WATER-INSOLUBLE COLORANT DISPERSION AND PRODUCTION METHOD THEREOF, AND RECORDING LIQUID, INK SET, PRINTED ARTICLE, IMAGE-FORMING METHOD AND IMAGE-FORMING APPARATUS USING THE SAME

• US 20090263635A1
• Filed: 04/21/2009
• Published: 10/22/2009
• Est. Priority Date: 04/21/2008
• Status: Abandoned Application

• Current Assignee: Fujifilm Corporation (Fujifilm Holdings Corporation)
• Original Assignee: Fujifilm Corporation (Fujifilm Holdings Corporation)
• Inventors: SANO, Satoshi, ONO, Michio
• Application Number:
  US12/427,385
• Publication Number:
  US 20090263635A1
• Time in Patent Office: Days
• US Class Current: 428/195.100
• CPC Class Codes: C08J 3/03 in aqueous media
• CPC Class Codes: C08K 5/0041 Optical brightening agents, organic pigments
• CPC Class Codes: C09B 67/0066 Aqueous dispersions of pigments containing only dispersing agents
• CPC Class Codes: C09B 67/009 polymeric dispersing agent
• CPC Class Codes: C09B 67/0096 Purification; Precipitation; Filtration
• CPC Class Codes: C09D 11/326 characterised by the pigment dispersant
• CPC Class Codes: Y10T 428/24802 Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]

Abstract

A method of producing a water-insoluble colorant dispersion, having the steps of:

• • providing a solution of a water-insoluble colorant dissolved in an aprotic water-soluble organic solvent in the presence of an alkali,
  • providing an aqueous medium of a polymer compound dissolved therein, which polymer compound has at least one acid group selected from the group consisting of a carboxylic acid group, a sulfonic acid group, a hydroxyl group, and a phosphoric acid group, as its hydrophilic group, and
  • bringing the solution and the aqueous medium in contact with each other, to form fine particles of the water-insoluble colorant in a medium including water, thereby obtaining a dispersion including the fine particles dispersed therein.

Claims

1. A method of producing a water-insoluble colorant dispersion, comprising the steps of:

providing a solution of a water-insoluble colorant dissolved in an aprotic water-soluble organic solvent in the presence of an alkali,

providing an aqueous medium of a polymer compound dissolved therein, which polymer compound has at least one acid group selected from the group consisting of a carboxylic acid group, a sulfonic acid group, a hydroxyl group, and a phosphoric acid group, as its hydrophilic group, and

bringing the solution and the aqueous medium in contact with each other, to form fine particles of the water-insoluble colorant in a medium including water, thereby obtaining a dispersion comprising the fine particles dispersed therein.

2. The method of producing a water-insoluble colorant dispersion as claimed in claim 1, wherein the polymer compound is water-insoluble but is water-soluble in the presence of alkali.

3. The method of producing a water-insoluble colorant dispersion as claimed in claim 1, wherein the polymer compound has at least one repeating unit represented by formula (I):

wherein W represents a single bond or a divalent linking group selected from the group consisting of —

CO—

, —

COO—

, —

CONR₈—

, —

OCO—

, and an arylene group;

L₁ represents a single bond or a divalent linking group, R₁ to R₈ each independently represents a hydrogen atom or a substituent;

Z₁ represents any one of the carboxylic acid group, the sulfonic acid group, the hydroxyl group and the phosphoric acid group; and

m and n each represents a copolymerization ratio.

4. The method of producing a water-insoluble colorant dispersion as claimed in claim 1, wherein either or both of the alkalis contained in the solution of the water-soluble colorant and in the aqueous medium is an organic base.

5. The method of producing a water-insoluble colorant dispersion as claimed in claim 1, further comprising the steps of:

forming flocculated aggregates of the fine particles of the water-insoluble colorant, said flocculated aggregates being flocculated and capable of being re-dispersed;

separating the flocculated aggregates from the dispersion;

disaggregating the flocculated aggregates; and

re-dispersing the fine particles into a re-dispersion medium.

6. The method of producing a water-insoluble colorant dispersion as claimed in claim 1, further comprising the step of:

adding an alkali in the re-dispersing step of the fine particles into the re-dispersion medium by disaggregating the flocculated aggregates.

7. The method of producing a water-insoluble colorant dispersion as claimed in claim 1, wherein the re-dispersion medium is an aqueous dispersion containing water.

8. The method of producing a water-insoluble colorant dispersion as claimed in claim 1, further comprising the step of:

heating the dispersion.

9. A dispersion of a water-insoluble colorant obtained by the method as claimed in claim 1, comprising the fine particles of the water-insoluble colorant, the alkali, and the polymer compound having an acid group.

10. The dispersion of a water-insoluble colorant as claimed in claim 9, wherein the average particle diameter of the fine particles containing the water-insoluble colorant is from 5 to 60 nm.

11. The dispersion of a water-insoluble colorant as claimed in claim 9, wherein the water-insoluble colorant is a pigment.

12. The dispersion of a water-insoluble colorant as claimed in claim 9, wherein the water-insoluble colorant is an organic pigment selected from the group consisting of quinacridone compound pigments, diketopyrrolopyrrole compound pigments, mono azo yellow organic pigments, condensed azo organic pigments, quinophthalone compound pigments, benz-imidazolone compound pigments, and disazo yellow pigments.

13. The dispersion of a water-insoluble colorant as claimed in claim 9, wherein the water-insoluble colorant is an organic pigment selected from the group consisting of quinacridone compound pigments, diketopyrrolopyrrole compound pigments, and azo yellow organic pigments.

14. The dispersion of a water-insoluble colorant as claimed in claim 9, wherein the water-insoluble colorant is an azo yellow organic pigment.

15. A recording liquid produced by using the dispersion of a water-insoluble colorant as claimed in claim 9, wherein the water-insoluble colorant is contained in an amount of 0.1 to 20% by mass with respect to a total mass of the recording liquid.

16. The recording liquid as claimed in claim 15, wherein the recording liquid is an inkjet recording liquid.

17. An ink set, comprising the recording liquid as claimed in claim 15.

18. A printed article having an image recorded thereon by a provider of, with a medium, the recording liquid as claimed in claim 15, wherein the provider has a function to adjust an applied amount or concentration of the recording liquid, thereby light-to-dark contrast of the printed article is adjusted.

19. A printed article having an image recorded thereon by a provider of, with a medium, the recording liquid by using the ink set as claimed in claim 17, wherein the provider has a function to adjust an applied amount or concentration of the recording liquid, thereby light-to-dark contrast of the printed article is adjusted.

20. An image-forming method, which comprises:

providing, with a medium, the recording liquid as claimed in claim 15; and

recording an image with the recording liquid.

21. An image-forming method, which comprises:

providing, with a medium, the recording liquid by using the ink set as claimed in claim 17; and

recording an image with the recording liquid.

22. An image-forming apparatus, having a recorder of an image, by providing, with a medium, the recording liquid as claimed in claim 15.

23. An image-forming apparatus, having a recorder of an image, by providing, with a medium, the recording liquid by using the ink set as claimed in claim 17.

24. A dispersion of a water-insoluble colorant obtained by the method as claimed in claim 1, wherein the fine particles containing the water-insoluble colorant show a color same as to that shown by the fine particles themselves in the state of crystals thereof, and wherein when the absorbance peak of the dispersion in a visible light region is set to 1, a light scattering intensity is 30,000 cps or less.

25. The dispersion of a water-insoluble colorant as claimed in claim 24, wherein the average particle diameter of the fine particles containing the water-insoluble colorant is from 5 to 60 nm.

26. The dispersion of a water-insoluble colorant as claimed in claim 24, wherein the water-insoluble colorant is a pigment.

27. The dispersion of a water-insoluble colorant as claimed in claim 24, wherein the water-insoluble colorant is an organic pigment selected from the group consisting of quinacridone compound pigments, diketopyrrolopyrrole compound pigments, mono azo yellow organic pigments, condensed azo organic pigments, quinophthalone compound pigments, benz-imidazolone compound pigments, and disazo yellow pigments.

28. The dispersion of a water-insoluble colorant as claimed in claim 24, wherein the water-insoluble colorant is an organic pigment selected from the group consisting of quinacridone compound pigments, diketopyrrolopyrrole compound pigments, and azo yellow organic pigments.

29. The dispersion of a water-insoluble colorant as claimed in claim 24, wherein the water-insoluble colorant is an azo yellow organic pigment.

30. A recording liquid produced by using the dispersion of a water-insoluble colorant as claimed in claim 24, wherein the water-insoluble colorant is contained in an amount of 0.1 to 20% by mass with respect to a total mass of the recording liquid.

31. The recording liquid as claimed in claim 30, wherein the recording liquid is an inkjet recording liquid.

32. An ink set, comprising the recording liquid as claimed in claim 30.

33. A printed article having an image recorded thereon by a provider of, with a medium, the recording liquid as claimed in claim 30, wherein the provider has a function to adjust an applied amount or concentration of the recording liquid, thereby light-to-dark contrast of the printed article is adjusted.

34. A printed article having an image recorded thereon by a provider of, with a medium, the recording liquid by using the ink set as claimed in claim 32, wherein the provider has a function to adjust an applied amount or concentration of the recording liquid, thereby light-to-dark contrast of the printed article is adjusted.

35. An image-forming method, which comprises:

providing, with a medium, the recording liquid as claimed in claim 30; and

recording an image with the recording liquid.

36. An image-forming method, which comprises:

providing, with a medium, the recording liquid by using the ink set as claimed in claim 32; and

recording an image with the recording liquid.

37. An image-forming apparatus, having a recorder of an image, by providing, with a medium, the recording liquid as claimed in claim 30.

38. An image-forming apparatus, having a recorder of an image, by providing, with a medium, the recording liquid by using the ink set as claimed in claim 32.