Method for Reducing Fouling of Coker Furnaces
First Claim
1. A method for reducing furnace fouling in a delayed coking process wherein at least one coker feed is supplied to a delayed coking unit comprised of a coker furnace, at least two coke drums and a coker fractionator comprising(a) increasing the aromaticity of the feed to produce a modified stream by combining with the feed upstream of the coker furnace at least one added stream selected from the group consisting of an aromatic gas oil, a hydrotreated aromatic gas oil and combinations thereof, said aromatic gas oil having an aromatic carbon content of at least about 40% as measured by 13C NMR based on the total carbon content of the added stream and said hydrotreated aromatic gas oil having an aromatic carbon content of at least about X % according to the formula
X=(A %)−
- [(0.02)·
(hydrogen uptake in the hydrotreater)]
where X is as least about 20% as measured by 13C NMR based on the total carbon content of the hydrotreated aromatic gas oil and A is the aromaticity of the unhydrotreated aromatic gas oil as measured by 13C NMR and is at least about 40%, hydrogen uptake is [ρ
·
659.5·
(Δ
hydrogen content (wt %) of the hydrotreater product and feed)] and ρ
is the density (grams/cc) of the hydrotreater feed;
(b) introducing the modified stream into the coker furnace;
(c) heating the modified stream to a coking temperature in the coker furnace to produce a heated modified stream; and
(d) transferring the heated modified stream from the coker furnace to a coke drum.
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Accused Products
Abstract
A method for reducing furnace fouling in a delayed coking process comprising (a) supplying at least one feed to a delayed coking unit comprised of coker furnace, at least two coke drums and a coker fractionator, (b) increasing the aromaticity of the feed to produce a modified stream by combining with the feed upstream of the coker furnace at least one added stream selected from the group consisting of an aromatic gas oil, a hydrotreated aromatic gas oil and combinations thereof, (c) introducing the modified feed stream into the coker furnace, d) heating the modified feed stream to a coking temperature in the coker furnace to produce a heated modified stream, and e) transferring the heated modified stream from the coker furnace to a coke drum.
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Citations
26 Claims
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1. A method for reducing furnace fouling in a delayed coking process wherein at least one coker feed is supplied to a delayed coking unit comprised of a coker furnace, at least two coke drums and a coker fractionator comprising
(a) increasing the aromaticity of the feed to produce a modified stream by combining with the feed upstream of the coker furnace at least one added stream selected from the group consisting of an aromatic gas oil, a hydrotreated aromatic gas oil and combinations thereof, said aromatic gas oil having an aromatic carbon content of at least about 40% as measured by 13C NMR based on the total carbon content of the added stream and said hydrotreated aromatic gas oil having an aromatic carbon content of at least about X % according to the formula
X=(A %)−- [(0.02)·
(hydrogen uptake in the hydrotreater)]
where X is as least about 20% as measured by 13C NMR based on the total carbon content of the hydrotreated aromatic gas oil and A is the aromaticity of the unhydrotreated aromatic gas oil as measured by 13C NMR and is at least about 40%, hydrogen uptake is [ρ
·
659.5·
(Δ
hydrogen content (wt %) of the hydrotreater product and feed)] and ρ
is the density (grams/cc) of the hydrotreater feed;(b) introducing the modified stream into the coker furnace; (c) heating the modified stream to a coking temperature in the coker furnace to produce a heated modified stream; and (d) transferring the heated modified stream from the coker furnace to a coke drum. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14)
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15. A method for reducing furnace fouling in a delayed coking process wherein at least one coker feed is supplied to a delayed coking unit comprised of a coker furnace, at least two coke drums and a coker fractionator comprising
(a) supplying the feed to the bottom of the fractionator to produce an overhead stream, a bottoms stream and at least one intermediate stream from the fractionator; -
(b) increasing the aromaticity of the bottoms stream to produce a modified stream by combining with the bottoms stream upstream of the coker furnace at least one added stream selected from the group consisting of an aromatic gas oil, a hydrotreated aromatic gas oil and combinations thereof, said aromatic gas oil having an aromatic carbon content of at least about 40% as measured by 13C NMR based on the total carbon content of the added stream and said hydrotreated aromatic gas oil having an aromatic carbon content of at least about X % according to the formula
X=(A %)−
[(0.02)·
(hydrogen uptake in the hydrotreater)]
where X is as least about 20% as measured by 13C NMR based on the total carbon content of the hydrotreated aromatic gas oil and A is the aromaticity of the unhydrotreated aromatic gas oil as measured by 13C NMR and is at least about 40%, hydrogen uptake is [ρ
·
659.5·
(Δ
hydrogen content (wt %) of the hydrotreater product and feed)] and ρ
is the density (grams/cc) of the hydrotreater feed;(c) introducing the modified stream into the coker furnace; (d) heating the modified stream to a coking temperature in the coker furnace to produce a heated modified stream; and (e) transferring the heated modified stream from the coker furnace to a coke drum. - View Dependent Claims (16, 17, 18, 19, 20, 21, 22)
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23. A method for reducing furnace fouling in a delayed coking process wherein at least one coker feed is supplied to a delayed coking unit comprised of a coker furnace, at least two coke drums and a coker fractionator comprising
(a) supplying the feed to the coker furnace without first passing the feed through the fractionator, (b) increasing the aromaticity of the feed to produce a modified stream by combining with the feed upstream of the coker furnace at least one added stream selected from the group consisting of an aromatic gas oil, a hydrotreated aromatic gas oil and combinations thereof, said aromatic gas oil having an aromatic carbon content of at least about 40% as measured by 13C NMR based on the total carbon content of the added stream and said hydrotreated aromatic gas oil stream having an aromatic carbon content of at least about X % according to the formula
X=(A %)−- [(0.02)·
(hydrogen uptake in the hydrotreater)]
where X is as least about 20% as measured by 13C NMR based on the total carbon content of the hydrotreated aromatic gas oil and A is the aromaticity of the unhydrotreated aromatic gas oil as measured by 13C NMR and is at least about 40%, hydrogen uptake is [ρ
·
659.5·
(Δ
hydrogen content (wt %) of the hydrotreater product and feed)] and ρ
is the density (grams/cc) of the hydrotreater feed;(c) introducing the modified stream into the coker furnace; (d) heating the modified stream to a coking temperature in the coker furnace to produce a heated modified stream; and (e) transferring the heated modified stream from the coker furnace to a coke drum. - View Dependent Claims (24, 25, 26)
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Specification