Four-Train Catalytic Gasification Systems

• US 20090324462A1
• Filed: 06/26/2009
• Published: 12/31/2009
• Est. Priority Date: 06/27/2008
• Status: Abandoned Application

• Current Assignee: Sure Champion Investments Limited
• Original Assignee: GreatPoint Energy, Inc.
• Inventors: Robinson, Earl T., Lau, Francis S., Dodson, Dwain
• Application Number:
  US12/492,497
• Publication Number:
  US 20090324462A1
• Time in Patent Office: Days
• US Class Current: 422/187
• CPC Class Codes: C10J 2300/0903 Feed preparation
• CPC Class Codes: C10J 2300/0906 Physical processes, e.g. shredding, comminuting, chopping, sorting
• CPC Class Codes: C10J 2300/093 Coal
• CPC Class Codes: C10J 2300/0973 Water
• CPC Class Codes: C10J 2300/0986 Catalysts
• CPC Class Codes: C10J 2300/1662 to methane (SNG) production of synthetic natural gas C10L3/08
• CPC Class Codes: C10J 2300/1671 with the production of electricity
• CPC Class Codes: C10J 2300/1675 making use of a steam turbine
• CPC Class Codes: C10J 2300/1687 with steam generation
• CPC Class Codes: C10J 2300/169 with water treatments treatment of water in general or water purification C02F
• CPC Class Codes: C10J 2300/1807 Recycle loops, e.g. gas, solids, heating medium, water
• CPC Class Codes: C10J 2300/1823 for synthesis gas
• CPC Class Codes: C10J 2300/1853 Steam reforming, i.e. injection of steam only
• CPC Class Codes: C10J 2300/1884 with one stream being synthesis gas
• CPC Class Codes: C10J 3/00 Production of combustible gases containing carbon monoxide from solid carbonaceous fuels destructive distillation processes C10B
• CPC Class Codes: C10J 3/482 Gasifiers with stationary fluidised bed
• CPC Class Codes: C10J 3/721 Multistage gasification, e.g. plural parallel or serial gasification stages
• CPC Class Codes: C10K 1/003 of acid contaminants, e.g. acid gas removal
• CPC Class Codes: C10K 1/004 Sulfur containing contaminants, e.g. hydrogen sulfide
• CPC Class Codes: C10K 1/006 Hydrogen cyanide
• CPC Class Codes: C10K 1/007 : of metal compounds
• CPC Class Codes: C10K 1/10 : with aqueous liquids alkaline reacting aqueous liquids C10K1/12
• CPC Class Codes: C10K 1/101 : with water only
• CPC Class Codes: C10K 1/102 : containing free acid
• CPC Class Codes: C10K 1/123 : containing alkali-, earth-alkali- or NH4 salts of inorganic acids derived from sulfur
• CPC Class Codes: C10K 1/14 : organic
• CPC Class Codes: C10K 1/143 : containing amino groups
• CPC Class Codes: C10K 1/16 : with non-aqueous liquids
• CPC Class Codes: C10K 1/20 : by treating with solids; Regenerating spent purifying masses separation by adsorption B01D53/02; separation by chemical reaction B01D53/34; refining of hydrocarbon oils with acids C10G17/02, C10G27/02, C10G29/12
• CPC Class Codes: C10K 1/32 : with selectively adsorptive solids, e.g. active carbon
• CPC Class Codes: C10K 3/04 : reducing the carbon monoxide content , e.g. water-gas shift [WGS]
• CPC Class Codes: C10L 3/08 : Production of synthetic natural gas

Abstract

Systems to convert a carbonaceous feedstock into a plurality of gaseous products are described. The systems include, among other units, four separate gasification reactors for the gasification of a carbonaceous feedstock in the presence of an alkali metal catalyst into the plurality of gaseous products including at least methane. Each of the gasification reactors may be supplied with the feedstock from a single or separate catalyst loading and/or feedstock preparation unit operations. Similarly, the hot gas streams from each gasification reactor may be purified via their combination at a heat exchanger, acid gas removal, or methane removal unit operations. Product purification may comprise trace contaminant removal units, ammonia removal and recovery units, and sour shift units.

Claims

1. A gasification system to generate a plurality of gases from a catalyzed carbonaceous feedstock, the system comprising:

(a) a first, a second, a third and a fourth gasifying reactor unit, wherein each gasifying reactor unit independently comprises;

(A1) a reaction chamber in which a catalyzed carbonaceous feedstock and steam are converted to (i) a plurality of gaseous products comprising methane, hydrogen, carbon monoxide, carbon dioxide, hydrogen sulfide and unreacted steam, (ii) unreacted carbonaceous fines and (iii) a solid char product comprising entrained catalyst;

(A2) a feed inlet to supply the catalyzed carbonaceous feedstock into the reaction chamber;

(A3) a steam inlet to supply steam into the reaction chamber;

(A4) a hot gas outlet to exhaust a hot first gas stream out of the reaction chamber, the hot first gas stream comprising the plurality of gaseous products;

(A5) a char outlet to withdraw the solid char product from the reaction chamber; and

(A6) a fines remover unit to remove at least a substantial portion of the unreacted carbonaceous fines that may be entrained in the hot first gas stream;

(b) (1) a single catalyst loading unit to supply the catalyzed carbonaceous feedstock to the feed inlets of the first, second, third and fourth gasifying reactor units, or

(2) a first and a second catalyst loading unit to supply the catalyzed carbonaceous feedstock to the feed inlets the first, second, third and fourth gasifying reactor units;

or

(3) a first, a second and a third catalyst loading unit to supply the catalyzed carbonaceous feedstock to the feed inlets of the first, second, third and fourth gasifying reactor units;

or

(4) a first, a second, a third catalyst and a fourth catalyst loading unit to supply the catalyzed carbonaceous feedstock to the feed inlets of the first, second, third and fourth gasifying reactor units,

wherein each catalyst loading unit independently comprises;

(B1) a loading tank to receive carbonaceous particulates and to load catalyst onto the particulates to form the catalyzed carbonaceous feedstock; and

(B2) a dryer to thermally treat the catalyzed carbonaceous feedstock to reduce moisture content;

(c) (1) when only the single catalyst loading unit is present, a single carbonaceous material processing unit to supply the carbonaceous particulates to the loading tank of the single catalyst loading unit, or

(2) when only the first and second catalyst loading units are present, (i) a single carbonaceous material processing unit to supply the carbonaceous particulates to the loading tanks of the first and second catalyst loading units, or (ii) a first and a second carbonaceous material processing unit to supply the carbonaceous particulates to the loading tanks of the first and second catalyst loading units, or

(3) when only the first, second and third catalyst loading units are present, (i) a single carbonaceous material processing unit to supply the carbonaceous particulates to the loading tanks of the first, second and third catalyst loading units, or (ii) a first and a second carbonaceous material processing unit to supply the carbonaceous particulates to the loading tanks of the first, second and third catalyst loading units, (iii) a first, a second and a third carbonaceous material processing unit to supply the carbonaceous particulates to the loading tanks of the first and second catalyst loading units, or

(4) when the first, second, third and fourth catalyst loading units are present, (i) a single carbonaceous material processing unit to supply the carbonaceous particulates to the loading tanks of the first, second, third and fourth catalyst loading units, or (ii) a first and a second carbonaceous material processing unit to supply the carbonaceous particulates to the loading tanks of the first, second, third and fourth catalyst loading units, or (iii) a first, a second and a third carbonaceous material processing unit to supply the carbonaceous particulates to the loading tanks of the first, second, third and fourth catalyst loading units, or (iv) a first, a second, a third and a fourth carbonaceous material processing unit to supply the carbonaceous particulates to the loading tanks of the first, second, third and fourth catalyst loading units,

wherein the single carbonaceous material processing unit comprises;

(C1) a receiver to receive and store a carbonaceous material; and

(C2) a grinder to grind the carbonaceous material into the carbonaceous particulates, the grinder in communication with the receiver;

(d) (1) a single heat exchanger unit to remove heat energy from the hot first gas streams from the first, second, third and fourth gasifying reactor units to generate steam and produce a single cooled first gas stream, or

(2) a first and a second heat exchanger unit to remove heat energy from the hot first gas streams from the first, second, third and fourth gasifying reactor units to generate steam, a first cooled first gas stream and a second cooled first gas stream, or

(3) a first, a second, a third and a fourth heat exchanger unit to remove heat energy from the hot first gas streams from the first second, third and fourth gasifying reactor unit to generate steam and produce a first cooled first gas stream, a second cooled first gas stream, a third cooled first gas stream and a fourth cooled first gas stream;

(e) (1) when only the single heat exchanger unit is present, a single acid gas remover unit to remove at least a substantial portion of the carbon dioxide and at least a substantial portion of the hydrogen sulfide from the single cooled first gas stream, to produce a single acid gas-depleted gas stream comprising at least a substantial portion of the methane, at least a substantial portion of the hydrogen and, optionally, at least a portion of the carbon monoxide from the single cooled first gas stream, or

(2) when only the first and second heat exchanger units are present, a single acid gas remover unit to remove at least a substantial portion of the carbon dioxide and at least a substantial portion of the hydrogen sulfide from the first and second cooled first gas streams to produce a single acid gas-depleted gas stream comprising at least a substantial portion of the methane, at least a substantial portion of the hydrogen and, optionally, at least a portion of the carbon monoxide from the first and second cooled first gas streams, or

(3) when the first, second, third and fourth heat exchanger units are present, a single acid gas remover unit to remove at least a substantial portion of the carbon dioxide and at least a substantial portion of the hydrogen sulfide from the first, second, third and fourth cooled first gas streams to produce a single acid gas-depleted gas stream comprising at least a substantial portion of the methane, at least a substantial portion of the hydrogen and, optionally, at least a portion of the carbon monoxide from the first, second, third and fourth cooled first gas streams;

(f) a single methane removal unit to separate and recover methane from the single acid gas-depleted gas stream, to produce a single methane-depleted gas stream and a single methane product stream, the single methane product stream comprising at least a substantial portion of the methane from the single acid gas-depleted gas stream; and

(g) (1) a single steam source to supply steam to the steam inlets of the first, second, third and fourth gasifying reactor units, or

(2) a first and a second steam source to supply stream to the steam inlets of the first, second, third and fourth gasifying reactor units.

2. The system according to claim 1, wherein the system further comprises one or more of:

(h) a trace contaminant removal unit between a heat exchanger unit and an acid gas remover unit, to remove at least a substantial portion of one or more trace contaminants from the single cooled first gas stream, or, when present, one or more of the first, second, third and fourth cooled first gas streams, wherein the single cooled first gas stream or the one or more of the first, second, third and fourth cooled first gas streams further comprise one or more trace contaminants comprising one or more of COS, Hg and HCN;

(i) a reformer unit to convert a portion of the single methane product stream into a syngas;

(j) a methane compressor unit to compress at least a portion of the single methane product stream;

(k) a carbon dioxide recovery unit to separate and recover methane carbon dioxide removed by the single acid gas remover unit;

(l) a sulfur recovery unit to extract and recover sulfur from the hydrogen sulfide removed by the single acid gas remover unit;

(m) a catalyst recovery unit to extract and recover at least a portion of the entrained catalyst from at least a portion of the solid char product, and recycle at least a portion of the recovered catalyst to the single catalyst loading unit, or when present, one or more of the first, second, third and fourth catalyst loading units;

(n) a gas recycle loop to recycle at least a portion of the single methane-depleted gas stream to one or more of the first, second, third and fourth gasifying reactor units;

(o) a waste water treatment unit to treat waste water generated by the system;

(p) a superheater to superheat the steam in or from the single steam source, or when present the first steam source and/or second steam source;

(q) a steam turbine to generate electricity from at least a portion of the steam supplied by the single steam source, or when present the first steam source and/or the second steam source; and

(r) a sour shift unit between a heat exchanger and an acid gas remover unit, to contact a cooled first gas stream with an aqueous medium under conditions suitable to convert at least a portion of carbon monoxide in the cooled first gas stream to carbon dioxide.

3. The system according to claim 1, wherein the system comprises:

(a) the first, second, third and fourth gasifying reactor units;

(b) the single catalyst loading unit, or the first and second catalyst loading units, or the first, second and third catalyst loadings units, or the first, second, third and fourth catalyst loading units;

(c) the single carbonaceous material processing unit, or the first and second carbonaceous material processing units, or the first, second and third carbonaceous material processing units, or the first, second, third and fourth carbonaceous material processing units;

(d) the first and second heat exchanger units, or the first, second, third and fourth heat exchanger units;

(e) the single acid gas remover unit;

(f) the single methane removal unit; and

(g) the single steam source, or the first and second steam sources.

4. The system according to claim 3, wherein the system further comprises one or more of:

(h) (1) when only the first and second heat exchanger units are present, a first and a second trace contaminant removal unit between the first and second heat exchanger units and the single acid gas remover unit, to remove at least a substantial portion of one or more trace contaminants from the first and second cooled first gas streams, or

(2) when the first, second, third and fourth heat exchanger units are present, a first, a second, a third and a fourth trace contaminant removal unit between the first, second, third and fourth heat exchanger units and the single acid gas remover unit, to remove at least a substantial portion of one or more trace contaminants from the first, second, third and fourth cooled first gas streams;

(i) (1) a single reformer unit to convert a portion of the single methane product stream into a syngas, or

(2) a first and a second reformer unit to convert a portion of the single methane product streams into a syngas;

(j) a single methane compressor unit to compress at least a portion of the single methane product stream;

(k) a single carbon dioxide recovery unit to separate and recover carbon dioxide removed by the single acid gas remover unit;

(l) a single sulfur recovery unit to extract and recover sulfur from the hydrogen sulfide removed by the single acid gas remover units;

(m) (1) a single catalyst recovery unit to extract and recover at least a portion of the entrained catalyst from at least a portion of the solid char product from the first, second, third and fourth gasifying units, and recycle at least a portion of the recovered catalyst to the single catalyst loading unit, or one or more of the first and second catalyst loading units, or one or more of the first, second and third catalyst loading units, or one or more of the first, second, third and fourth catalyst loading units;

or

(2) a first and a second catalyst recovery unit to extract and recover at least a portion of the entrained catalyst from at least a portion of the solid char product from the first, second, third and fourth gasifying units, and recycle at least a portion of the recovered catalyst to the single catalyst loading unit, or one or more of the first and second catalyst loading units, or one or more of the first, second and third catalyst loading units, or one or more of the first, second, third and fourth catalyst loading units;

or

(3) a first, a second, a third and a fourth catalyst recovery unit to extract and recover at least a portion of the entrained catalyst from at least a portion of the solid char product from the first, second, third and fourth gasifying units, and recycle at least a portion of the recovered catalyst to the single catalyst loading unit, or one or more of the first and second catalyst loading units, or one or more of the first, second and third catalyst loading units, or one or more of the first, second, third and fourth catalyst loading units;

(n) a gas recycle loop to recycle at least a portion of the single methane-depleted gas stream to one or more of the first, second, third, and fourth gasifying reactor units;

(o) a waste water treatment unit to treat waste water generated by the system;

(p) a superheater to superheat the steam in or from the single steam source, or when present the first steam source and/or second steam source;

(q) a steam turbine to generate electricity from at least a portion of the steam supplied by the single steam source, or when present the first steam source and/or the second steam source; and

(r) (1) when only the first and second heat exchanger units are present, a first and a second sour shift unit between the first and second heat exchanger units and the single acid gas remover unit, to convert at least a portion of carbon monoxide in the first and second cooled first gas streams to carbon dioxide, or

(2) when the first, second, third and fourth heat exchanger units are present, (i) a first and a second sour shift unit between the first, second, third and fourth heat exchanger units and the single acid gas remover unit, to convert at least a portion of carbon monoxide in the first, second, third and fourth cooled first gas streams to carbon dioxide, or (ii) a first, a second, a third and a fourth sour shift unit between the first, second, third and fourth heat exchanger units and the single acid gas remover units, to convert at least a portion of carbon monoxide in the first, second, third and fourth cooled first gas stream to carbon dioxide.

5. The system according to claim 1, wherein the system comprises:

(a) the first, second, third and fourth gasifying reactor units;

(b) the single catalyst loading unit, or the first and second catalyst loading units, or the first, second and third catalyst loading units, or the first, second, third and fourth catalyst loading units;

(c) the single carbonaceous material processing unit, or the first and second carbonaceous material processing units, or the first, second and third carbonaceous material processing units, or the first, second, third and fourth carbonaceous material processing units;

(d) the single heat exchanger unit;

(e) the single acid gas remover unit;

(f) the single methane removal unit; and

(g) the single steam source, or the first and second steam sources.

6. The system according to claim 5, wherein the system further comprises one or more of:

(h) a single trace contaminant removal unit between the single heat exchanger unit and the single acid gas remover unit, to remove at least a substantial portion of one or more trace contaminants from the single cooled first gas stream;

(i) (1) a single reformer unit to convert a portion of the single methane product stream into a syngas, or

(2) a first and a second reformer unit to convert a portion of the single methane product streams into a syngas;

(j) a single methane compressor unit to compress at least a portion of the single methane product stream;

(k) a single carbon dioxide recovery unit to separate and recover carbon dioxide removed by the single acid gas remover unit;

(l) a single sulfur recovery unit to extract and recover sulfur from the hydrogen sulfide removed by the single acid gas remover unit;

(m) (1) a single catalyst recovery unit to extract and recover at least a portion of the entrained catalyst from at least a portion of the solid char product from the first, second, third and fourth gasifying units, and recycle at least a portion of the recovered catalyst to the single catalyst loading unit, or one or more of the first and second catalyst loading units, or one or more of the first, second and third catalyst loading units, or one or more of the first, second, third and fourth catalyst loading units;

or

(2) a first and a second catalyst recovery unit to extract and recover at least a portion of the entrained catalyst from at least a portion of the solid char product from the first, second, third and fourth gasifying units, and recycle at least a portion of the recovered catalyst to the single catalyst loading unit, or one or more of the first and second catalyst loading units, or one or more of the first, second and third catalyst loading units, or one or more of the first, second, third and fourth catalyst loading units;

or

(3) a first, a second, a third and a fourth catalyst recovery unit to extract and recover at least a portion of the entrained catalyst from at least a portion of the solid char product from the first, second, third and fourth gasifying units, and recycle at least a portion of the recovered catalyst to the single catalyst loading unit, or one or more of the first and second catalyst loading units, or one or more of the first, second and third catalyst loading units, or one or more of the first, second, third and fourth catalyst loading units;

(n) a gas recycle loop to recycle at least a portion of the single methane-depleted gas stream to one or more of the first, second, third, and fourth gasifying reactor units;

(o) a waste water treatment unit to treat waste water generated by the system;

(p) a superheater to superheat the steam in or from the single steam source, or when present the first steam source and/or second steam source;

(q) a steam turbine to generate electricity from at least a portion of the steam supplied by the single steam source, or when present the first steam source and/or the second steam source; and

(r) a single sour shift unit between the single heat exchanger unit and the single acid gas remover unit, to convert at last a portion of carbon monoxide in the single cooled first gas stream to carbon dioxide.

7. The system according to claim 1, wherein the system comprises:

(a) the first, second, third and fourth gasifying reactor units;

(b) the single catalyst loading unit, or the first and second catalyst loading units;

(c) the single carbonaceous material processing unit, or the first and second carbonaceous material processing units;

(d) the first and second heat exchanger units;

(e) the single acid gas remover unit;

(f) the single methane removal unit; and

(g) the single steam source, or the first and second steam sources.

8. The system according to claim 7, wherein the system further comprises one or more of:

(h) (i) a single trace contaminant removal unit between the first and second heat exchanger units and the single acid gas remover unit, to remove at least a substantial portion of one or more trace contaminants from the first and second cooled first gas streams, or (ii) a first and a second trace contaminant removal unit between the first and second heat exchanger units and the single acid gas remover unit, to remove at least a substantial portion of one or more trace contaminants from the first and second cooled first gas streams;

(i) (1) a single reformer unit to convert a portion of the single methane product stream into a syngas, or

(2) a first and a second reformer unit to convert a portion of the single methane product streams into a syngas;

(j) a single methane compressor unit to compress at least a portion of the single methane product stream;

(k) a single carbon dioxide recovery unit to separate and recover carbon dioxide removed by the single acid gas remover unit;

(l) a single sulfur recovery unit to extract and recover sulfur from the hydrogen sulfide removed by the single acid gas remover unit;

(m) (1) a single catalyst recovery unit to extract and recover at least a portion of the entrained catalyst from at least a portion of the solid char product from the first, second, third and fourth gasifying units, and recycle at least a portion of the recovered catalyst to the single catalyst loading unit, or one or more of the first and second catalyst loading units;

or

(2) a first and a second catalyst recovery unit to extract and recover at least a portion of the entrained catalyst from at least a portion of the solid char product from the first, second, third and fourth gasifying units, and recycle at least a portion of the recovered catalyst to the single catalyst loading unit, or one or more of the first and second catalyst loading units;

(n) a gas recycle loop to recycle at least a portion of the single methane-depleted gas stream to the first, second, third, and fourth gasifying reactor units;

(o) a waste water treatment unit to treat waste water generated by the system;

(p) a superheater to superheat the steam in or from the single steam source, or when present the first steam source and/or second steam source;

(q) a steam turbine to generate electricity from at least a portion of the steam supplied by the single steam source, or when present the first steam source and/or the second steam source; and

(r) (1) a single sour shift unit between the first and second heat exchanger units and the single acid gas remover unit, to convert at least a portion of carbon monoxide in the first and second cooled first gas streams to carbon dioxide, or

(2) a first and a second sour shift unit between the first and second exchanger units and the single acid gas remover unit, to convert at least a portion of carbon monoxide in the first and second cooled first gas streams to carbon dioxide.

9. The system according to claim 2, comprising at least (k), (l) and (m).

10. The system according to claim 2, wherein the system comprises (k), and the system further comprises a carbon dioxide compressor unit to compress recovered carbon dioxide.

11. The system according to claim 2, wherein the system comprises (r) and a trim methanator between an acid gas remover unit and a methane removal unit.

12. The system according to claim 4, comprising at least (k), (l) and (m).

13. The system according to claim 4, wherein the system comprises (k), and the system further comprises a carbon dioxide compressor unit to compress recovered carbon dioxide.

14. The system according to claim 4, wherein the system comprises (r) and a trim methanator between an acid gas remover unit and a methane removal unit.

15. The system according to claim 6, comprising at least (k), (l) and (m).

16. The system according to claim 6, wherein the system comprises (k), and the system further comprises a carbon dioxide compressor unit to compress recovered carbon dioxide.

17. The system according to claim 6, wherein the system comprises (r) and a trim methanator between an acid gas remover unit and a methane removal unit.

18. The system according to claim 8, comprising at least (k), (l) and (m).

19. The system according to claim 8, wherein the system comprises (k), and the system further comprises a carbon dioxide compressor unit to compress recovered carbon dioxide.

20. The system according to claim 8, wherein the system comprises (r) and a trim methanator between an acid gas remover unit and a methane removal unit.

21. The system according to claim 1, wherein the system produces a product stream of pipeline-quality natural gas.