Treatment of Fly Ash For Use in Concrete

• US 20090013907A1
• Filed: 07/12/2007
• Published: 01/15/2009
• Est. Priority Date: 07/12/2007
• Status: Active Grant

• Current Assignee: CoorsTek Incorporated (Trelleborg AB)
• Original Assignee: Ceramatec, Inc. (Trelleborg AB)
• Inventors: Akash, Akash, Boxley, Chett, Zhao, Qiang
• Granted Patent: US 8,172,940 B2
• Time in Patent Office: Days
• US Class Current: 106/705
• CPC Class Codes: C04B 12/005 Geopolymer cements, e.g. reaction products of aluminosilicates with alkali metal hydroxides or silicates
• CPC Class Codes: C04B 14/044 Polysilicates, e.g. geopolymers
• CPC Class Codes: C04B 18/08 Flue dust , i.e. fly ash
• CPC Class Codes: C04B 20/023 Chemical treatment
• CPC Class Codes: C04B 20/04 Heat treatment
• CPC Class Codes: C04B 7/243 Mixtures thereof with activators or composition-correcting additives, e.g. mixtures of fly ash and alkali activators
• CPC Class Codes: Y02P 40/10 Production of cement, e.g. improving or optimising the production methods; Cement grinding
• CPC Class Codes: Y02W 30/91 Use of waste materials as fillers for mortars or concrete

Abstract

A process for treating fly ash to render it highly usable as a concrete additive. A quantity of fly ash is obtained that contains carbon and which is considered unusable fly ash for concrete based upon foam index testing. The fly ash is mixed with an activator solution sufficient to initiate a geopolymerization reaction and for a geopolymerized fly ash. The geopolymerized fly ash is granulated. The geopolymerized fly ash is considered usable fly ash for concrete according to foam index testing. The geopolymerized fly ash may have a foam index less than 35% of the foam index of the untreated fly ash, and in some cases less than 10% of the foam index of the untreated fly ash. The activator solution may contain an alkali metal hydroxide, carbonate, silicate, aluminate, or mixtures thereof.

Claims

1. A process of treating fly ash for use as a cement additive for use in concrete comprising:

obtaining a quantity of fly ash that contains between 1 and 50% carbon, by weight, based upon loss on ignition (LOI) and which is considered unusable fly ash for concrete based upon foam index testing;

mixing the fly ash with an activator solution sufficient to initiate a geopolymerization reaction and form a geopolymerized fly ash; and

granulating the geopolymerized fly ash, wherein the geopolymerized fly ash is considered, at a minimum, usable fly ash for concrete according to foam index testing.

2. The process according to claim 1, wherein the activator solution comprises an activator selected from a metal carbonate, a metal silicate, a metal aluminate, a metal sulfate, a metal hydroxide, and mixtures thereof.

3. The process according to claim 1, wherein the activator solution comprises a metal carbonate.

4. The process according to claim 1, wherein the activator solution comprises a metal silicate.

5. The process according to claim 1, wherein the activator solution comprises a metal aluminate.

6. The process according to claim 1, wherein the activator solution comprises a metal hydroxide.

7. The process according to claim 1, wherein the activator solution comprises a carbonate and an alkali hydroxide.

8. The process according to claim 2, wherein the ratio of activator to fly ash is between 1:

50 and 10;

1.

9. The process according to claim 1, wherein the geopolymerized fly ash is granulated by spray drying.

10. The process according to claim 9, wherein the geopolymerized fly ash is heated to a temperature between 20 and 250°

C.

11. The process according to claim 9, wherein the geopolymerized fly ash is heated to a temperature between 20 and 150°

C.

12. The process according to claim 1, wherein the geopolymerized fly ash is granulated by crushing.

13. The process according to claim 1, wherein the granulated, geopolymerized fly ash has a mean particle size between 0.1 and 1000 microns.

14. The process according to claim 1, wherein the granulated, geopolymerized fly ash has a mean particle size between 10 and 100 microns.

15. The process according to claim 1, wherein the geopolymerized fly ash is considered premium grade for concrete based upon foam index testing.

16. The process according to claim 1, wherein the geopolymerized fly ash is considered standard grade for concrete based upon foam index testing.

17. The process according to claim 1, wherein the fly ash contains one or more heavy metals.

18. The process according to claim 1, further comprising the step of mixing the granulated and geopolymerized fly ash with an activator solution sufficient to initiate a second geopolymerization reaction and form a second geopolymerized fly ash.

19. A geopolymerized fly ash prepared according to the process of claim 1.

20. A concrete mixture comprising the geopolymerized fly ash prepared according to the process of claim 1.

21. A process of treating fly ash for use as a cement additive for use in concrete comprising:

obtaining a quantity of fly ash that contains carbon and has a foam index;

mixing the fly ash with an activator solution sufficient to initiate a geopolymerization reaction and form a geopolymerized fly ash; and

granulating the geopolymerized fly ash, wherein the geopolymerized fly ash has foam index less than 35% of the foam index of the untreated fly ash.

22. The process according to claim 21, wherein the activator solution comprises an activator selected from a metal carbonate, a metal silicate, a metal aluminate, a metal sulfate, a metal hydroxide, and mixtures thereof.

23. The process according to claim 21, wherein the activator solution comprises a metal carbonate.

24. The process according to claim 21, wherein the activator solution comprises a metal silicate.

25. The process according to claim 21, wherein the activator solution comprises a metal aluminate.

26. The process according to claim 21, wherein the activator solution comprises a metal hydroxide.

27. The process according to claim 21, wherein the activator solution comprises a carbonate and an alkali hydroxide.

28. The process according to claim 21, wherein the geopolymerized fly ash is granulated by spray drying.

29. The process according to claim 21, wherein the geopolymerized fly ash is granulated by crushing.

30. The process according to claim 21, wherein the geopolymerized fly ash has a foam index less than 20% of the foam index of the untreated fly ash.

31. The process according to claim 21, wherein the geopolymerized fly ash has a foam index less than 15% of the foam index of the untreated fly ash.

32. The process according to claim 21, wherein the geopolymerized fly ash has a foam index less than 10% of the foam index of the untreated fly ash.

33. The process according to claim 21, further comprising the step of mixing the granulated and geopolymerized fly ash with an activator solution sufficient to initiate a second geopolymerization reaction and form a second geopolymerized fly ash.

34. A geopolymerized fly ash prepared according to the process of claim 21.

35. A concrete mixture comprising the geopolymerized fly ash prepared according to the process of claim 21.