Antimicrobial cidality formulations with residual efficacy, uses thereof, and the preparation thereof

• US 20090074881A1
• Filed: 11/05/2008
• Published: 03/19/2009
• Est. Priority Date: 05/02/2006
• Status: Abandoned Application

• Current Assignee: Yclean Enterprises LLC
• Original Assignee: BioNeutral Laboratories Corp. USA (Bioneutral Group Inc.)
• Inventors: Kielbania, Andrew J. JR.
• Application Number:
  US12/290,918
• Publication Number:
  US 20090074881A1
• Time in Patent Office: Days
• US Class Current: 424/616
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 37/02 Saturated carboxylic acids or thio analogues thereof; Derivatives thereof
• CPC Class Codes: A01N 37/10 Aromatic or araliphatic carboxylic acids, or thio analogues thereof; Derivatives thereof
• CPC Class Codes: A01N 37/36 containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
• CPC Class Codes: A01N 59/00 Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
• CPC Class Codes: A01N 59/14 Boron; Compounds thereof
• CPC Class Codes: A01N 59/16 Heavy metals; Compounds thereof

Abstract

The present invention is a quick-kill formulation that is able to kill organisms such as bacteria, viruses, fungi, mold, spore-forming bacteria and combinations thereof. In addition, the formulation contains a residual kill component that is effective for at least one day. The unique formulation is effective without being corrosive. This is an advantage that allows it to be used in a wide range of applications, one application being in the medical field for sterilizing instruments. Another improvement of this formulation over the prior art is that it is stabilized such that, unlike prior art formulations, tap water, as opposed to distilled water, may be used in its manufacture.

Claims

1. A composition, comprising:

a quick kill component, wherein the quick kill component is able to kill organisms selected from the group consisting of bacteria, viruses, fungi, mold, spore-forming bacteria and combinations thereof, and

a residual kill component, wherein the residual component has a residual efficacy against spores or bacteria or viruses for at least one day.

2. The composition of claim 1, wherein the quick kill component includes a peroxy based composition.

3. The composition of claim 1, wherein the residual kill component includes a component having silver, boron, copper, or combinations thereof.

4. The composition of claim 1, wherein the residual kill component has residual efficacy against aspergillus niger spores for at least one day.

5. The composition of claim 1, wherein the residual kill component has residual efficacy against aspergillus niger spores for at least two days.

6. The composition of claim 1, wherein the residual kill component has residual efficacy against aspergillus niger spores for at least three days.

7. The composition of claim 1, wherein the composition is effective to exhibit a time to kill of 5 minutes or less and preferably a time to kill of 1 minute or less against each of Staphylococcus aureus ATCC 6538, Escherichia coli ATCC 8739 when diluted 1 to 2 with a 4% human protein broth.

8. The composition of claim 1, wherein the composition is an antimicrobial composition.

9. The composition of claim 1, wherein the composition is an anti-corrosion composition.

13. The composition of claim 1, wherein the surfactant is about 0.1% to about 2% dodecylbenzene sulfonic acid.

21. The composition of claim 10, wherein a. The antimicrobial composition of claim 1 which comprises about 0.1% dodecylbenzene sulfonic acid, about 2% citric acid, about 2% hydrogen peroxide, about 0.6% peracetic acid and about 1000 parts per million (ppm) silver nitrate.

29. The composition of claim 1 which comprises about 0.1% dodecylbenzene sulfonic acid, about 0.01% citric acid, about 9.0% hydrogen peroxide, about 0.6% peracetic acid, about 0.3% benzoic acid, 5.0% boric acid, 0.5% silver nitrate and about 10.0% butyl cellusolve.

30. The composition of claim 1 which comprises about 0.1% dodecylbenzene sulfonic acid, about 4.3% citric acid, about 5.2% hydrogen peroxide, about 0.5% peracetic acid and about 0.006% silver nitrate.

10. A composition, comprising:

at least one surfactant present in a concentration from about 0.01% to about 80% by weight;

an acid or acid salt present in a concentration of from about 0.01% to about 20% by weight;

at least one peroxide in a concentration of from about 0.01% to about 55% by weight;

at least one peracid in a concentration of from about 0.01% to about 30% by weight;

at least one source of silver, boron or copper salt, or combinations thereof in a concentration of from about 0.01% to about 10% by weight; and

the balance water.

11. The composition of claim 10, wherein the composition further comprises the use of at least one water soluble solvent in a concentration of about 0.01% to about 20%

12. The composition of claim 10, wherein the surfactant is anionic or nonionic.

14. The composition of claim 10, wherein the acid is from about 0.01% to about 5.0% citric acid.

15. The composition of claim 10, wherein the peroxide is from about 1.0 to about 10.0% hydrogen peroxide.

16. The composition of claim 10, wherein the at least one source of silver, boron or copper salt, or combinations thereof is silver and the concentration is from about 1000 ppm to about 0.5% of silver nitrate.

17. The composition of claim 10, wherein the at least one source of silver, boron or copper salt, or combinations thereof is from about 1000 ppm to about 0.5% of silver nitrate and about 2.0% to about 6.0% boric acid.

18. The composition of claim 10, wherein the peracid is about 0.05 to 6.0% peric acid.

19. The composition of claim 10, wherein the composition includes a wetting agent.

20. The composition of claim 10, wherein the water is tap water.

22. The composition of claim 10, which comprises about 0.1% dodecylbenzene sulfonic acid, about 3% citric acid, about 3% hydrogen peroxide, about 3% peracetic acid and about 1000 parts per million (ppm) silver nitrate.

23. The composition of claim 10 which comprises about 2% dodecylbenzene sulfonic acid, about 0.1% citric acid, about 2% hydrogen peroxide, about 0.6% peracetic acid and about 1000 parts per million (ppm) silver nitrate.

24. The composition of claim 10 which comprises about 0.5% dodecylbenzene sulfonic acid, about 0.01% citric acid, about 9.3% hydrogen peroxide, about 0.6% peracetic acid, about 0.2% benzoic acid, about 4% boric acid, about 10% butyl cellusolve and about 0.5% silver nitrate.

25. The composition of claim 10 which comprises about 0.5% dodecylbenzene sulfonic acid, about 0.01% citric acid, about 9.3% hydrogen peroxide, about 0.6% peracetic acid, about 0.2% benzoic acid, about 4% boric acid, about 10% butyl cellusolve and about 0.1% silver nitrate.

26. The composition of claim 10 which comprises about 0.5% dodecylbenzene sulfonic acid, about 0.01% citric acid, about 9.3% hydrogen peroxide, about 0.6% peracetic acid, about 0.2% benzoic acid, about 4% boric acid, about 10% butyl cellusolve and about 0.1% silver nitrate.

27. The composition of claim 10 which comprises about 0.1% dodecylbenzene sulfonic acid, about 0.01% citric acid, about 9.0% hydrogen peroxide, about 0.6% peracetic acid, about 0.3% benzoic acid, about 5.0% boric acid and about 10.0% butyl cellusolve.

28. The composition of claim 10 which comprises about 0.1% dodecylbenzene sulfonic acid, about 0.01% citric acid, about 9.0% hydrogen peroxide, about 0.6% peracetic acid, about 0.3% benzoic acid, 0.5% silver nitrate and about 10.0% butyl cellusolve.