Non-Aqueous Slurries Used as Thickeners and Defoamers

• US 20090071369A1
• Filed: 11/25/2008
• Published: 03/19/2009
• Est. Priority Date: 01/20/2005
• Status: Abandoned Application

• Current Assignee: Sherwin-Williams Company
• Original Assignee: Sherwin-Williams Company
• Inventors: Sweitzer, Gerald M., Walker, Joseph K., Ragone, Pietro J., Martuch, Robert A.
• Application Number:
  US12/277,524
• Publication Number:
  US 20090071369A1
• Time in Patent Office: Days
• US Class Current: 106/169.10
• CPC Class Codes: C08J 2300/00 Characterised by the use of unspecified polymers
• CPC Class Codes: C08J 3/11 from solid polymers
• CPC Class Codes: C08K 3/36 Silica
• CPC Class Codes: C08K 5/01 Hydrocarbons C08K5/0091 takes precedence
• CPC Class Codes: C08L 1/28 Alkyl ethers
• CPC Class Codes: C08L 1/284 with hydroxylated hydrocarbon radicals
• CPC Class Codes: C09D 5/04 Thixotropic paints
• CPC Class Codes: C09D 7/43 Thickening agents

Abstract

A low VOC, HAPs free, substantially non-aqueous slurry for use as a rheology modifier in aqueous systems including but not limited to latex paints. The slurry comprises a particulate water-swelling polymer such as hydroxyethyl cellulose, mineral oil carrier liquid, a non-ionic surfactant, a particulate thickening agent, a defoamer, and optionally an amine component.

Claims

1. A slurry, adapted to modify the rheology of a latex paint composition, comprising:

(a) from about 40% to about 45%, based on the total weight of the slurry, of a particulate water-swelling polymer having a molecular weight of about 100,000 to about 20 million;

(b) from about 20% to about 30%, based on the total weight of the slurry, of a mineral oil carrier vehicle which is a non-solvent for the water-swelling polymer;

(c) from about 20% to about 30%, based on the total weight of the slurry, of a mineral oil based defoamer, wherein the defoamer prevents hard settling of the particulate water-swelling polymer;

(d) from about 2% to about 4%, based on the total weight of the slurry, of a non-ionic surfactant having an HLB value of about 8-12; and

(e) from about 0.15% to 0.25% based on the total weight of the slurry of a particulate thickening agent;

wherein the slurry is stable for at least seven weeks.

2. The slurry of claim 1 further comprising about 0.1% to about 2% based on the total weight of the slurry, of an amine.

3. The slurry of claim 2 wherein the amine is selected from 2-amino-2-methyl-1-propanol, ammonium hydroxide, monoethanolamine, diethanolamine, N,N dimethylethanolamine, or triethanolamine.

4. The slurry of claim 1 wherein the defoamer comprises mineral oil treated with hydrophobic silica.

5. The slurry of claim 1 wherein the particulate water-swelling polymer comprises hydroxyethyl cellulose.

6. The slurry of claim 1 wherein the particulate water-swelling polymer is selected from the group consisting of hydroxyethyl cellulose, carboxy methyl cellulose, hydroxylpropyl methyl cellulose, hydroxylpropyl cellulose, methylcellulose, hydroxylethyl ethylcellulose, methylethyl hydroxyethyl cellulose, ethoxylated cellulose, cellulose ether, cellulose acetate, cellulose acetate propronate, cellulose tricetate, cellulose nitrate, microcrystalline cellulose, hydroxypropyl guar, guar gum, polyacrylic polymer, carboxyvinyl polymer, hydrophobically modified polyacrylic polymer, alkali-swellable polyacrylate, polyquatemium-10, xantham gum, colodial magnesium aluminum silicate, and acrylic copolymer.

7. A slurry composition comprising:

(a) polymer particles capable of swelling in the presence of water, wherein said polymer particles are suspended in a hydrocarbon carrier liquid, wherein the hydrocarbon carrier liquid is present in sufficient amounts to coat the polymer particles;

(b) a defoamer composition, wherein said defoamer composition is present in an amount sufficient to provide a slurry that is stable for at least seven weeks;

(c) fumed silica;

(d) a non-ionic surfactant.

8. The slurry of claim 7, wherein the polymer particles capable of swelling in the presence of water are selected from the group consisting of hydroxyethyl cellulose, carboxy methyl cellulose, hydroxylpropyl methyl cellulose, hydroxylpropyl cellulose, methylcellulose, hydroxylethyl ethylcellulose, methylethyl hydroxyethyl cellulose, ethoxylated cellulose, cellulose ether, cellulose acetate, cellulose acetate propronate, cellulose tricetate, cellulose nitrate, microcrystalline cellulose, hydroxypropyl guar, guar gum, polyacrylic polymer, carboxyvinyl polymer, hydrophobically modified polyacrylic polymer, alkali-swellable polyacrylate, polyquaternium-10, xantham gum, colodial magnesium aluminum silicate, and acrylic copolymer.

9. The slurry of claim 7, wherein the polymer particles are hydroxyethyl cellulose.

10. The slurry of claim 7, wherein the defoamer comprises mineral oil treated with hydrophobic silica.

11. A composition adapted to modify the rheological properties of an aqueous system, upon dilution with water, the composition comprising:

(a) polymer particles which swell in the presence of water;

(b) a water-insoluble, non-oxygenated, liquid carrier which is a non-solvent for said polymer particles;

(c) a non-ionic surfactant present in sufficient amounts to allow said polymer particles to substantially disperse in the aqueous system prior to swelling;

(d) a thickening agent present in amounts sufficient to retard settling of the polymer particles in the composition; and

(e) a defoamer, wherein said defoamer is adapted to be active upon dilution of the composition with water, and wherein said defoamer is present in an amount sufficient to prevent hard settling of the polymer particles,

wherein the polymer particles remain suspended in the liquid carrier during storage.

12. The composition of claim 11 wherein said polymer particles are selected from the group consisting of hydroxyethyl cellulose, carboxy methyl cellulose, hydroxylpropyl methyl cellulose, hydroxylpropyl cellulose, methylcellulose, hydroxylethyl ethylcellulose, methylethyl hydroxyethyl cellulose, ethoxylated cellulose, cellulose ether, cellulose acetate, cellulose acetate propronate, cellulose tricetate, cellulose nitrate, microcrystalline cellulose, hydroxypropyl guar, guar gum, polyacrylic polymer, carboxyvinyl polymer, hydrophobically modified polyacrylic polymer, alkali-swellable polyacrylate, polyquatemium-10, xantham gum, colodial magnesium aluminum silicate, and acrylic copolymer.

13. The composition of claim 11 wherein said polymer particles are hydroxyethyl cellulose.

14. The composition of claim 11 wherein the liquid carrier comprises mineral oil.

15. The composition of claim 11 wherein the defoamer comprises a mineral oil based defoamer.

16. The composition of claim 11 wherein the surfactant has an HLB value of about 8-12.