PHOSPHOR AND USE THEREOF

• US 20090066230A1
• Filed: 05/24/2006
• Published: 03/12/2009
• Est. Priority Date: 05/24/2005
• Status: Active Grant

• Current Assignee: Independent Administrative Institution National Institute For Materials Science, Mitsubishi Chemical Corporation (Mitsubishi Chemical Group Corp.)
• Original Assignee: IND Admin INS National Institute For Materials SCI, Mitsubishi Chemical Corporation (Mitsubishi Chemical Group Corp.)
• Inventors: Hirosaki, Naoto, Kijima, Naoto, Seto, Takatoshi
• Granted Patent: US 8,206,611 B2
• Time in Patent Office: Days
• US Class Current: 313/504
• CPC Class Codes: C01B 21/0602 with two or more other elements chosen from metals, silicon or boron
• CPC Class Codes: C01B 21/0821 Oxynitrides of metals, boron or silicon
• CPC Class Codes: C01B 21/0823 Silicon oxynitrides
• CPC Class Codes: C01B 21/0826 Silicon aluminium oxynitrides, i.e. sialons
• CPC Class Codes: C04B 2235/3208 Calcium oxide or oxide-forming salts thereof, e.g. lime
• CPC Class Codes: C04B 2235/3217 Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
• CPC Class Codes: C04B 2235/3224 Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
• CPC Class Codes: C04B 2235/3229 Cerium oxides or oxide-forming salts thereof
• CPC Class Codes: C04B 2235/3418 Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
• CPC Class Codes: C04B 2235/3852 Nitrides, e.g. oxynitrides, carbonitrides, oxycarbonitrides, lithium nitride, magnesium nitride
• CPC Class Codes: C04B 2235/386 Boron nitrides
• CPC Class Codes: C04B 2235/3865 Aluminium nitrides
• CPC Class Codes: C04B 2235/3878 Alpha silicon nitrides
• CPC Class Codes: C04B 2235/3895 Non-oxides with a defined oxygen content, e.g. SiOC, TiON
• CPC Class Codes: C04B 2235/40 Metallic constituents or additives not added as binding phase
• CPC Class Codes: C04B 2235/401 Alkaline earth metals
• CPC Class Codes: C04B 2235/402 Aluminium
• CPC Class Codes: C04B 2235/428 Silicon
• CPC Class Codes: C04B 2235/46 Gases other than oxygen used as reactant, e.g. nitrogen used to make a nitride phase
• CPC Class Codes: C04B 2235/5409 expressed by specific surface values
• CPC Class Codes: C04B 2235/5445 : submicron sized, i.e. from 0,1 to 1 micron
• CPC Class Codes: C04B 2235/656 : characterised by specific heating conditions during heat treatment
• CPC Class Codes: C04B 2235/6562 : Heating rate
• CPC Class Codes: C04B 2235/6582 : Hydrogen containing atmosphere
• CPC Class Codes: C04B 2235/761 : Unit-cell parameters, e.g. lattice constants
• CPC Class Codes: C04B 35/581 : based on aluminium nitride
• CPC Class Codes: C04B 35/593 : obtained by pressure sintering
• CPC Class Codes: C04B 35/597 : based on silicon oxynitride, e.g. SIALONS
• CPC Class Codes: C04B 35/6262 : of calcined, sintered clinker or ceramics
• CPC Class Codes: C09K 11/0883 : Arsenides; Nitrides; Phosphides
• CPC Class Codes: C09K 11/77218 : Silicon Aluminium Nitrides or Silicon Aluminium Oxynitrides
• CPC Class Codes: C09K 11/77348 : Silicon Aluminium Nitrides or Silicon Aluminium Oxynitrides
• CPC Class Codes: C09K 11/77928 : Silicon Aluminium Nitrides or Silicon Aluminium Oxynitrides
• CPC Class Codes: H01L 2224/48091 : Arched
• CPC Class Codes: H01L 2224/48247 : connecting the wire to a bond pad of the item
• CPC Class Codes: H01L 2224/73265 : Layer and wire connectors
• CPC Class Codes: H01L 2924/00014 : the subject-matter covered by the group, the symbol of which is combined with the symbol of this group, being disclosed without further technical details
• CPC Class Codes: H01L 33/502 : Wavelength conversion materials

Abstract

A phosphor which emits light having high brightness, serves as an excellent orange or red phosphor whose light brightness is less decreased when exposed to an excitation source contains a crystal phase having the chemical composition expressed by the general formula [1]:

(1−a−b)(Ln′_pM^II′_1−pM^III′M^IV′N₃)·a(M^IV′_(3n+2)/4N_nO)·b(AM^IV′₂N₃)  [1]

• • wherein Ln′ represents a metal element selected from the group consisting of lanthanoids, Mn, and Ti; Mn^II′ represents a divalent metal element except the Ln′ element; M^III′ represents a trivalent metal element; M^IV′ represents a tetravalent metal element; A represents a metal element selected from the group consisting of Li, Na, and K; 0<p≦0.2; 0≦a, 0≦b, a+b>0, 0≦n, and 0.002≦(3n+2)a/4≦0.9.

Claims

1. A nitride or oxynitride phosphor containing a divalent alkaline earth metal element and a divalent to tetravalent rare-earth metal element, wherein, the nitride or oxynitride phosphor corresponding to the following i) and/or ii):

i) the alkaline earth metal element is substituted by an element having a lower valence than the alkaline earth metal element and/or a vacancy; and

ii) the rare-earth metal element is substituted by an element having a lower valence than the rare-earth metal element and/or a vacancy.

2. The nitride or oxynitride phosphor according to claim 1, wherein the nitrogen ions contained in the phosphor are substituted by oxygen ions.

3. The nitride or oxynitride phosphor according to claim 1, which contains a monovalent or zerovalent alkaline earth metal element, and a divalent rare-earth element.

39. A light emitting device comprising a first illuminant which emits light having a wavelength of 330 nm to 500 nm, and a second illuminant which emits visible light upon irradiation with light from the first illuminant, wherein the second illuminant contains the phosphor according to claim 1.

42. The light emitting device according to claim 39, wherein the first illuminant is a laser diode or light emitting diode.

45. The light emitting device according to claim 42, wherein the first illuminant is a light emitting diode which emits light having a wavelength of 330 nm to 420 nm, and the second illuminant is composed of the red phosphor according to claim 1, a blue phosphor which emits fluorescence exhibiting an emission peak in the wavelength from 420 nm to 500 nm upon excitation with light having a wavelength of 330 nm to 420 nm, and a green phosphor which emits fluorescence exhibiting an emission peak in the wavelength from 500 nm to 570 nm upon excitation with light having a wavelength of 330 nm to 420 nm, and the red, green, and blue light are mixed thereby producing white light.

48. The light emitting device according to claim 42, wherein the first illuminant is a light emitting diode which emits light having a wavelength of 420 nm to 500 nm, and the blue light emitted from the light emitting diode is mixed with light emitted from the phosphor according to claim 1 upon excitation with a light from the first illuminant thereby producing white light.

51. The light emitting device according to claim 42, wherein the first illuminant is a light emitting diode which emits light having a wavelength of 420 nm to 500 nm, the second illuminant is composed of the phosphor according to claim 1, and a green phosphor which emits fluorescence exhibiting an emission peak in the wavelength from 500 nm to 570 nm upon excitation with light having a wavelength of 420 nm to 500 nm, and thus the light emitting device emits a white light.

54. The light emitting device according to claim 42, wherein the first illuminant is a light emitting diode which emits light having a wavelength of 420 nm to 500 nm, the second illuminant is composed of the phosphor according to claim 1, and a yellow phosphor which emits fluorescence exhibiting an emission peak in the wavelength from 550 nm to 600 nm upon excitation with light having a wavelength of 420 nm to 500 nm, and thus the light emitting device emits a white light.

57. A lighting system comprising the light emitting device according to claim 39.

60. A display having an excitation source and a phosphor, wherein the phosphor includes at least the phosphor according to claim 1.

63. The display according to claim 60, wherein the excitation source is vacuum ultraviolet light having a wavelength of 100 nm to 190 nm, ultraviolet light having a wavelength of 190 nm to 380 nm, or an electron beam.

66. The display according to claim 63, wherein the phosphor is composed of the phosphor according to claim 1, a blue phosphor which emits a blue fluorescence upon excitation with the excitation source, and a green phosphor which emits a green fluorescence upon excitation with the excitation source.

69. A display comprising the light emitting device according to claim 39.

72. The display according to claim 60, wherein the display is a vacuum fluorescent display (VFD), a field emission display (FED), a plasma display panel (PDP), or a cathode ray tube (CRT).

75. The display according to claim 69, wherein the display is a vacuum fluorescent display (VFD), a field emission display (FED), a plasma display panel (PDP), or a cathode ray tube (CRT).

78. A phosphor mixture comprising the phosphor according to claim 1.

81. A phosphor-containing composition comprising the phosphor according to claim 1 and a liquid medium.

84. A pigment comprising the phosphor according to claim 1.

87. An ultraviolet absorbing agent comprising the phosphor according to claim 1.

4. A phosphor containing a crystal phase having the chemical composition expressed by the general formula [1]:

(1−

a−

b)(Ln′

_pM^II′

<sub>1−

p</sub>M^III′

M^IV′

N₃)·

a(M^IV′

_(3n+2)/4N_nO)·

b(AM^IV′

₂N₃) 

 

[1]

wherein in the general formula [1], Ln′

is at least one metal element selected from the group consisting of lanthanoids, Mn, and Ti;

Mn^II′

represents one or more elements selected from the group consisting of divalent metal elements except the Ln′

element;

M^III′

represents one or more elements selected from the group consisting of trivalent metal elements;

M^IV′

represents one or more elements selected from the group consisting of tetravalent metal elements;

A represents one or more monovalent metal elements selected from the group consisting of Li, Na, and K;

p satisfies 0<

p≦

0.2; and

a, b, and n satisfy 0≦

a, 0≦

b, a+b>

0, 0≦

n, and 0.002≦

(3n+2)a/4≦

0.9.

5. The phosphor according to claim 4, wherein the crystal structure of the crystal phase has a space group Cmc2₁ or P2₁.

6. The phosphor according to claim 4, wherein in the general formula [1], M^II′

includes Ca and Sr at a ratio of 80 mol % or more in total.

7. The phosphor according to claim 4, wherein in the general formula [1], M^II′

is Ca, M^II′

is Al, and M^IV is Si.

8. The phosphor according to claim 4, which is a mixture of a crystal phase having the chemical composition expressed by the general formula [1], a crystal phase having a crystal structure different from that of said crystal phase (hereinafter referred to as “

other crystal phase”

), and/or an amorphous phase, wherein the proportion of the crystal phase having the chemical composition expressed by the general formula [1] in the mixture is 20% by mass or more.

9. The phosphor according to claim 8, wherein the other crystal phase and/or the amorphous phase is a conductive inorganic substance.

10. The phosphor according to claim 9, wherein the conductive inorganic substance is an oxide, oxynitride, nitride, or mixture thereof containing one or more elements selected from the group consisting of Zn, Al, Ga, In, and Sn.

11. The phosphor according to claim 8, wherein the other crystal phase and/or the amorphous phase is an inorganic phosphor having a chemical composition different from the chemical composition expressed by the general formula [1].

12. The phosphor according to claim 4, wherein fluorescence exhibiting a peak in the wavelength from 550 nm to 700 nm is emitted upon irradiation with an excitation source.

13. The phosphor according to claim 12, wherein the excitation source is ultraviolet light or visible light having a wavelength of 100 nm to 570 nm.

14. The phosphor according to claim 4, wherein the general formula [1] is a crystal phase having the chemical composition expressed by the general formula [10]:

(Eu_yLn″

_wM^II<sub>1−

y−

w</sub>M^IIIM^IVN₃)<sub>1−

x</sub>(M^IV<sub>(3−

+2)/4</sub>N_nO)_x 

 

[10]

wherein in the general formula [10], Ln″

is at least one metal element selected from the group consisting of lanthanoids except Eu, Mn, and Ti;

M^II represents divalent metal elements including Mg, Ca, Sr, Ba, and Zn at a ratio of 90 mol % or more in total;

M^III represents trivalent metal elements including Al at a ratio of 80 mol % or more;

M^IV represents tetravalent metal elements including Si at a ratio of 90 mol % or more;

y satisfies 0<

y≦

0.2;

w satisfies 0≦

w<

0.2;

x satisfies 0<

x≦

0.45;

n satisfies 0≦

n; and

n and x satisfy 0.002≦

(3n+2)x/4≦

0.9.

15. The phosphor according to claim 14, wherein the general formula [10] is a crystal phase having the chemical composition expressed by the general formula [11]:

(Eu_yM^II<sub>1−

y</sub>M^IIIM^IVN₃)<sub>1−

x</sub>(M^IV_(3n+2)/4N_nO)_x 

 

[11]

wherein in the general formula [11], M^II represents divalent metal elements including Mg, Ca, Sr, Ba, and Zn at a ratio of 90 mol % or more in total;

M^III represents trivalent metal elements including Al at a ratio of 80 mol % or more;

M^IV represents tetravalent metal elements including Si at a ratio of 90 mol % or more;

y satisfies 0.0001≦

y≦

0.1;

x satisfies 0≦

x≦

0.45;

n satisfies 0≦

n; and

n and x satisfy 0.002≦

(3n+2)x/4≦

0.9.

16. The phosphor according to claim 14, wherein in the general formula [10], M^II includes Ca and Sr at a ratio of 80 mol % or more in total.

17. The phosphor according to claim 15, wherein in the general formula [11], M^II includes Ca and Sr at a ratio of 80 mol % or more in total.

18. The phosphor according to claim 14, wherein in the general formula [10], x satisfies 0.2≦

x≦

0.4, and n and x satisfy 0.4≦

(3n+2)x/4≦

0.8.

19. The phosphor according to claim 15, wherein in the general formula [11], x satisfies 0.2≦

x≦

0.4, and n and x satisfy 0.4≦

(3n+2)x/4≦

0.8.

20. The phosphor according to claim 14, wherein in the general formula [10], M^II is Ca, M^III is Al, and M^IV is Si.

21. The phosphor according to claim 15, wherein in the general formula [11], M^II is Ca, M^III is Al, and M^IV is Si.

22. The phosphor according to claim 4, wherein the general formula [1] is expressed by the general formula [21]:

(Ce_yLn_zM^II<sub>1−

y−

z</sub>M^IIIM^IVN₃)<sub>1−

x</sub>(M^IV_(3n+2)/4N_nO)_x 

 

[21]

wherein in the general formula [21], Ln is at least one metal element selected from the group consisting of lanthanoids except Ce, Mn, and Ti;

M^II represents divalent metal elements including Mg, Ca, Sr, Ba, and Zn at a ratio of 90 mol % or more in total;

M^III represents trivalent metal elements including Al at a ratio of 80 mol % or more;

M^IV represents tetravalent metal elements including Si at a ratio of 90 mol % or more;

x satisfies 0≦

x≦

0.45;

y satisfies 0<

y≦

0.2;

z satisfies 0≦

z≦

0.2;

n satisfies 0≦

n; and

n and x satisfy 0.002≦

(3n+2)x/4≦

0.9.

23. The phosphor according to claim 22, wherein in the general formula [21], M^II includes Ca and Sr at a ratio of 80 mol % or more in total.

24. The phosphor according to claim 22, wherein in the general formula [21], x satisfies 0.15≦

x≦

0.3, and n and x satisfy 0.3≦

(3n+2)x/4≦

0.6.

25. The phosphor according to claim 22, wherein in the general formula [21], M^II is Ca, M^III is Al, and M^IV is Si.

26. The phosphor according to claim 4, wherein the general formula [1] is expressed by the general formula [30]:

(Eu_yLn″

_wM^II<sub>1−

y−

w</sub>M^IIIM^IVN₃)<sub>1−

x′</sub>

(AM^IV₂N₃)_x′

 

 

[30]

wherein in the general formula [30], Ln″

is at least one metal element selected from the group consisting of lanthanoids except Eu, Mn, and Ti;

M^II represents divalent metal elements including Mg, Ca, Sr, Ba, and Zn at a ratio of 90 mol % or more in total;

M^III represents trivalent metal elements including Al at a ratio of 80 mol % or more;

M^IV represents tetravalent metal elements including Si at a ratio of 90 mol % or more;

A represents one or more metal elements selected from Li, Na, and K;

x′

satisfies 0<

x′

<

1.0;

y satisfies 0<

y≦

0.2; and

w satisfies 0≦

w≦

0.2.

27. The phosphor according to claim 26, wherein the general formula [30] is expressed by the general formula [31]:

(Eu_yM^II<sub>1−

y</sub>M^IIIM^IVN₃)<sub>1−

x′</sub>

(AM^IV₂N₃)_x′

 

 

[31]

wherein in the general formula [31], M^II represents divalent metal elements including Mg, Ca, Sr, Ba, and Zn at a ratio of 90 mol % or more in total;

M^III represents trivalent metal elements including Al at a ratio of 80 mol % or more;

M^IV represents tetravalent metal elements including Si at a ratio of 90 mol % or more;

A represents one or more metal elements selected from the group consisting of Li, Na, and K;

x′

satisfies 0<

x′

<

0.5; and

y satisfies 0<

y≦

0.2.

28. The phosphor according to claim 26, wherein in the general formula [30], M^II includes Ca and Sr at a ratio of 80 mol % or more in total.

29. The phosphor according to claim 27, wherein in the general formula [31], M^II includes Ca and Sr at a ratio of 80 mol % or more in total.

30. The phosphor according to claim 26, wherein in the general formula [30], x′

satisfies 0.03<

x′

≦

0.35.

31. The phosphor according to claim 27, wherein in the general formula [31], x′

satisfies 0.03<

x′

≦

0.35.

32. The phosphor according to claim 26, wherein in the general formula [30], M^II is Ca, M^III is Al, and M^IV is Si.

33. The phosphor according to claim 27, wherein in the general formula [31], M^II is Ca, M^III is Al, and M^IV is Si.

34. The phosphor according to claim 4, wherein the general formula [1] is expressed by the general formula [41]:

(Ce_yLn_zM^II<sub>1−

y−

z</sub>M^III_M^IVN₃)<sub>1−

x′</sub>

(AM^IV₂N₃)_x′

 

 

[41]

wherein in the general formula [41], Ln is at least one metal element selected from the group consisting of lanthanoids except Ce, Mn, and Ti;

M^II represents divalent metal elements including Mg, Ca, Sr, Ba, and Zn at a ratio of 90 mol % or more in total;

M^III represents trivalent metal elements including Al at a ratio of 80 mol % or more;

M^IV represents tetravalent metal elements including Si at a ratio of 90 mol % or more;

A represents one or more metal elements selected from the group consisting of Li, Na, and K;

x′

satisfies 0<

x′

<

1.0;

y satisfies 0<

y≦

0.2; and

z satisfies 0≦

z≦

0.2.

35. The phosphor according to claim 34, wherein in the general formula [41], M^II includes Ca and Sr at a ratio of 80 mol % or more in total.

36. The phosphor according to claim 34, wherein in the general formula [41], x′

satisfies 0.03≦

x′

≦

0.35.

37. The phosphor according to claim 34, wherein in the general formula [41], M^II is Ca, M^III is Al, and M^IV is Si.

40. A light emitting device comprising a first illuminant which emits light having a wavelength of 330 nm to 500 nm, and a second illuminant which emits visible light upon irradiation with light from the first illuminant, wherein the second illuminant contains the phosphor according to claim 4.

43. The light emitting device according to claim 40, wherein the first illuminant is a laser diode or light emitting diode.

46. The light emitting device according to claim 43, wherein the first illuminant is a light emitting diode which emits light having a wavelength of 330 nm to 420 nm, and the second illuminant is composed of the red phosphor according to claim 4, a blue phosphor which emits fluorescence exhibiting an emission peak in the wavelength from 420 nm to 500 nm upon excitation with light having a wavelength of 330 nm to 420 nm, and a green phosphor which emits fluorescence exhibiting an emission peak in the wavelength from 500 nm to 570 nm upon excitation with light having a wavelength of 330 nm to 420 nm, and the red, green, and blue light are mixed thereby producing white light.

49. The light emitting device according to claim 43, wherein the first illuminant is a light emitting diode which emits light having a wavelength of 420 nm to 500 nm, and the blue light emitted from the light emitting diode is mixed with light emitted from the phosphor according to claim 4 upon excitation with a light from the first illuminant thereby producing white light.

52. The light emitting device according to claim 43, wherein the first illuminant is a light emitting diode which emits light having a wavelength of 420 nm to 500 nm, the second illuminant is composed of the phosphor according to claim 4, and a green phosphor which emits fluorescence exhibiting an emission peak in the wavelength from 500 nm to 570 nm upon excitation with light having a wavelength of 420 nm to 500 nm, and thus the light emitting device emits a white light.

55. The light emitting device according to claim 43, wherein the first illuminant is a light emitting diode which emits light having a wavelength of 420 nm to 500 nm, the second illuminant is composed of the phosphor according to claim 4, and a yellow phosphor which emits fluorescence exhibiting an emission peak in the wavelength from 550 nm to 600 nm upon excitation with light having a wavelength of 420 nm to 500 nm, and thus the light emitting device emits a white light.

58. A lighting system comprising the light emitting device according to claim 40.

61. A display having an excitation source and a phosphor, wherein the phosphor includes at least the phosphor according to claim 4.

64. The display according to claim 61, wherein the excitation source is vacuum ultraviolet light having a wavelength of 100 nm to 190 nm, ultraviolet light having a wavelength of 190 nm to 380 nm, or an electron beam.

67. The display according to claim 64, wherein the phosphor is composed of the phosphor according to claim 4, a blue phosphor which emits a blue fluorescence upon excitation with the excitation source, and a green phosphor which emits green fluorescence upon excitation with the excitation source.

70. A display comprising the light emitting device according to claim 40.

73. The display according to claim 61, wherein the display is a vacuum fluorescent display (VFD), a field emission display (FED), a plasma display panel (PDP), or a cathode ray tube (CRT).

76. The display according to claim 70, wherein the display is a vacuum fluorescent display (VFD), a field emission display (FED), a plasma display panel (PDP), or a cathode ray tube (CRT).

79. A phosphor mixture comprising the phosphor according to claim 4.

82. A phosphor-containing composition comprising the phosphor according to claim 4 and a liquid medium.

85. A pigment comprising the phosphor according to claim 4.

88. An ultraviolet absorbing agent comprising the phosphor according to claim 4.

38. A phosphor containing an alkaline earth metal element, silicon, and nitrogen, wherein an inorganic compound having the same crystal structure as that of the phosphor (except for a solid solution of the phosphor) is solid-dissolved.

41. A light emitting device comprising a first illuminant which emits light having a wavelength of 330 nm to 500 nm, and a second illuminant which emits visible light upon irradiation with light from the first illuminant, wherein the second illuminant contains the phosphor according to claim 38.

44. The light emitting device according to claim 41, wherein the first illuminant is a laser diode or light emitting diode.

47. The light emitting device according to claim 44, wherein the first illuminant is a light emitting diode which emits light having a wavelength of 330 nm to 420 nm, and the second illuminant is composed of the red phosphor according to claim 38, a blue phosphor which emits fluorescence exhibiting an emission peak in the wavelength from 420 nm to 500 nm upon excitation with light having a wavelength of 330 nm to 420 nm, and a green phosphor which emits fluorescence exhibiting an emission peak in the wavelength from 500 nm to 570 nm upon excitation with light having a wavelength of 330 nm to 420 nm, and the red, green, and blue light are mixed thereby producing white light.

50. The light emitting device according to claim 44, wherein the first illuminant is a light emitting diode which emits light having a wavelength of 420 nm to 500 nm, and the blue light emitted from the light emitting diode is mixed with light emitted from the phosphor according to claim 38 upon excitation with a light from the first illuminant thereby producing white light.

53. The light emitting device according to claim 44, wherein the first illuminant is a light emitting diode which emits light having a wavelength of 420 nm to 500 nm, the second illuminant is composed of the phosphor according to claim 38, and a green phosphor which emits fluorescence exhibiting an emission peak in the wavelength from 500 nm to 570 nm upon excitation with light having a wavelength of 420 nm to 500 nm, and thus the light emitting device emits a white light.

56. The light emitting device according to claim 44, wherein the first illuminant is a light emitting diode which emits light having a wavelength of 420 nm to 500 nm, the second illuminant is composed of the phosphor according to claim 38, and a yellow phosphor which emits fluorescence exhibiting an emission peak in the wavelength from 550 nm to 600 nm upon excitation with light having a wavelength of 420 nm to 500 nm, and thus the light emitting device emits a white light.

59. A lighting system comprising the light emitting device according to claim 41.

62. A display having an excitation source and a phosphor, wherein the phosphor includes at least the phosphor according to claim 38.

65. The display according to claim 62, wherein the excitation source is vacuum ultraviolet light having a wavelength of 100 nm to 190 nm, ultraviolet light having a wavelength of 190 nm to 380 nm, or an electron beam.

68. The display according to claim 65, wherein the phosphor is composed of the phosphor according to claim 38, a blue phosphor which emits blue fluorescence upon excitation with the excitation source, and a green phosphor which emits green fluorescence upon excitation with the excitation source.

71. A display comprising the light emitting device according to claim 41.

74. The display according to claim 62, wherein the display is a vacuum fluorescent display (VFD), a field emission display (FED), a plasma display panel (PDP), or a cathode ray tube (CRT).

77. The display according to claim 71, wherein the display is a vacuum fluorescent display (VFD), a field emission display (FED), a plasma display panel (PDP), or a cathode ray tube (CRT).

80. A phosphor mixture comprising the phosphor according to claim 38.

83. A phosphor-containing composition comprising the phosphor according to claim 38 and a liquid medium.

86. A pigment comprising the phosphor according to claim 38.

89. An ultraviolet absorbing agent comprising the phosphor according to claim 38.