ELECTRO-CHEMICAL SENSOR

• US 20090178921A1
• Filed: 08/08/2006
• Published: 07/16/2009
• Est. Priority Date: 09/21/2005
• Status: Abandoned Application

• Current Assignee: Schlumberger Technology Corporation (Schlumberger NV)
• Original Assignee: Schlumberger Technology Corporation (Schlumberger NV)
• Inventors: Robinson, Kay Louise, Pagels, Markus, Hackett, Simon, Jiang, Li, Lawrence, Nathan
• Application Number:
  US12/067,596
• Publication Number:
  US 20090178921A1
• Time in Patent Office: Days
• US Class Current: 204/400
• CPC Class Codes: E21B 49/08 Obtaining fluid samples or testing fluids, in boreholes or wells
• CPC Class Codes: G01N 27/48 using polarography, i.e. measuring changes in current under a slowly-varying voltage

Abstract

An electro-chemical sensor is described having two molecular redox systems one being sensitive the other insensitive to the species to be detected and both being covalently bound to a polymer and having a detector to detect relative shifts in the voltammograms of the two redox systems.

Claims

1. An electro-chemical sensor comprising at least one redox system sensitive to a species to be detected and at least one redox system essentially insensitive to the species to be detected, wherein the at least two redox systems are covalently bound to an organic polymer.

2. The sensor of claim 1 wherein the at least two redox systems are bound to the same polymer.

3. The sensor of claim 1 wherein the sensed species are protons or sulfides.

4. The sensor of claim 1 wherein the at least two redox systems have a maximum or peak redox reaction at different voltages.

5. The sensor of claim 1 wherein the polymer or polymers are mounted onto the same conductive substrate.

6. The sensor of claim 4 wherein the substrate is carbon-based.

7. The sensor of claim 1 wherein the insensitive redox system has a maximum or peak redox reaction essentially insensitive to variations in the concentration of the sensed species.

8. The sensor of claim 1 comprising a detector adapted to measure the redox potential of said at least two redox system in the presence of the species and to convert measurements into an signal indicative of the concentration of said species.

10. A downhole tool for measuring characteristic parameters of wellbore effluents comprising an electrochemical sensor in accordance with claim 1.

11. A downhole formation sampling tool for measuring characteristic parameters of wellbore effluents comprising an electro-chemical sensor in accordance with claim 1.

12. A downhole tool for measuring characteristic parameters of wellbore effluents comprising an electrochemical sensor in accordance with claim 1 mounted onto a permanently installed part of the wellbore.

9. Polymer for use in an electrochemical sensor comprising at least one redox system sensitive to a species to be detected and at least one redox system essentially insensitive to the species to be detected.