Method and Device for the Absorption of Acid Gas From Natural Gas

• US 20090199712A1
• Filed: 05/23/2006
• Published: 08/13/2009
• Est. Priority Date: 06/27/2005
• Status: Abandoned Application

• Current Assignee: UHDE GmbH (Thyssenkrupp AG)
• Original Assignee: UHDE GmbH (Thyssenkrupp AG)
• Inventors: Cosfeld, Martin, Menzel, Johannes
• Application Number:
  US11/922,170
• Publication Number:
  US 20090199712A1
• Time in Patent Office: Days
• US Class Current: 95/163
• CPC Class Codes: B01D 53/1462 Removing mixtures of hydrogen sulfide and carbon dioxide
• CPC Class Codes: C10L 3/10 Working-up natural gas or synthetic natural gas
• CPC Class Codes: C10L 3/102 of acid contaminants

Abstract

A method and a device for the absorption of pressurised natural gas containing at least hydrogen sulphide and carbon dioxide, using a physically active absorption agent. The natural gas containing acid gas is first conveyed to an absorption column, where it is directly contacted with the physical detergent, and the physical detergent absorbs the acid gas, leaving only a residue. The charged detergent is conveyed to a stripping column, the working pressure being further reduced. The residue of the released acid gas from the detergent is desorbed in said stripping column. The detergent thus regenerated is returned, at least in part, to the absorption column. The acid gas leaving the first separator is conveyed to another absorption column, in which the part of the released acid gas containing predominately hydrogen sulphide is reabsorbed with regenerated detergent and mixed with the charged detergent from the first separator. The remaining acid gas not reabsorbed from the absorption column downstream of the first separator, is recovered as stripping gas. Said stripping gas is used in the stripping column for removing the hydrogen sulphide from the detergent supplied to the stripping column. The finely regenerated solvent is divided into two partial flows, one of which is conveyed to the absorption column downstream of the first separator stage while the other is conveyed to the absorption column in the flow of natural gas.

Claims

1-10. -10. (canceled)

11. A process for the absorption of pressurized natural gas containing at least hydrogen sulphide and carbon dioxide, with the aid of physically acting absorbents, comprising

piping sour gas-bearing natural gas to an absorption column in which it comes into direct contact with a physically acting washing agent, the latter absorbing the sour gas and leaving a residual sour gas content only,

feeding laden washing agent to a first separator, thereby reducing the working pressure and part of the solved sour gas being removed from the washing agent,

at least a part stream of laden washing agent again undergoing a working pressure reduction and treatment in a stripping column where the residual content of solved sour gas is removed from the washing agent,

returning at least part of thus regenerated washing agent to the absorption column,

feeding sour gas leaving the first separator to a further absorption column in which regenerated washing agent is used to re-absorb a released sour gas portion that mainly contains hydrogen sulphide and that is added to laden washing agent in the first separator,

the remaining sour gas portion not re-absorbed in the further absorption column arranged downstream of the first separator is recovered as stripping gas,

said stripping gas is utilized in a stripping column for removing the hydrogen sulphide from the washing agent fed to the stripping column, and

the intensely regenerated solvent is split up into two part streams, the first one being piped to the further absorption column arranged downstream of the first separator and the second one being fed to the absorption column arranged in the natural gas stream.

12. The process according to claim 11, wherein the washing agent leaving the first separator undergoes a working pressure reduction and is piped to the second separator prior to feeding the partly laden washing agent to the stripping column.

13. The process according to claim 11, wherein

the pressure selected for the sour gas absorption is >

50 bar,

the pressure in the first separator is in the range of 6 to 30 bar, and

the pressure selected for the stripping column is in the range of 0.2 to 3 bar.

14. The process according to claim 12, wherein the pressure in the second separator is rated in the range of 1 to 3 bar, but in any case above the pressure in the stripping column.

15. The process according to claim 11, wherein a recycle gas flash step is arranged upstream of the first separator in order to ensure a pressure reduction of the laden solvent to a value between the absorption pressure and that of the first separator, the released and co-absorbed flash gas, which also contains useful gas components, is being returned to the upstream side of the absorption column by means of a recycle compressor.

16. The process according to claim 11, wherein the laden solvent is pre-heated with the aid of a pre-heater prior to entering the stripping column.

17. The process according to claim 16, wherein the warm regenerated solvent leaving the stripping column is cooled by way of heat exchange with the laden solvent piped to the pre-heater and subsequently undergoes a secondary cooling prior to using the secondary-cooled and regenerated solution for absorption.

18. The process according to claim 11, wherein the solvent is a mixture of n-formylmorpholine and n-acetylmorpholine.

19. A device suited for the process described in claim 11, wherein the first separator and the further absorption column arranged downstream on the sour gas side form a constructional unit, the first separator being integrated into the bottom of the absorption column.

20. A device suited for the process described in claim 12, wherein the second separator and the stripping column form a constructional unit, the separator being stacked on top of the head of the stripping column and equipped with a liquid drain piping that includes a device for pressure reduction, a header for liquid fluids in the stripping column head zone, an inlet for laden washing agent in the stripping column bottom as well as withdrawing devices for sour gas in the head zone of the stripping column and in the second separator.

21. The process according to claim 13, wherein

the pressure selected for the sour gas absorption is about 70 bar, and

the pressure in first separator is about 15 bar.

22. The process according to claim 14, wherein the pressure in second separator is about 1 bar.