BIO-BASED POLYETHYLENE TEREPHTHALATE POLYMER AND METHOD OF MAKING SAME
First Claim
1. A bio-based polyethylene terephthalate polymer comprisingfrom about 25 to about 75 weight percent of a terephthalate component, wherein the terephthalate component is selected from terephthalic acid, dimethyl terephthalate, isophthalic acid, and a combination thereof, andfrom about 20 to about 50 weight percent of a diol component, wherein the diol component is selected from ethylene glycol, cyclohexane dimethanol, and a combination thereof,wherein at least about one weight percent of at least one of the terephthalate and/or the diol component is derived from at least one bio-based material.
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Abstract
A bio-based polyethylene terephthalate polymer comprising from about 25 to about 75 weight percent of a terephthalate component and from about 20 to about 50 weight percent of a diol component, wherein at least about one weight percent of at least one of the terephthalate and/or the diol component is derived from at least one bio-based material. A method of producing a bio-based polyethylene terephthalate polymer comprising obtaining a diol component comprising ethylene glycol, obtaining a terephthalate component comprising terephthalic acid, wherein at least one of the diol component and/or the diol component is derived from at least one bio-based material, and reacting the diol component and the terephthalate component to form a bio-based polyethylene terephthalate polymer comprising from about 25 to about 75 weight percent of the terephthalate component and from about 20 to about 50 weight percent of the diol component.
93 Citations
29 Claims
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1. A bio-based polyethylene terephthalate polymer comprising
from about 25 to about 75 weight percent of a terephthalate component, wherein the terephthalate component is selected from terephthalic acid, dimethyl terephthalate, isophthalic acid, and a combination thereof, and from about 20 to about 50 weight percent of a diol component, wherein the diol component is selected from ethylene glycol, cyclohexane dimethanol, and a combination thereof, wherein at least about one weight percent of at least one of the terephthalate and/or the diol component is derived from at least one bio-based material.
- 11. A bio-based container comprising a bio-based polyethylene terephthalate polymer, wherein at least one weight percent of the polyethylene terephthalate polymer is derived from at least one bio-based material, wherein the bio-based container has an intrinsic viscosity from about 0.45 dL/g to about 1.0 dL/g.
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18. A method of producing a bio-based polyethylene terephthalate polymer comprising
a. obtaining a diol component comprising ethylene glycol; -
b. obtaining a terephthalate component comprising terephthalic acid, wherein at least one of the diol and/or the terephthalate component is derived from at least one bio-based material; and c. reacting the diol component and the terephthalate component to form a bio-based polyethylene terephthalate polymer, wherein the bio-based polyethylene terephthalate polymer comprises from about 25 to about 75 weight percent of the terephthalate component and from about 20 to about 50 weight percent of the diol component. - View Dependent Claims (19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29)
ii. fermenting sugar or derivatives thereof to ethanol; iii. dehydrating ethanol to ethylene; iv. oxidizing ethylene to ethylene oxide; and v. converting ethylene oxide to ethylene glycol.
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24. The method of claim 18, wherein step (a) further comprises
i. obtaining sugar or derivatives thereof from at least one bio-based material; -
ii. reacting sugar or derivatives to form a mixture comprising ethylene glycol and at least one glycol excluding the ethylene glycol; and iii. separating ethylene glycol from the mixture.
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25. The method of claim 18, wherein step (b) further comprises
i. obtaining carene from at least one bio-based material; -
ii. converting carene to cymene; and iii. oxidizing cymene to terephthalic acid.
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26. The method of claim 18, wherein step (b) further comprises
i. obtaining limonene from at least one bio-based material; -
ii. converting the limonene to at least one terpene; iii. converting the at least one terpene to cymene; and iv. oxidizing cymene to terephthalic acid.
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27. The method of claim 18, further comprising adding a supplemental component to the bio-based polyethylene terephthalate polymer, wherein the supplement component is selected from at least one coloring agent, at least one fast reheat additive, at least one gas barrier additive, at least one UV blocking additive, and a combination thereof.
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28. The bio-based polyethylene terephthalate polymer produced by the method of claim 18.
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29. A container comprising the bio-based polyethylene terephthalate polymer of claim 26.
Specification