Anti-reflection film, polarizing plate, and liquid crystal display device

• US 20090135356A1
• Filed: 09/06/2005
• Published: 05/28/2009
• Est. Priority Date: 09/13/2004
• Status: Abandoned Application

• Current Assignee: Fujifilm Corporation (Fujifilm Holdings Corporation)
• Original Assignee: Fujifilm Corporation (Fujifilm Holdings Corporation)
• Inventors: Ando, Takumi
• Application Number:
  US11/659,487
• Publication Number:
  US 20090135356A1
• Time in Patent Office: Days
• US Class Current: 349/137
• CPC Class Codes: B82Y 20/00 Nanooptics, e.g. quantum optics or photonic crystals
• CPC Class Codes: C08K 3/36 Silica
• CPC Class Codes: C08K 7/26 Silicon- containing compounds
• CPC Class Codes: C09D 7/61 inorganic
• CPC Class Codes: C09D 7/67 Particle size smaller than 100 nm
• CPC Class Codes: C09D 7/68 Particle size between 100-1000 nm
• CPC Class Codes: C09D 7/70 characterised by shape, e.g. fibres, flakes or microspheres
• CPC Class Codes: G02B 1/111 using layers comprising organic materials
• CPC Class Codes: G02B 1/14 Protective coatings, e.g. hard coatings
• CPC Class Codes: G02B 5/30 Polarising elements light-modulating devices with active elements G02F1/00
• CPC Class Codes: G02B 5/3033 in the form of a thin sheet or foil, e.g. Polaroid
• CPC Class Codes: G02F 1/133502 Antiglare, refractive index matching layers
• CPC Class Codes: G02F 2202/36 Micro- or nanomaterials
• CPC Class Codes: Y10T 428/24421 Silicon containing

Abstract

An anti-reflection film comprising: a transparent support; at least one high refractive index hard coat layer; and a low refractive index layer disposed as an outermost layer, in this order, wherein (i) the high refractive index hard coat layer has a refractive index of 1.55 or more and a thickness of 4 to 15 μm; (ii) the anti-reflection film has a surface roughness Ra (center line average roughness) of 0.10 μm or less; and (iii) the low refractive index layer comprises a hollow silica microparticle having an average particle diameter of 5 to 200 nm and a refractive index of 1.17 to 1.40.

Claims

1. An anti-reflection film comprising:

a transparent support;

at least one high refractive index hard coat layer; and

a low refractive index layer disposed as an outermost layer, in this order, wherein

(i) the high refractive index hard coat layer has a refractive index of 1.55 or more and a thickness of 4 to 15 μ

m;

(ii) the anti-reflection film has a surface roughness Ra (center line average roughness) of 0.10 μ

m or less; and

(iii) the low refractive index layer comprises a hollow silica microparticle having an average particle diameter of 5 to 200 nm and a refractive index of 1.17 to 1.40.

2. The anti-reflection film of claim 1,

wherein at least one of the hard coat layer and the low refractive index layer comprises:

(a) at least one of a hydrolysate of organosilane and a partial condensate thereof, the organosilane comprising a hydroxyl group or a hydrolyzable group directly linked with silicon; and

(b) at least one type of metal chelate compound having, as a central metal, a metal selected from Zr, Ti, and Al, and having, as ligands, an alcohol represented by a general formula R³OH (where R³ represents an alkyl group having one to ten carbon atoms) and a compound represented by a general formula R⁴COCH₂COR⁵ (where R⁴ represents an alkyl group having one to ten carbon atoms, and R⁵ represents an alkyl group having one to ten carbon atoms or an alkoxy group having one to ten carbon atoms).

3. The anti-reflection film of claim 1, further comprising:

an intermediate layer having a medium refractive index between those of the transparent support and the high refractive index hard coat layer, the intermediate layer being between the transparent support and the high refractive index hard coat layer.

4. The anti-reflection film of claim 1, wherein the transparent support is a cellulose acylate film.

5. The anti-reflection film of claim 1, wherein the hard coat layer comprises a binder and at least one type of translucent particle having a refractive index different from that of the binder.

6. The anti-reflection film of claim 1, wherein the anti-reflection film has a degree of transmission image sharpness of 60% or more.

7. The anti-reflection film of any of claim 1, wherein the hard coat layer has a haze value of 10% or more.

8. The anti-reflection film of any of claim 1, wherein, in a scattered light profile of the hard coat layer measured by a goniophotometer, an intensity of scattered light having an emission angle of 30°

is 0.01% to 0.2% of an intensity of light having an emission angle of 0°

.

9. The anti-reflection film of claim 1, wherein the hard coat layer is formed by coating a coating composition comprising at least a transparent resin and a solvent having a boiling point of 100°

C. or less, and drying.

10. The anti-reflection film of any of claim 1, wherein the hard coat layer formed by coating a coating composition comprising at least a transparent resin and a solvent, followed by drying, is dried with drying air at a flowing rate of 1 m/second or more.

11. A polarizing plate comprising a polarizing film having two surfaces sandwiched between protection films, wherein one of the protection films is the anti-reflection film of claim 1.

12. The polarizing plate of claim 11, wherein the other protection film that is not the anti-reflection film is an optical compensation film having an optically anisotropic layer, the optically anisotropic layer is a layer containing a compound having a discotic structural unit, the discotic structural unit has a disc surface inclined with respect to a surface of the protection film, and an angle made by the disc surface of the discotic structural unit and the surface of the protection film varies in a depth direction of the optically anisotropic layer.

13. A liquid crystal display device comprising the anti-reflection film of claim 1 as a top surface layer of a display.

14. A liquid crystal display device comprising the anti-reflection film of claim 1 as a top surface layer of a display having a liquid crystal cell of VA mode or IPS mode.

15. A liquid crystal display device comprising the anti-reflection film of claim 1 as a top surface layer of the display having a liquid crystal cell of OCB mode.

16. A liquid crystal display device comprising the polarizing plate of claim 11 as a top surface layer of a display.

17. A liquid crystal display device comprising the polarizing plate of claim 11 as a top surface layer of a display having a liquid crystal cell of VA mode or IPS mode.

18. A liquid crystal display device comprising the polarizing plate of claim 11 as a top surface layer of the display having a liquid crystal cell of OCB mode.