Process for preparing lube basestocks having superior low temperature properties at high VI

• US 20090166252A1
• Filed: 12/16/2008
• Published: 07/02/2009
• Est. Priority Date: 12/28/2007
• Status: Active Grant

• Current Assignee: ExxonMobil Research & Engineering Company (Exxon Mobil Corporation)
• Original Assignee: ExxonMobil Research & Engineering Company (Exxon Mobil Corporation)
• Inventors: Larkin, David W., Murphy, William J., Daage, Michel
• Granted Patent: US 8,182,672 B2
• Time in Patent Office: Days
• US Class Current: 208/64
• CPC Class Codes: B01J 2229/20 to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
• CPC Class Codes: B01J 2229/42 Addition of matrix or binder particles
• CPC Class Codes: B01J 29/74 Noble metals
• CPC Class Codes: B01J 35/0006 Catalysts containing parts with different compositions
• CPC Class Codes: B01J 35/19 Catalysts containing parts with different compositions
• CPC Class Codes: C10G 2300/1022 Fischer-Tropsch products
• CPC Class Codes: C10G 2300/1062 Lubricating oils
• CPC Class Codes: C10G 2300/202 Heteroatoms content, i.e. S, N, O, P
• CPC Class Codes: C10G 2300/207 Acid gases, e.g. H2S, COS, SO2, HCN
• CPC Class Codes: C10G 2300/4018 Spatial velocity, e.g. LHSV, WHSV
• CPC Class Codes: C10G 2400/10 Lubricating oil
• CPC Class Codes: C10G 65/043 at least one step being a change in the structural skeleton

Abstract

A process for preparing basestocks having superior low temperature properties at high viscosity index (VI). More particularly, a waxy feedstock is contacted with a first dewaxing catalyst having a refined constraint index (CI*) 2.0 or less followed by contacting with a second dewaxing catalyst having a refined constraint index greater than 2.0.

Claims

1. A two stage process for dewaxing a waxy lube feedstock which comprises:

(a) contacting a feedstock in a first dewaxing stage with at least one 1D, 10-ring molecular sieve containing catalyst having a refined constraint index of 2.0 or less under first hydroisomerizing dewaxing conditions to produce a first dewaxed product stream; and

(b) contacting said first dewaxed product stream in a second dewaxing stage with at least one 1D, 10-ring molecular sieve containing catalyst having a refined constraint index of greater than 2.0 under second hydroisomerizing dewaxing conditions to produce a dewaxed product.

2. The process of claim 1, further comprising:

Contacting a feedstock with a hydrotreating catalyst capable of converting a substantial amount of the sulfur in the feedstock to H₂S and nitrogen to NH3, under hydrotreating conditions, thereby resulting in a hydrotreated feedstock containing less sulfur than the waxy lube feedstock, based on the total weight of the feedstock; and

separating the hydrotreated feedstock from hydrogen sulfide, ammonia and any light hydrocarbons,

wherein said separated hydrotreated feedstock is contacted with the molecular sieve catalyst in said first dewaxing stage.

3. The process of claim 2, wherein the waxy lube feedstock contains from about 500 wppm to about 3.0 wt % sulfur.

4. The process of claim 2, wherein the hydrotreating catalyst is comprised of at least one Group 6 metal and at least one Group 8 metal of the IUPAC Periodic Table on a metal oxide support.

5. The process of claim 1, wherein the first hydroisomerizing dewaxing conditions comprise a temperature of 250°

C. to 400°

C., pressures of from 791 to 20786 kPa (100 to 3000 psig), liquid hourly space velocities of from 0.1 to 10 hr<sup>−

1</sup>, and hydrogen treat gas rates from 45 to 1780 m³/m³ (250 to 10000 scf/B).

6. The process of claim 1, wherein the second hydroisomerizing dewaxing conditions comprise a temperature of 250°

C. to 400°

C., pressures of from 791 to 20786 kPa (100 to 3000 psig), liquid hourly space velocities of from 0.1 to 10 hr<sup>−

1</sup>, and hydrogen treat gas rates from 45 to 1780 m³/m³ (250 to 10000 scf/B).

7. The process of claim 1, wherein the feedstock is selected from the group consisting of slack waxes, hydrocracker bottoms and Fischer-Tropsch waxes.

8. The process of claim 1, wherein the molecular sieve of the first dewaxing stage catalyst is selected from the group consisting of ZSM-48, EU-2, EU-11 and ZBM-30.

9. The process of claim 8 wherein the first dewaxing stage catalyst contains 0.1 to 5 wt % of a hydrogenation metal.

10. The process of claim 9 wherein the hydrogenation metal is selected from the group consisting of Pt and Pd.

11. The process of claim 1, wherein the molecular sieve of second dewaxing stage catalyst is selected from the group consisting of ZSM-48, ZSM-22, ZSM-23, ZSM-35 and SAPO-11.

12. The process of claim 11 wherein the second dewaxing stage catalyst contains 0.1 to 5 wt % of a hydrogenation metal.

13. The process of claim 12 wherein the hydrogenation metal is selected from the group consisting of Pt and Pd.

14. The process of claim 1, wherein the molecular sieve of the first dewaxing stage catalyst is comprised of ZSM-48, the molecular sieve of the second dewaxing stage is comprised of ZSM-23, and said first and second stage catalysts having an effective amount of a hydrogenation metal selected from the group consisting of Pt and Pd.

15. The process of claim 1, wherein the dewaxed product from the second dewaxing stage is treated with a hydrofinishing catalyst under hydrofinishing conditions.

16. The process of claim 15 wherein said hydrofinishing catalyst is comprised of at least one metal selected from Group VI or Group VIII on a metal oxide support.

17. The process of claim 16 wherein at least one of the metals of the hydrofinishing catalyst is selected from Pt and Pd.

18. The process of claim 15, wherein the hydrofinishing catalyst selected from the group consisting of MCM-41, MCM-48, and MCM-50.

19. The process of claim 1 wherein the refined constraint index for said second dewaxing stage catalyst is at least 2.5.

20. The process of claim 19 wherein the refined constraint index for said second dewaxing stage catalyst is at least 3.0.