ELECTROCHEMICAL IMPEDANCE SPECTROSCOPY METHOD AND SYSTEM

• US 20090027070A1
• Filed: 07/16/2008
• Published: 01/29/2009
• Est. Priority Date: 02/14/2006
• Status: Abandoned Application

• Current Assignee: Ndsu-Research Foundation
• Original Assignee: Ndsu-Research Foundation
• Inventors: Gelling, Victoria Johnston
• Application Number:
  US12/174,540
• Publication Number:
  US 20090027070A1
• Time in Patent Office: Days
• US Class Current: 324/693
• CPC Class Codes: G01N 17/02 Electrochemical measuring systems for weathering, corrosion or corrosion-protection measurement

Abstract

A dual cell Electrochemical Impedance System (EIS) testing apparatus and method for measuring coating integrity on various substrates. The counter reference electrode is in a first cell in electrical contact with the coating. The working electrode is in a second cell in electrical contact with the coating instead of the substrate material acting as the working electrode. Voltage is applied at the working electrode at varying frequencies and current is measured at the combined reference/counter electrode. From the known voltage and the measured current, the impedance of the coating is calculated. Coatings on non-metallic substrates can be measured with this apparatus. In one embodiment, the EIS cells are in the form of vacuum cups containing an electrolyte gel for testing non-horizontal coatings in the field. Also, known current can be applied to the working electrode and voltage measured at the counter reference electrode can be used to calculate coating impedance.

Claims

1. An apparatus for measuring impedance of a coating on a substrate comprising:

a first cell chamber;

wherein said first cell chamber has a first opening;

a counter-reference electrode positioned in said first cell chamber;

a second cell chamber;

wherein said second cell chamber has a second opening;

a working electrode positioned in said second cell chamber;

an electrolyte positioned in said first, second cell chambers;

wherein said electrolyte is in electrical contact with said counter-reference electrode in said first cell chamber;

wherein said electrolyte is in electrical contact with said working electrode in said second cell chamber;

means for securing said first opening and said second opening to a coating;

wherein said electrolyte makes electrical contact with said coating when said first opening and said second opening are in contact with said coating by said means for securing;

a potentiostat electrically connected to said counter-reference electrode and to said working electrode;

wherein said potentiostat is adapted to apply alternating voltage at varying frequencies to said working electrode and measure current at said counter-reference electrode;

means for calculating impedance from measured current; and

means for outputting impedance.

2. An apparatus as recited in claim 1:

wherein the distance between said counter-reference electrode and the coating is adjustable; and

wherein the distance between said working electrode and the coating is adjustable.

3. An apparatus as recited in claim 1, wherein said counter reference electrode comprises a niobium platinum plated mesh;

and

wherein said working electrode comprises a niobium platinum plated mesh.

4. An apparatus as recited in claim 1, wherein said means for securing is adapted to secure said first opening and said second opening to a non-horizontal coating.

5. An apparatus as recited in claim 1, wherein said electrolyte comprises a conductive gel.

6. An apparatus as recited in claim 1, wherein said means for securing comprises:

a frame supporting said first cell chamber and said second cell chamber;

a spring loaded plunger connected to said frame; and

a base connected to said spring loaded plunger;

wherein said base is adapted to support a coated substrate.

7. An apparatus as recited in claim 6, wherein the distance between said first cell chamber and said second cell chamber is adjustable.

8. An apparatus as recited in claim 1, wherein said means for securing comprises:

a first vacuum cup coupled to said reference counter electrode; and

a second vacuum cup coupled to said working electrode.

9. An apparatus as recited in claim 1, further comprising:

wherein said potentiostat is adapted to apply alternating current at varying frequencies to said working electrode;

wherein said potentiostat is further adapted to measure voltage at said counter-reference electrode; and

means for calculating impedance from measured voltage.

10. An apparatus as recited in claim 1:

wherein said first cell chamber comprises a cavity in a first body;

wherein said first opening comprises a first O-ring mounted in said first body;

wherein said second cell chamber comprises a cavity in a second body; and

wherein said second opening comprises a second O-ring mounted in said second body.

11. An apparatus as recited in claim 1:

wherein said first cell chamber comprises a first vacuum cup; and

wherein said second cell chamber comprises a second vacuum cup.

12. An apparatus as recited in claim 11, wherein said counter reference electrode comprises stainless steel;

and

wherein said working electrode comprises stainless steel.

13. An apparatus for measuring the impedance of a coating on a substrate comprising:

a first vacuum cup having a first cavity;

a counter-reference electrode positioned in said first cavity;

a second vacuum cup having a second cavity;

a working electrode positioned in said second cavity;

an electrolyte positioned in said first, second cavities;

said electrolyte adapted to conduct electricity between a coating and an electrode;

a potentiostat electrically connected to said counter-reference electrode and said working electrode;

wherein said potentiostat is adapted to apply alternating current at varying frequencies to said working electrode and measure potential at said counter-reference electrode;

means for calculating impedance from measured potential; and

means for outputting impedance.

14. An apparatus as recited in claim 13, wherein said first, second vacuum cups are adapted to couple to a non-horizontal coating.

15. An apparatus as recited in claim 13, wherein said electrolyte comprises a conductive gel.

16. An apparatus as recited in claim 13, further comprising:

wherein said potentiostat is adapted to apply alternating voltage at varying frequencies to said working electrode;

wherein said potentiostat is further adapted to measure current at said counter-reference electrode; and

means for calculating impedance from measured current.

17. An electrode cell for measuring impedance of a coating on a substrate comprising:

a planar vacuum cup base having a first aperture;

a resilient vacuum pad having first and second sides, said first side adapted to mate with said planar vacuum cup base;

said second side of said vacuum pad having a concave cavity;

a second aperture in said vacuum pad adapted to align with said first aperture;

an electrode comprising a disk and perpendicular stem;

said disk of said electrode adapted to fit inside said concave cavity of said vacuum pad;

said stem of said electrode adapted to fit in said first aperture and said second aperture;

wherein said stem is further adapted to couple said vacuum pad to said vacuum base;

said stem adapted to electrically connect to a potentiostat;

an electrolyte positioned in said concave cavity;

said electrolyte adapted to conduct electricity between a coating and said electrode;

wherein when said concave cavity of said vacuum pad containing said electrolyte is positioned on a coating, said electrode makes electrical contact with the coating through said electrolyte.

18. An electrode cell as recited in claim 17, wherein moving said electrode away from said coating relative to said vacuum cup base forms a vacuum between said concave cavity and said coating.

19. An electrode cell as recited in claim 18, wherein said vacuum pad is adapted to releasably couple to a non-horizontal coating.

20. An electrode cell as recited in claim 17, wherein said electrolyte comprises a conductive gel.

21. A method for measuring impedance of a coating on a substrate comprising:

providing a first electrode chamber having a counter-reference electrode and an electrolyte in said chamber;

providing a second electrode chamber having a working electrode and an electrolyte in said chamber;

providing a potentiostat adapted to apply alternating voltage at varying frequencies to said working electrode and measure current at said counter-reference electrode;

coupling said first and second electrode chamber to a coating wherein said electrolyte makes electrical contact with said coating;

applying alternating voltage at varying frequencies to said working electrode;

measuring current at said counter-reference electrode;

calculating impedance from said measured current; and

outputting impedance to interpret coating integrity.

22. A method as recited in claim 21, wherein said counter reference electrode comprises a niobium platinum plated mesh;

and

wherein said working electrode comprises a niobium platinum plated mesh.

23. A method as recited in claim 21:

wherein said potentiostat is adapted to apply alternating current at varying frequencies to said working electrode and measure voltage at said counter-reference electrode;

measuring voltage at said counter reference electrode; and

calculating impedance from said measured voltage.

24. A method as recited in claim 21, further comprising coupling said first, second chamber to a non-horizontal coating.

25. A method as recited in claim 21:

wherein said first electrode chamber comprises a first vacuum cup; and

wherein said second electrode chamber comprises a second vacuum cup.

26. An apparatus as recited in claim 25, wherein said counter reference electrode comprises stainless steel;

and

wherein said working electrode comprises stainless steel.

27. A method as recited in claim 21, wherein said electrolyte comprises a conductive gel.