Multilayered Catalyst Compositions

• US 20090175773A1
• Filed: 01/08/2008
• Published: 07/09/2009
• Est. Priority Date: 01/08/2008
• Status: Abandoned Application

• Current Assignee: BASF Catalysts LLC (BASF SE)
• Original Assignee: BASF Catalysts LLC (BASF SE)
• Inventors: Deeba, Michel, Rabinowitz, Harold, Chen, Shau-Lin F.
• Application Number:
  US11/970,879
• Publication Number:
  US 20090175773A1
• Time in Patent Office: Days
• US Class Current: 423/213.500
• CPC Class Codes: B01D 2255/1021 Platinum
• CPC Class Codes: B01D 2255/1023 Palladium
• CPC Class Codes: B01D 2255/1025 Rhodium
• CPC Class Codes: B01D 2255/2042 Barium
• CPC Class Codes: B01D 2255/206 Rare earth metals
• CPC Class Codes: B01D 2255/20715 Zirconium
• CPC Class Codes: B01D 2255/2092 Aluminium
• CPC Class Codes: B01D 2255/40 Mixed oxides
• CPC Class Codes: B01D 2255/407 Zr-Ce mixed oxides
• CPC Class Codes: B01D 2255/9025 Three layers
• CPC Class Codes: B01D 2255/908 O2-storage component incorporated in the catalyst
• CPC Class Codes: B01D 53/945 characterised by a specific catalyst
• CPC Class Codes: B01D 53/9472 in different zones
• CPC Class Codes: B01D 53/9477 with catalysts positioned on separate bricks, e.g. exhaust systems
• CPC Class Codes: B01J 20/3021 Milling, crushing or grinding
• CPC Class Codes: B01J 23/464 Rhodium
• CPC Class Codes: B01J 23/63 with rare earths or actinides
• CPC Class Codes: B01J 35/023 Catalysts characterised by dimensions, e.g. grain size
• CPC Class Codes: B01J 35/40 characterised by dimensions, e.g. grain size in a colloidal state B01J35/23; crystallite size B01J35/77
• CPC Class Codes: B01J 37/0036 Grinding
• CPC Class Codes: B01J 37/0244 : Coatings comprising several layers
• CPC Class Codes: B01J 37/0248 : Coatings comprising impregnated particles
• CPC Class Codes: Y02T 10/12 : Improving ICE efficiencies

Abstract

A layered, three-way conversion catalyst having the capability of simultaneously catalyzing the oxidation of hydrocarbons and carbon monoxide and the reduction of nitrogen oxides is disclosed. Engine exhaust treatment systems including such catalysts are also provided. The catalyst generally comprises three layers in conjunction with a carrier. The three layers comprise two rhodium-containing layers and one palladium-containing layer. The two rhodium layers can be adjacent to each other, or they can be separated by another precious metal-containing layer. At least one of the two layers comprising the rhodium component comprises an oxygen storage component. Methods of making and using these catalysts are also provided.

Claims

1. A layered catalyst composite comprising:

a catalytic material on a carrier, the catalytic material comprising first, second, and third layers, the first layer comprising a first precious metal selected from a first rhodium component on a first support, the second layer comprising a second precious metal selected from a second rhodium component on a second support, and the third layer comprising a third precious metal component on a third support;

wherein the catalytic material is effective to substantially simultaneously oxidize carbon monoxide and hydrocarbons and reduce nitrogen oxides.

2. The composite of claim 1, wherein the catalytic material comprises the rhodium components in amounts to provide a rhodium loading in the catalytic material in the range of 1 to 14 g/ft³.

3. The composite of claim 1, wherein at least one of the supports is an oxygen storage component comprising a stabilized ceria-zirconia composite.

4. The composite of claim 1, wherein the first layer and the second layer are adjacent to each other.

5. The composite of claim 1, wherein the third layer is located between the first layer and the second layer, and the third precious metal component comprises a palladium component.

6. The composite of claim 1, wherein the first, second, and third supports each independently comprise compound that is activated, stabilized, or both selected from the group consisting of alumina, silica, silica-alumina, alumino-silicates, alumina-zirconia, lanthana-alumina, lanthana-zirconia-alumina, baria-alumina, baria-lanthana-alumina, baria-lanthana-neodymia-alumina, alumina-chromia, and alumina-ceria.

7. The composite of claim 1, wherein the first layer, the second layer, or both further comprise a platinum component.

8. The composite of claim 1, wherein the third layer is deposited on the carrier as an inner layer, the third precious metal component comprises a palladium component;

and the third support comprising a high surface area refractory metal oxide;

the first layer is deposited on the third layer as a middle layer; and

the second layer is deposited on the first layer as an outer layer, and the second support comprises a high surface area refractory metal oxide, and the second layer further comprises an oxygen storage component.

9. The composite of claim 8, wherein

the inner layer comprises a stabilized alumina and palladium, and is substantially free of an oxygen storage component;

the middle layer comprises a stabilized alumina and is substantially free of an oxygen storage component; and

the outer layer comprises a stabilized alumina, one or more ceria-zirconia oxide composites to provide ceria in an amount in the range of 15 to 30% by weight of the layer, and rhodium.

10. The composite of claim 8, wherein

the inner layer comprises a stabilized alumina and palladium, and is substantially free of an oxygen storage component;

the middle layer comprises one or more ceria-zirconia oxide composites to provide ceria in an amount in the range of 15 to 30% by weight of the layer and rhodium, and is substantially free of an alumina component; and

the outer layer comprises a stabilized alumina;

one or more ceria-zirconia oxide composites to provide ceria in an amount in the range of 15 to 30% by weight of the layer, and rhodium.

11. The composite of claim 8, wherein

the inner layer comprises a stabilized alumina, palladium, and one or more ceria-zirconia oxide composites to provide ceria in an amount in the range of 15 to 30% by weight of the layer;

and

the middle layer and the outer layer have substantially the same composition, each comprising one or more ceria-zirconia oxide composites to provide ceria in an amount in the range of 5 to 15% by weight of the layer, rhodium, and a stabilized alumina.

12. The composite of claim 1, wherein the first layer is deposited on the carrier as an inner layer, the first support comprises a high surface area refractory metal oxide;

the third layer is deposited on the first layer as a middle layer, the third precious metal component comprises a palladium component; and

the second layer is deposited on the middle layer as an outer layer, the second support comprises a high surface area refractory metal oxide support, and the second layer further comprises an oxygen storage component.

13. The composite of claim 12, wherein

the inner layer comprises a stabilized alumina, rhodium, and one or more ceria-zirconia oxide composites to provide ceria in an amount in the range of 20 to 40% by weight of the layer;

the middle layer comprises a stabilized alumina, palladium, and one or more ceria-zirconia oxide composites to provide ceria in an amount in the range of 5 to 20% by weight of the layer; and

the outer layer comprises a stabilized alumina, rhodium, platinum, and one or more ceria-zirconia oxide composites to provide ceria in an amount in the range of 15 to 40% by weight of the layer.

14. The composite of claim 13, wherein at least one layer comprises a lanthana-stabilized alumina.

15. An exhaust gas treatment system comprising a combination of a first composite and a second composite, wherein the first composite comprises a first inner layer deposited on a first carrier comprising a palladium component and a support, a first middle layer deposited on the first inner layer, the first middle layer comprising a rhodium component and a support, and a first outer layer deposited on the first middle layer, the first outer layer comprising a palladium and a support;

and wherein the second composite comprises a second inner layer deposited on the first carrier or on a second carrier, the second inner layer comprising a rhodium component and a support, a second middle layer deposited on the second inner layer, the second middle layer comprising a palladium component and a support, and a second outer layer deposited on the second middle layer, the second outer layer comprising a rhodium component and a support.

16. The system of claim 15, wherein the first composite is located upstream of the second composite.

17. The system of claim 15, wherein the second composite is located upstream of the first composite.

18. A method for treating a gas comprising hydrocarbons, carbon monoxide, and nitrogen oxides comprising:

contacting the gas with a catalytic material on a carrier, the catalytic material comprising three layers, wherein at least two layers each comprise a rhodium component and a support, the support of one of the at least two layers comprises an oxygen storage component, and a third layer comprises a precious metal component and a support;

wherein the catalytic material is effective to substantially simultaneously oxidize the carbon monoxide and the hydrocarbons and reduce the nitrogen oxides.

19. The method of claim 18, further comprising locating the catalytic material in a close-coupled position of an exhaust gas treatment system wherein the catalytic material comprises an inner layer, a middle layer, and an outer layer, the inner layer being deposited on the carrier and comprising a first rhodium component on a first support, the middle layer being deposited on the inner layer and comprising a palladium component on a second support, and the outer layer being deposited on the middle layer and comprising a second rhodium component on a third support;

wherein the catalytic material comprises the rhodium components in amounts to provide a rhodium loading in the catalytic material in the range of 1 to 14 g/ft³, and the catalytic material comprises the palladium component in an amount to provide a palladium loading in the catalytic material in the range of 20 to 200 g/ft³.

20. The method of claim 18, further comprising locating the catalytic material in an underfloor position of an exhaust gas treatment system wherein the catalytic material comprises an inner layer, a middle layer, and an outer layer, the inner layer being deposited on the carrier and comprising a first rhodium component on a first support, the middle layer being deposited on the inner layer and comprising a palladium component on a second support, and the outer layer being deposited on the middle layer and comprising a second rhodium component on a third support;

wherein the catalytic material comprises the rhodium components in amounts to provide a rhodium loading in the catalytic material in the range of 1 to 14 g/ft³, and the catalytic material comprises the palladium component in an amount to provide a palladium loading in the catalytic material in the range of 5 to 30 g/ft³.

21. A method of making a layered catalyst composite, the method comprising providing a carrier and coating the carrier with first, second, and third layers of catalytic material;

wherein at least two layers each comprise a rhodium component, one of the at least two layers comprising the rhodium component comprises an oxygen storage component, and a third layer comprises a precious metal component and a support.

22. The method of claim 21, comprising depositing the at least two layers comprising the rhodium component adjacent to each other.

23. The method of claim 21, comprising depositing one of the at least two layers comprising the rhodium component on the carrier, depositing the third layer on the first layer, and depositing the other of the at least two layers comprising the rhodium component on the third layer.

24. A layered catalyst composite comprising:

a catalytic material on a carrier, the catalytic material comprising an inner layer, a middle layer, and an outer layer, the inner layer deposited on the carrier comprising a first rhodium component on a first support, the middle layer deposited on the inner layer comprising a palladium component on a second support, and the outer layer deposited on the middle layer comprising a second rhodium component on a third support;

wherein the catalytic material is effective to substantially simultaneously oxidize carbon monoxide and hydrocarbons and reduce nitrogen oxides;

wherein the catalytic material comprises the rhodium components in amounts to provide a rhodium loading in the catalytic material in the range of 1 to 14 g/ft³, and the catalytic material comprises the palladium component in an amount to provide a palladium loading in the catalytic material in the range of 5 to 200 g/ft³.

25. The composite of claim 24, wherein the palladium component is present in an amount to provide a palladium loading in the catalytic material in the range of 5 to 30 g/ft³.

26. The composite of claim 24, wherein the inner layer, the outer layer, or both further comprise a platinum component in an amount in the range of 1 to 6 g/ft³.