HYDROGEN GENERATOR

• US 20090252670A1
• Filed: 03/09/2009
• Published: 10/08/2009
• Est. Priority Date: 04/07/2008
• Status: Active Grant

• Current Assignee: Honeywell International Inc.
• Original Assignee: Honeywell International Inc.
• Inventors: Eickhoff, Steven J., Zhang, Chunbo
• Granted Patent: US 8,187,348 B2
• Time in Patent Office: Days
• US Class Current: 423/648.100
• CPC Class Codes: C01B 3/065 from a hydride
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

A hydrogen generator includes a container with multiple concentric hollow cylinders of chemical hydride fuel disposed within the container. A water vapor source is disposed within the container and operable to deliver water vapor to the cylinders of chemical hydride fuel. Generated hydrogen is provided via a hydrogen output port formed in the container.

Claims

1. A hydrogen generator comprising:

a container;

a multiple concentric hollow cylinders of chemical hydride fuel disposed within the container;

a water vapor source disposed within the container and operable to deliver water vapor to the cylinders of chemical hydride fuel; and

a hydrogen output port formed in the container.

2. The hydrogen generator of claim 1 wherein the hollow cylinders of chemical hydride fuel are substantially round.

3. The hydrogen generator of claim 1 wherein the generator comprises three concentric hollow cylinders of chemical hydride.

4. The hydrogen generator of claim 1 wherein the hydrogen vapor source comprises:

a water reservoir; and

wicking material extending into the water reservoir and disposed adjacent the hollow cylinders of chemical hydride to provide water vapor.

5. The hydrogen generator of claim 4 and further comprising water impermeable, water vapor and hydrogen permeable membranes disposed between the wicking material and the hollow cylinders of chemical hydride.

6. The hydrogen generator of claim 4 wherein the wicking material comprises a first wicking material extending into the water reservoir and a second wicking material in fluid contact with the first wicking material and extending adjacent the hollow cylinders of chemical hydride.

7. The hydrogen generator of claim 4 and further comprising air gaps between the membranes and the hollow cylinders of chemical hydride, wherein the air gaps are formed to provide diffusion of the water vapor and transport of generated hydrogen.

8. The hydrogen generator of claim 7 and further comprising a pressure release valve coupled to the air gaps and operable to maintain hydrogen pressure in the container at or below a predetermined pressure.

9. The hydrogen generator of claim 5 and further comprising perforated metal supports coupled to membranes and positioned to support the membrane, confine the hollow cylinders of chemical hydride, and transfer heat generated during reaction of the chemical hydride with water vapor.

10. The hydrogen generator of claim 1 wherein the hollow cylinders of chemical hydride are formed a with grain size of from approximately 1 to 100 μ

m.

11. A pressurized hydrogen generator comprising:

a pressure container;

a multiple concentric hollow cylinders of chemical hydride fuel disposed within the container;

a water reservoir within a smallest hollow cylinder of chemical hydride fuel;

a wicking structure coupled to the water reservoir and extending along sides of the multiple concentric hollow cylinders of chemical hydride fuel to provide water vapor to the fuel; and

water impermeable and hydrogen and water vapor permeable membranes separating the wicking structure from each of the multiple concentric hollow cylinders of chemical hydride fuel; and

a hydrogen output port.

12. The pressurized hydrogen generator of claim 11 wherein the hollow cylinders of chemical hydride fuel are substantially round.

13. The pressurized hydrogen generator of claim 11 wherein the generator comprises three concentric hollow cylinders of chemical hydride.

14. The pressurized hydrogen generator of claim 11 and further comprising air gaps between the membranes and the hollow cylinders of chemical hydride, wherein the air gaps are formed to provide diffusion of the water vapor and transport of generated hydrogen.

15. The pressurized hydrogen generator of claim 14 and further comprising a pressure release valve coupled to the air gaps and operable to maintain hydrogen pressure in the container at or below a predetermined pressure.

16. The pressurized hydrogen generator of claim 11 and further comprising perforated metal supports coupled to the membranes and positioned to support the membranes, confine the hollow cylinders of chemical hydride, and transfer heat generated during reaction of the chemical hydride with water vapor.

17. The pressurized hydrogen generator of claim 11 wherein the hollow cylinders of chemical hydride are formed a with grain size of from approximately 1 to 100 μ

m.

18. A method comprising:

adding water to a hydrogen generator;

wicking the water proximate multiple concentric hollow cylinders of a chemical hydride hydrogen producing fuel;

allowing water vapor to pass from the wicked water to the hydrogen producing fuel; and

providing hydrogen via an output port.

19. The method of claim 18 and further comprising venting hydrogen when the pressure of hydrogen within the generator exceeds a predetermined pressure.

20. The method of claim 18 wherein the chemical hydride is formed with a grain size of from approximately 1 to 100 μ

m.