Biomass Treatment Method

• US 20090050134A1
• Filed: 08/22/2007
• Published: 02/26/2009
• Est. Priority Date: 08/22/2007
• Status: Active Grant

• Current Assignee: Alliance For Sustainable Energy LLC, Sustainable Technology Corporation
• Original Assignee: Alliance For Sustainable Energy LLC
• Inventors: Friend, Julie, Elander, Richard T., Tucker, Melvin P. III, Lyons, Robert C.
• Granted Patent: US 7,819,976 B2
• Time in Patent Office: Days
• US Class Current: 127/29
• CPC Class Codes: C08H 8/00 Macromolecular compounds derived from lignocellulosic materials pretreatment thereof B27N
• CPC Class Codes: C13K 1/02 obtained by saccharification of cellulosic materials manufacture of fodder A23K10/32
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel

Abstract

A method for treating biomass was developed that uses an apparatus which moves a biomass and dilute aqueous ammonia mixture through reaction chambers without compaction. The apparatus moves the biomass using a non-compressing piston. The resulting treated biomass is saccharified to produce fermentable sugars.

Claims

1. A method for treating biomass comprising:

a) providing biomass;

b) loading the biomass of (a) using a non-compacting feeder into an apparatus comprising;

i) a cylindrical barrel having a first end fitted with a piston and a second end fitted with a discharge valve;

ii) optionally, an offset attached at one offset end to the cylindrical barrel near the cylindrical barrel first end, and having a sealable valve at the unattached offset end;

iii) at least 2 sealable ports in the cylindrical barrel or in the offset;

iv) optionally, a valve in the cylindrical barrel dividing the barrel into separate first and second chambers, said first chamber having the barrel first end fitted with said piston, and said second chamber having the barrel second end with the discharge valve; and

v) a flash tank attached to the discharge valve at the second end of the barrel;

wherein said biomass is loaded into the cylindrical barrel or optionally into said offset attached to said cylindrical barrel;

c) closing off said cylindrical barrel and offset, if present;

d) optionally applying vacuum via at least one port in the cylindrical barrel;

e) adding through said at least one port in the cylindrical barrel or offset an aqueous solution comprising ammonia in an amount that is less than about 12 weight percent relative to dry weight of biomass in the barrel, creating a biomass and aqueous ammonia mixture, and further wherein the dry weight of biomass is at a high solids concentration of at least about 15 weight percent relative to the weight of the biomass and aqueous ammonia mixture, and adding steam through said second port in the cylindrical barrel or offset, if present, to reach a temperature inside the barrel that is between about 85°

C. and about 180°

C.;

f) closing the ports in the cylindrical barrel and offset, if present, to provide an impermeable chamber;

g) holding the biomass and aqueous ammonia mixture in the impermeable chamber at suitable temperature for a time that is between about 30 seconds and about 4 hours;

h) optionally moving the biomass and aqueous ammonia mixture to a second chamber in the cylindrical barrel, if present, by displacement with said piston wherein the biomass is not compacted, and holding it for a time that is between about 2 minutes and 4 hours; and

i) moving the biomass and aqueous ammonia mixture with said piston through the impermeable cylindrical barrel of (g) or (h) through the discharge valve into the flash tank;

wherein treated biomass is produced.

3. The method of claim 1 wherein one or more of steps (a), (b), (c), (d), (e), (f), (g), and (h) are repeated at least once prior to (i).

5. The method of claim 1 or 2 wherein no de-compaction step is included.

6. The method of claim 1 or 2 wherein the aqueous ammonia is between about 4% and about 6% relative to dry weight of biomass.

7. The method of claim 1 or 2 wherein the dry weight of biomass is at least about 20% relative to the weight of the creating a biomass and aqueous ammonia mixture.

8. The method of claim 7 wherein the dry weight of biomass is at least about 30% relative to the weight of the creating a biomass and aqueous ammonia mixture.

9. The method of claim 8 wherein the dry weight of biomass is at least about 50% relative to the weight of the creating a biomass and aqueous ammonia mixture.

10. The method of claim 1 or 2 wherein the suitable temperature is between about 120°

C. and about 160°

C.

11. The method of claim 10 wherein the suitable temperature is between about 140°

C. and about 150°

C.

12. The method of claim 1 or 2 wherein the non-compacting feeder of (b) is a hopper equipped with a non-compacting flow inducer.

13. The method of claim 1 or 2 wherein the first cylindrical chamber is closed with at least one valve.

14. The method of claim 13 wherein the first chamber is closed with a first valve to close off the non-compacting feeder and a second valve to close off the second chamber of (h).

15. The method of claim 1 or 2 wherein the discharge valve is a gradual expansion venturi.

16. The method of claim 1 or 2 wherein said biomass is selected from the group consisting of switchgrass, waste paper, sludge from paper manufacture, corn grain, corn cobs, corn husks, corn fiber, corn stover, grasses, wheat, wheat straw, hay, barley, barley straw, rice straw, sugar cane bagasse, sorghum, soy, components obtained from milling of grains, trees, branches, roots, leaves, wood chips, sawdust, shrubs and bushes, vegetables, fruits, flowers and animal manure.

17. The method of claim 16 wherein biomass is selected from the group consisting of corn cobs, corn stover, corn fiber, corn husks, sugar cane bagasse, sawdust, switchgrass, wheat straw, hay, rice straw, and grasses.

18. The method of claim 17 wherein biomass is selected from the group consisting of corn cobs, corn stover, corn fiber, sawdust, and sugar cane bagasse.

19. The method of claim 1 or 2 wherein said biomass is derived from multiple feedstocks.

20. The treated biomass produced by the method of claim 1 or 2.

21. The hydrolysate produced by saccharification of the treated biomass produced by the methods of claim 1 or 2.

2. A method for treating biomass comprising:

a) providing a mixture of biomass and an aqueous solution comprising ammonia wherein the dry weight of biomass is at least about 15 weight percent relative to total weight of the biomass and aqueous ammonia mixture, and the aqueous ammonia is in an amount that is less than about 12 weight percent relative to dry weight of biomass;

b) loading the biomass and aqueous ammonia mixture of (a) using a non-compacting feeder into an apparatus comprising;

i) a cylindrical barrel having a first end fitted with a piston and a second end fitted with a discharge valve;

ii) optionally, an offset attached at one offset end to the cylindrical barrel near the cylindrical barrel first end, and having a sealable valve at the unattached offset end;

iii) at least 2 sealable ports in the cylindrical barrel or in the offset;

iv) a valve in the cylindrical barrel dividing the barrel into separate first and second chambers, said first chamber having the barrel first end fitted with said piston, and said second chamber having the barrel second end with the discharge valve; and

v) a flash tank attached to the discharge valve at the second end of the barrel;

wherein said biomass is loaded into the first chamber of the cylindrical barrel or optionally into said offset attached to said cylindrical barrel;

c) closing off said first chamber in the barrel and the offset, if present;

d) optionally applying vacuum via said least one port;

e) adding through the least one first port in the first chamber or offset, if present, steam to reach a temperature inside the chamber that is between about 85°

C. and about 180°

C.;

f) closing the ports in the first chamber and offset, if present, to provide an impermeable first chamber;

g) holding the biomass and aqueous ammonia mixture in the impermeable first chamber at suitable temperature for a time that is between about 30 seconds and about 4 hours;

h) optionally, moving the biomass and aqueous ammonia mixture through an opened valve into the second chamber of the cylindrical barrel by displacement with a piston through the impermeable first chamber wherein the biomass is not compacted,

i) optionally, closing the opened valve to form a second impermeable chamber and holding the biomass and aqueous ammonia mixture for a time that is between about 2 minutes and about 4 hours; and

j) moving the biomass and aqueous ammonia mixture by displacement with a piston following step (g) or step (i) through the discharge valve into the flash tank;

wherein the biomass is not compacted and whereby treated biomass is produced.

4. The method of claim 2 wherein one or more of steps (a), (b), (c), (d), (e), (f), (g), (h) and (i) are repeated at least once prior to k).