a solvent to form a first solution;

reacting over time a mixed solution to form a reacted solution;

applying the reacted solution to a clean substrate; and

gelling the reacted solution on the substrate to form the inorganic, stable superhydrophobic surface,

wherein the mixed solution is the first solution.

22. The method according to claim 21, further comprising the step of mixing an acid and water in the first solution to form a second solution, wherein the mixed solution is the second solution.

23. The method according to claim 21, further comprising the step of mixing a eutectic with the first solution to form a second solution, wherein the mixed solution is the second solution.

24. The method according to claim 21, wherein one or more precursors is functionalized.

25. The method according to claim 21, wherein stable is defined as the surface maintaining a contact angle of greater than 150 degrees after 1,000 hours of multi factor ageing tests.

26. The method according to claim 21, wherein the substrate is a dielectric substrate.

27. The method according to claim 21, wherein the substrate is an insulating substrate.

28. The method according to claim 21, wherein the surface is UV-stable, wherein UV-stable is defined as the surface maintaining a contact angle of at least 150 degrees after 1,000 hours of a UV weathering test according to ASTM D 4329.

29. The method according to claim 21, the surface maintaining a contact angle of greater than 150 degrees after 5,500 hours of multi factor ageing tests.

30. The method according to claim 21, the surface maintaining a contact angle of greater than 162 degrees after 1,000 hours of multi factor ageing tests.

31. The method according to claim 21, the surface maintaining a contact angle of greater than 162 degrees after 5,500 hours of multi factor ageing tests.

32. The method according to claim 21, wherein the one or more precursors are organometallic.

33. The method according to claim 32, wherein the one or more precursors are tetra organometallic and tri organometallic.

34. The method according to claim 21, wherein the solvent is an alcohol.

35. The method according to claim 34, wherein the solvent is ethanol.

36. The method according to claim 21, wherein the step of mixing the one or more precursors and the solvent to form the first solution is run at a temperature of between 10-80°

C.

37. The method according to claim 22, wherein the acid is one of hydrochloric acid, sulfuric acid, phosphoric acid, chromic acid, oxalic acid, formic acid, and acetic acid.

38. The method according to claim 22, wherein the step of mixing the acid and water in the first solution to form the second solution is run at a temperature of between 10-40°

C.

39. The method according to claim 21, wherein the step of reacting over time the mixed solution to form the reacted solution runs between 30 minutes and 8 hours.

40. The method according to claim 21, wherein the step of applying the reacted solution to the clean substrate is by dipcoating.

41. The method according to claim 21, wherein the step of applying the reacted solution to the clean substrate is by spincoating.

42. The method according to claim 21, wherein the step of applying the reacted solution to the clean substrate is by spray coating.

43. The method according to claim 21, wherein the step of applying the reacted solution to the clean substrate is by painting.

44. The method according to claim 21, comprising the further step of cleaning the substrate prior to the step of applying the reacted solution to a clean substrate, wherein the step of cleaning the substrate includes Piranha solution cleaning.

45. The method according to claim 21, comprising the further step of cleaning the substrate prior to the step of applying the reacted solution to a clean substrate, wherein the step of cleaning the substrate includes alkali/H₂O₂ cleaning.

46. The method according to claim 21, comprising the further step of cleaning the substrate prior to the step of applying the reacted solution to a clean substrate, wherein the step of cleaning the substrate includes UV/ozone cleaning.

47. The method according to claim 21, comprising the further step of cleaning the substrate prior to the step of applying the reacted solution to a clean substrate, wherein the step of cleaning the substrate includes mechanical abrasion of the substrate.

48. The method according to claim 21, wherein the step of gelling the reacted solution on the substrate to form the inorganic, stable superhydrophobic surface is by a base catalyzed reaction.

49. The method according to claim 21, further comprising the step of fine-tuning the strength of the resultant inorganic, stable superhydrophobic surface by adjusting the ratio of the precursors if more than one precursor is used.

50. The method according to claim 21, further comprising the step of firing to strengthen the surface structure.

51. The method according to claim 21, further comprising the step of post-treatment of the structured surface for improved hydrophobicity.

52. A process of improving the superhydrophobic properties of a surface of a substrate comprising a near-ambient temperature surface treatment using a coupling agent to increase the contact angle and decrease the hysteresis of the surface.

53. The near-ambient temperature surface treatment process according to claim 52, further comprising using at least one eutectic liquid as a solvent and templating agents for the creation of surface structures.

54. The near-ambient temperature surface treatment process according to claim 52, wherein the surface is an inorganic, stable superhydrophobic surface, wherein stable is defined as the surface maintaining a contact angle of greater than 150 degrees after 1,000 hours of multi factor ageing tests.

55. A method of forming an inorganic, stable superhydrophobic surface comprising the following steps:

mixing a sol with nanoparticles to form a first solution;

applying the first solution to a clean substrate; and

gelling the first solution on the substrate to form the inorganic, stable superhydrophobic surface;

wherein the nanoparticles are used as sacrificial templating agents

56. The method of forming an inorganic, stable superhydrophobic surface according to claim 55, wherein stable is defined as the surface maintaining a contact angle of greater than 150 degrees after 1,000 hours of multi factor ageing tests.