Polyester moulding composition for use in electronic devices

• US 20090105381A1
• Filed: 04/21/2006
• Published: 04/23/2009
• Est. Priority Date: 05/03/2005
• Status: Abandoned Application

• Current Assignee: DSM IP Assets BV (DSM-Firmenich AG)
• Original Assignee: DSM IP Assets BV (DSM-Firmenich AG)
• Inventors: Janssen, Robert H.C., Kuijk, Egbert W., Zwartkruis, Theodorus J.G.
• Application Number:
  US11/919,645
• Publication Number:
  US 20090105381A1
• Time in Patent Office: Days
• US Class Current: 524/127
• CPC Class Codes: C08K 5/0066 Flame-proofing or flame-retarding additives
• CPC Class Codes: C08K 5/16 Nitrogen-containing compounds C08K5/0091 takes precedence
• CPC Class Codes: C08K 5/3492 Triazines
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 67/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds C08L67/06 takes precedence

Abstract

The invention relates to A polyester moulding composition consisting of (A) 100 parts by weight (pbw) of a polymer composition consisting of (A-i) at least 50 pbw of a thermoplastic polyester, and, optionally, (A-ii) at least one other polymer, (B) between 2 and 40 pbw of a flame retardant system consisting of (B-i) a nitrogen based organic flame retardant compound free of phosphorus or a phosphorus free salt thereof, and, optionally, (B-ii) less than 1 pbw of a phosphorus containing flame retardant compound, (C) between 0.01 and 1 pbw of a mould release agent, and optionally (D) 0-10 pbw of a fibrous reinforcing agent, and (E) 0-100 pbw of other additives. The invention also relates to the use of the composition for making molded parts, in particular part for use in electrical or electronic applications, and to these molded parts.

Claims

1. A polyester molding composition having a comparative tracking index (CTI) of at least 400 Volt and a glow wire ignition temperature (GWIT) of at least 775°

C. at 1.0 mm, consisting of

(A) 100 parts by weight (pbw) of a polymer composition consisting of (A-i) at least 50 pbw of a thermoplastic polyester, and, optionally, (A-ii) at least one other polymer,

(B) between 2 and 40 pbw of a flame retardant system consisting of (B-i) a nitrogen based organic flame retardant compound free of phosphorus or a phosphorus free salt thereof, and, optionally,

(B-ii) less than 1 pbw of a phosphorus containing flame retardant compound, comprising less than 0.1 pbw of an arylenedioxy-tetrakisphenyl-diphosphate and substituted and oligomeric derivatives thereof, (C) between 0.01 and 1 pbw of a mould release agent, and optionally

(D) 0-10 pbw of a fibrous reinforcing agent, and

(E) 0-100 pbw of other additives.

2. A composition according to claim 1, wherein the nitrogen containing organic flame retardant compound (B-i) is a compound selected from the group consisting melamine cyanurate and condensation products of melamine, and mixtures thereof.

3. A composition according to claim 1, wherein the nitrogen containing organic flame retardant compound (B-i) consists for at least 90 wt % of melamine cyanurate.

4. A composition according to claim 1, wherein the nitrogen containing organic flame retardant compound (B-i) is present in an amount between 5 and 25 pbw, preferably between 7.5 and 20 pbw.

5. A composition according to claim 1, wherein the flame retardant system (B) comprises less than 0.1 pbw of the phosphorus containing flame retardant compound (B-ii).

6. A composition according to claim 1, wherein the thermoplastic polyester (A-i) is PET, PTT, PBT or a mixture or a copolymer thereof.

7. A composition according to claim 1, wherein the polymer composition comprises as the other polymer (B-ii), a rubber impact modifier, a thermoplastic polymer, a compatibilizer polymer or a combination thereof.

8. A composition according to claim 1, wherein the composition comprises 0.05-0.5 pbw of the mould release agent (C)1 relative to 100 pbw of the polymer composition (A).

9. A composition according to claim 1, wherein the composition comprises 0-3 pbw of the fibrous reinforcing agent (D), relative to 100 pbw of the polymer composition (A).

10. A composition according to claim 1, wherein the at least one other additive (E) is selected from the group consisting of UV-stabilizers, heat-stabilizers, anti-oxidants, pigments, inorganic fillers, CTI improving agents and mixtures thereof.

11. A composition according to claim 1, wherein the at least one other additive (E) is present in an amount of 0-49 pbw, preferably 0-25 pbw, relative to 100 pbw of the polymer composition (A).

12. A composition according to claim 10, wherein the composition comprises the CTI improving additive in an amount of 0.01-5 pbw, preferably 0.05-1 pbw, relative to 100 pbw of the polymer composition (A).

13. Use of a composition according to claim 1 for making a molded part for use in electrical or electronic applications

14. Molded part for use in electrical or electronic applications made of a composition according to claim 1.

15. Molded part according to claim 14, wherein the molded part is a housing for an electrical circuit breaker, a switchgear, a contactor, a motor starter, or a fuse holder.

16. Molded part according to claim 14, wherein the molded part is a lamp housing or a lamp socket.

17. Electrical or electronic article, comprising a moulded part made of a composition according to claim 1.