Biomass Treatment Apparatus

• US 20090053800A1
• Filed: 08/22/2007
• Published: 02/26/2009
• Est. Priority Date: 08/22/2007
• Status: Abandoned Application

• Current Assignee: Alliance For Sustainable Energy LLC, E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: Alliance For Sustainable Energy LLC
• Inventors: Friend, Julie, Elander, Richard T., Tucker, Melvin P. III, Lyons, Robert C.
• Application Number:
  US11/843,128
• Publication Number:
  US 20090053800A1
• Time in Patent Office: Days
• US Class Current: 435/289.100
• CPC Class Codes: C12M 21/12 for producing fuels or solvents C12M21/04 takes precedence; liquid carbonaceous fuels C10L1/00, solid fuels C10L5/00
• CPC Class Codes: C12M 45/02 by mechanical forces; Stirring; Trituration; Comminuting crushing, pulverizing, disintegrating in general B02C
• CPC Class Codes: C12M 45/03 by control of the humidity or content of liquids; Drying
• CPC Class Codes: C12M 45/09 by enzymatic treatment
• CPC Class Codes: C12M 45/20 Heating; Cooling heating or cooling apparatus for laboratory uses B01L7/00
• CPC Class Codes: D21C 11/0007 Recovery of by-products, i.e. compounds other than those necessary for pulping, for multiple uses or not otherwise provided for volatile compounds obtained by decomposition of spent liquors in order to regenerate them D21C11/125; compounds obtained by fractionating the liquors in order to regenerate them D21C11/0042
• CPC Class Codes: D21C 9/007 by mechanical or physical means

Abstract

An apparatus was developed for treatment of biomass in which reactants are added to biomass and the biomass mixture is moved through the apparatus without compacting under force of a non-compacting piston. Treatment systems used in this reactor result in effectively treated biomass that is particularly suitable for subsequent saccharification to produce fermentable sugars.

Claims

1. An apparatus for treating biomass comprising, in combination:

a) a cylindrical barrel having a first end fitted with a piston and a second end fitted with a discharge valve;

b) optionally, an offset attached at one offset end to the cylindrical barrel near the cylindrical barrel first end, and said offset having a sealable valve at the unattached offset end;

c) at least 2 sealable ports in the cylindrical barrel or in the offset;

d) optionally, a valve in the cylindrical barrel dividing the barrel into separate first and second chambers, said first chamber having the barrel first end fitted with said piston, and said second chamber having the barrel second end with the discharge valve; and

e) a flash tank attached to the discharge valve at the second end of the barrel;

wherein said apparatus provides for a sealable impermeable barrel and non-compacting flow of treated biomass.

2. The apparatus of claim 1, wherein the cylindrical barrel is oriented horizontally and a downward directed elbow, having a first and second end within the flash tank, is attached to the discharge valve at the second end of the barrel, with the first elbow end surrounding the discharge valve in the second end of the barrel, and the second elbow end opening within the flask tank.

3. The apparatus of claim 1 wherein the barrel is covered by an insulation jacket, a steam jacket, band heaters, or a combination thereof.

4. The apparatus of claim 1 wherein the optional offset of (b) is present and a hopper is connected to the valve end of the offset.

5. The apparatus of claim 4 wherein the hopper is attached to a non-compacting flow inducer.

6. The apparatus of claim 1 wherein the discharge valve is a gradual expansion venturi.

7. The apparatus of claim 6 wherein the gradual expansion venturi is a V-port valve or a swingcheck valve.

8. The apparatus of claim 1 wherein the flash tank of (e) comprises at least one sealable port in the bottom of the flash tank.

9. The apparatus of claim 1 wherein a paddle mixer is attached at the bottom of the flash tank.

10. The apparatus of claim 1 wherein the flash tank of (e) comprises at least one sealable port in the top of the flash tank.

11. The apparatus of claim 10 wherein a condenser is attached through tubing to said port in the top of the flash tank.

12. A method for treating biomass in the apparatus of claim 1 comprising:

a) loading biomass using a non-compacting feeder into the cylindrical barrel through the open first end or the offset;

b) fitting the piston;

c) optionally applying vacuum via at least one port in the cylindrical barrel;

d) adding at least one reactant other than steam via at least one port in the cylindrical barrel or offset;

e) adding steam via at least one port in the cylindrical barrel to reach a suitable temperature inside the barrel;

f) sealing the ports of c), d), and e) and all valves to provide an impermeable chamber;

g) allowing said biomass and at least one reactant to react for a time that is between about 30 seconds and about 4 hours; and

h) opening the discharge valve and moving the reacted biomass from step (g) from the impermeable chamber by displacement with the piston into the flash tank;

wherein steps a) and b) may be in either order, wherein d) and e) may be in any order or concurrent, and whereby non-compacted treated biomass is produced.

13. The method of claim 12, wherein:

i) the cylindrical barrel comprises a valve dividing the barrel into separate first and second chambers, said first chamber having the barrel first end fitted with said piston, and said second chamber having the barrel second end with the discharge valve;

ii) said valve is closed in step (f) whereby said first chamber is rendered impermeable;

iii) step (g) occurs in said first impermeable chamber; and

iv) prior to step (h), the biomass product from the impermeable first chamber is moved into said second chamber by displacement with the piston and held in said second chamber for a time that is about 2 minutes to about 4 hours, wherein said biomass is not compacted.

14. The method of claim 12 or 13 wherein no de-compaction step is included.

15. The method of claim 12 or 13 wherein the dry weight of biomass in (g) is at a high solids concentration of at least about 15% relative to the weight of biomass, reactant and steam mixture.

16. The method of claim 15 wherein the dry weight of biomass in (g) is at a high solids concentration of at least about 20% relative to the weight of biomass, reactant and steam mixture.

17. The method of claim 16 wherein the dry weight of biomass in (g) loaded is at a high solids concentration of at least about 30% relative to the weight of biomass, reactant and steam mixture.

18. The method of claim 12 wherein the suitable temperature is between about 85°

C. and about 300°

C.

19. The method of claim 18 wherein the temperature is between about 120°

C. and about 210°

C.

20. The method of claim 12 or 13 wherein said biomass is selected from the group consisting of switchgrass, waste paper, sludge from paper manufacture, corn grain, corn cobs, corn husks, corn stover, corn fiber, grasses, wheat, wheat straw, hay, barley, barley straw, rice straw, sugar cane bagasse, sorghum, soy, components obtained from milling of grains, trees, branches, roots, leaves, wood chips, sawdust, shrubs and bushes, vegetables, fruits, flowers and animal manure.

21. The method of claim 20 wherein biomass is selected from the group consisting of corn cobs, corn stover, corn fiber, corn husks, sugar cane bagasse, sawdust, switchgrass, wheat straw, hay, rice straw, and grasses.

22. The method of claim 21 wherein biomass is selected from the group consisting of corn cobs, corn stover, corn fiber, sawdust, and sugar cane bagasse.

23. The method of claim 12 or 13 wherein said biomass is derived from multiple feedstocks.

24. The method of claim 12 or 13 wherein said biomass is premixed with at least one reactant.

25. The method of claim 12 or 13 wherein the reactant is selected from the group consisting of base, acid, organosolvent, oxidizing agent, steam and combinations of base, acid, organosolvent, oxidizing agent, and steam.

26. The treated biomass produced by the method of claim 12 or 13.

27. The hydrolysate produced by saccharification of the treated biomass produced by the methods of claim 12 or 13.