FUNCTIONALIZED DIAMOND PARTICLES AND METHODS FOR PREPARING THE SAME

• US 20090218276A1
• Filed: 02/29/2008
• Published: 09/03/2009
• Est. Priority Date: 02/29/2008
• Status: Abandoned Application

• Current Assignee: Brigham Young University (The Church of Jesus Christ of Latter-Day Saints)
• Original Assignee: Brigham Young University (The Church of Jesus Christ of Latter-Day Saints)
• Inventors: Linford, Matthew R., Saini, Gaurav
• Application Number:
  US12/040,638
• Publication Number:
  US 20090218276A1
• Time in Patent Office: Days
• US Class Current: 210/506
• CPC Class Codes: B01J 20/285 based on polymers
• CPC Class Codes: B01J 20/286 Phases chemically bonded to a substrate, e.g. to silica or to polymers
• CPC Class Codes: B01J 20/3204 Inorganic carriers, supports or substrates
• CPC Class Codes: B01J 20/3268 Macromolecular compounds
• CPC Class Codes: B01J 20/327 Polymers obtained by reactions involving only carbon to carbon unsaturated bonds
• CPC Class Codes: B01J 20/3272 Polymers obtained by reactions otherwise than involving only carbon to carbon unsaturated bonds
• CPC Class Codes: B01J 20/3282 Crosslinked polymers
• CPC Class Codes: B01J 2220/54 Sorbents specially adapted for analytical or investigative chromatography
• CPC Class Codes: Y10T 428/2998 including synthetic resin or polymer

Abstract

A functionalized particle is disclosed. The functionalized particle may include a diamond-particle substrate and a coating comprising at least one polymeric compound on at least a surface portion of the diamond-particle substrate, the at least one polymeric compound having at least one amine group. Additionally, the at least one polymeric compound may be at least partially reacted. The at least one polymeric compound may also be at least partially cured. The diamond substrate may be porous. In addition, a second coating coupled to at least a surface portion of the first coating. A separation apparatus may have a stationary phase including a plurality of diamond particles and a coating comprising at least one polymeric compound on at least a surface portion of the plurality of diamond particles is also disclosed. A method for forming a functionalized particle is also disclosed.

Claims

1. A functionalized particle, comprising:

a diamond-particle substrate;

a coating positioned on at least a surface portion of the diamond-particle substrate, the coating comprising at least one polymeric compound having at least one amine group;

wherein the at least one polymeric compound is at least partially, covalently reacted to form at least one carbon-nitrogen bond; and

wherein the coating is substantially stable in a 2.5 M HCl solution and a 2.5 M NaOH solution.

2. The functionalized particle of claim 1, wherein the at least one polymeric compound comprises at least one of a homopolymer and a copolymer.

3. The functionalized particle of claim 1, wherein the diamond-particle substrate is porous.

4. The functionalized particle of claim 1, wherein the diamond-particle substrate comprises a plurality of sintered diamond particles.

5. The functionalized particle of claim 1, wherein the diamond-particle substrate comprises polycrystalline diamond.

6. The functionalized particle of claim 1, wherein the at least one polymeric compound is at least partially cured to at least partially cross link the at least one polymeric compound.

7. The functionalized particle of claim 1, wherein the coating comprises the reaction product of the at least one amine group on the at least one polymeric compound and a cross-linking agent.

8. The functionalized particle of claim 1, further comprising a second compound that is coupled to the at least one amine group on the at least one polymeric compound.

9. The functionalized particle of claim 8, wherein the second compound comprises at least one of a branched alkyl chain, a straight alkyl chain, and an aromatic ring.

10. The functionalized particle of claim 1, wherein the diamond particle comprises a micron-sized diamond particle.

11. The functionalized particle of claim 1, wherein the diamond particle comprises a nanodiamond particle.

12. The functionalized particle of claim 1, wherein the at least one polymeric compound comprises at least one of polyallylamine, polyallylamine hydrochloride, polyethylenimine, polylysine, polyvinylamine, chitosan, trimethylchitosan, polydiallyldimethyl ammonium chloride, poly(N,N′

-dimethylaminoethylmethacrylate), poly(2-vinylpyridine), poly(4-vinylpyridine), polyvinylimidazole, poly(2-(dimethylamino)ethyl acrylate), poly(2-aminoethyl methacrylate) hydrochloride, and polyoxazoline.

13. The functionalized particle of claim 1, wherein the at least one polymeric compound comprises a polymeric compound formed from at least one of an allylamine monomer, a vinylamine monomer, an ethylenimine monomer, a lysine monomer, an arginine monomer, a histidine monomer, a 2-isocyanatoethyl methacrylate monomer, an aziridine monomer, a 1-vinylimidazole monomer, a 1-vinyl-2-pyrrolidone monomer, a 2-vinylpyridine monomer, a 4-vinylpyridine monomer, a 2-(dimethylamino)ethyl acrylate monomer, a 2-aminoethyl methacrylate hydrochloride monomer, and/or a 2-(tert-butylamino)ethyl methacrylate monomer, and an oxazoline monomer.

14. The functionalized particle of claim 1, wherein the at least one polymeric compound comprises a polymeric compound formed from at least one monomer comprising an amine group and at least one of a 2-hydroxyethylacrylate monomer, a styrene monomer, a 1,3-butadiene monomer, a methyl methacrylate monomer, a methyl acrylate monomer, a butyl acrylate monomer, a dodecyl methacrylate monomer, an acrylonitrile monomer, an acrylic acid monomer, a methacrylic acid monomer, a 4-vinylbenzyl chloride monomer, a 4-(trifluoromethyl)styrene monomer, a 3-nitrostyrene monomer, a vinyl ether monomer, a stearyl acrylate monomer, and a vinyl acetate monomer.

32. The functionalized particle of claim 1, wherein the amine group is a primary amine group.

33. The functionalized particle of claim 1, wherein the coating has a surface that includes at least one hydrophobic portion and at least one hydrophilic portion.

15. A functionalized particle, comprising:

a diamond-particle substrate;

a coating positioned on at least a surface portion of the diamond-particle substrate, the coating comprising at least one polymeric compound having at least one amine group;

wherein the coating is substantially stable in a 2.5 M HCl solution and a 2.5 M NaOH solution.

16. (canceled)

17. A functionalized particle, comprising:

a diamond-particle substrate;

a coating positioned on at least a surface portion of the diamond-particle substrate, the coating having a surface that includes at least one hydrophobic portion and at least one hydrophilic portion.

18. The functionalized particle of claim 17, wherein the coating comprises at least one polymeric compound having at least one amine group.

19. (canceled)

20. A separation apparatus comprising:

a stationary phase, the stationary phase comprising;

a plurality of diamond particles; and

a coating positioned on at least a surface portion of the plurality of diamond particles, the coating comprising at least one polymeric compound having at least one amine group;

wherein the at least one polymeric compound is at least partially cross linked.

21. A method for forming a functionalized particle, comprising:

depositing a coating on at least a portion of a diamond-particle substrate, the coating comprising at least one polymeric compound having at least one amine group;

cross linking at least a portion of the at least one polymeric compound during and/or after the coating has been deposited on at least a portion of the diamond-particle substrate.

22. The method of claim 21, wherein cross linking at least a portion of the at least one polymeric compound includes curing at least a portion of the at least one polymeric compound.

23. The method of claim 21, wherein cross linking at least a portion of the at least one polymeric compound further comprises reacting the at least one amine group with a cross-linking agent.

24. The method of claim 21, wherein at least a portion of the at least one polymeric compound is cross linked prior to depositing the coating on at least a portion of the diamond-particle substrate.

25. The method of claim 21, further comprising sintering a plurality of diamond particles to form the diamond-particle substrate, wherein the formed diamond-particle substrate is porous.

26. The method of claim 21, further comprising oxidizing at least a portion of the diamond-particle substrate.

27. The method of claim 21, further comprising coupling a second compound to the at least one amine group on the at least one polymeric compound.

28. A method for forming a functionalized particle, comprising:

depositing a coating on at least a portion of a diamond-particle substrate, the coating comprising at least one polymeric compound having at least one amine group;

curing the coating to cross link at least a portion of the at least one polymeric compound.

29. The method of claim 28, wherein curing the coating comprises exposing the coating to at least one of heat, radiation, and UV light.

30. A method for forming a functionalized particle, comprising:

depositing a coating on at least a portion of a diamond-particle substrate;

reacting the coating to form a surface that includes at least one hydrophobic portion and at least one hydrophilic portion.

31. The method of claim 30, wherein reacting the coating includes cross linking at least one polymeric compound in the coating.

34. A method of separating a mixture comprising:

passing a sample through a stationary phase, the stationary phase comprising;

a plurality of diamond particles; and

a coating positioned on at least a surface portion of the plurality of diamond particles, the coating comprising at least one polymeric compound having at least one amine group;

wherein the at least one polymeric compound is at least partially cross linked.

35. The method of claim 34, wherein the method is a solid phase extraction method.