Detection of Explosive Materials

• US 20100000882A1
• Filed: 09/14/2007
• Published: 01/07/2010
• Est. Priority Date: 10/04/2006
• Status: Abandoned Application

• Current Assignee: Arizona Board of Regents (University of Arizona)
• Original Assignee: Arizona Board of Regents (University of Arizona)
• Inventors: Cagan, Avi, Wang, Joseph
• Application Number:
  US12/444,113
• Publication Number:
  US 20100000882A1
• Time in Patent Office: Days
• US Class Current: 205/781
• CPC Class Codes: G01N 33/0057 for warfare agents or explosives properties of explosives G01N33/227
• CPC Class Codes: G01N 33/22 Fuels, explosives liquid hydrocarbons G01N33/28

Abstract

Among other things, methods and systems are described for detecting chemicals including explosive materials. For example, a system for detecting materials includes a sample gathering unit designed to obtain a portion of a target material to be tested. In addition, the system includes a sample holding unit that has a first end designed to attach to the sample gathering unit and form a housing that retains at least the obtained portion of the target material. Further, a reagent holding unit is included and designed to attach to a second end of the sample holding unit. The reagent holding unit is designed to introduce the reagent into the formed housing to mix with the obtained target material and start a chemical reaction.

Claims

1. A system for detecting a target material, the system comprising:

a sample gathering unit configured to obtain a portion of the target material to be tested;

a sample holding unit having a first end configured to attach to the sample gathering unit and form a housing that retains at least the obtained portion of the target material; and

a reagent holding unit attached to a second end of the sample holding unit, wherein the reagent holding unit is configured to introduce the reagent into the formed housing to mix with the obtained target material and start a chemical reaction.

2. The system of claim 1, further comprising:

an electrochemical sensor unit configured to interface with contents of the formed housing; and

a reader configured to interface with the conductive sensor unit to detect an electrical signal associated with the contents of the formed housing.

3. The system of claim 2, wherein the electrochemical sensor unit comprises:

a working electrode; and

at least one of a reference electrode and a counter electrode.

4. The system of claim 3, wherein the reader is configured to interface with the electrochemical sensor unit to detect the electrical signal associated with the contents of the formed housing comprising

applying a potential through the interfaced electrochemical sensor;

in response to the applied potential, measuring at least one of

an electrical potential between the working electrode and one of the reference electrode and the counter electrde, and

an electrical current between the working electrode and one of the reference electrode and counter electrode, and

processing the measured at least one of the electrical potential and electrical current to generate an output signal that indicates a presence or absence of a reaction between an explosive material and the reagent.

5. The system of claim 1, wherein the target material comprises an explosive material.

6. The system of claim 1, wherein

the target material comprises one of urea nitrate and a peroxide-based explosive material;

and

the reagent comprises a mixture of a solvent and an acid.

7. The system of claim 6, wherein

the target material comprises urea nitrate (UN);

and

the reagent comprises p-nitrotoluene (NT) based mixture.

8. The system of claim 6, wherein

the target material comprises one of triacetone triperoxide (TATP) and hexamethylene triperoxide diamine (HMTD);

and

the reagent comprises hydrochloric acid (HCl) based mixture.

9. The system of claim 4 further comprising a display unit for displaying the determined electrical potential and electrical current.

10. The system of claim 4 further comprising a computing system for processing the determined electrical potential and electrical current.

11. A method for detecting a material, the method comprising:

obtaining a sample of a target material to be tested;

sealing the obtained sample of the target material in a detection unit;

introducing a reagent into the detection unit to mix with the target material, wherein the reagent is configured to start a chemical reaction and generate a product when mixed with an explosive material;

measuring an electrochemical signal associated with the mixture of reagent and the target material; and

processing the measured electrochemical signal to generate an output that indicates a presence or absence of a chemical reaction between the target material land the reagent.

12. The method of claim 11, wherein processing the measured electrochemical signal comprises:

obtaining a signal profile associated with the mixture of the reagent and the target material; and

comparing the obtained signal profile against a signal profile associated with a reaction between the reagent and an explosive material.

13. The method of claim 12, wherein comparing the obtained signal profile with the signal profile associated with a reaction between the reagent and an explosive material comprises:

identifying a presence of at least one of urea nitrate and a peroxide-based explosive material in the target material.

14. The method of claim 13, wherein

identifying a presence of at least one of urea nitrate and a peroxide-based explosive material in the target material comprises:

identifying a presence of urea nitrate (UN) in the target material; and

identifying a presence of a reaction product comprising 2,4-dinitrotoluene (2,4-DNT).

15. The method of claim 13, wherein

identifying a presence of at least one of urea nitrate and a peroxide-based explosive material in the target material comprises:

identifying a presence of one of triacetone triperoxide (TATP) and hexamethylene triperoxide diamine (HMTD) in the target material; and

identifying a presence of a reaction product comprising hydrogen peroxide (H₂O₂).

16. The method of claim 12 further comprising displaying the obtained signal profile to a user.

17. The method of claim 11, wherein measuring an electrochemical signal comprises obtaining at least one of an electrical potential and an electrical current.

18. The method of claim 17 further comprising processing the obtained signal profile to determine a relationship between a concentration of an explosive material and a magnitude of the signal profile.

19. The method of claim 11, wherein introducing the reagent into the detection unit comprises automatically introducing the reagent into the detection unit when the obtained sample of the target material is sealed in the detection unit.

20. A system for testing a target material, the system comprising:

a sample gathering unit configured to obtain a portion of the target material to be tested;

a sample holding unit having a first end configured to attach to the sample gathering unit and form a housing that retains at least the obtained portion of the target material; and

a reagent holding unit attached to a second end of the sample holding unit, wherein the reagent holding unit is configured to introduce the reagent into the formed housing to mix with the obtained target material and start a chemical reaction.

an electrochemical sensor unit configured to interface with contents of the formed housing;

a reader configured to interface with the conductive sensor unit to detect an electrical signal associated with the contents of the formed housing; and

a processor configured to process the detected electrical signal to generate an output signal indicative of a presence of an explosive material in the target material, wherein the processing comprises;

generating a voltammetric signal profile that includes a relationship between currents measured and potentials applied;

comparing the generated signal profile against a known signal profile of an explosive material.

21. The detection system of claim 20, further comprising a light source configured to irradiate the target material.

22. A microelectrode sensing device, comprising:

a substrate;

an array of microelectrode sensors formed on the substrate, each microelectrode sensor comprising

one or more conductive layers, that at least partially conducts electricity, formed above the substrate and patterned to comprise at least a working electrode and a reference electrode to measure electrical activities associated with a chemical reaction between a target material and a reagent; and

a reading unit configured to interface the one or more conductive layers, wherein the reading unit detects the measured electrical activities.

23. A method of testing a target material comprising:

obtaining a portion of the target material;

irradiating the obtained portion of the target material;

sealing the irradiated sample of the target material in a detection unit;

in response to sealing the irradiated sample of the target material in a detection unit, automatically introducing a reagent into the detection unit to mix with the target material, wherein the reagent is configured to start a chemical reaction and generate a product when mixed with an explosive material;

measuring an electrochemical signal associated with the mixture of reagent and the target material; and

processing the measured electrochemical signal to generate an output that indicates a presence or absence of a chemical reaction between the target material land the reagent.

24. A compute program product, embodied on a tangible computer readable-medium, operable to cause a data processing apparatus to perform apparatus comprising:

obtain an electrical signal associated with a reaction between a target material and a reagent;

processing the obtained electrical signal to identify a presence of an explosive material in the target material; and

based on the processing, generating an output signal, wherein the generated output signal comprises at least one of

a visual indication of the presence of an explosive material in the target material; and

an audio indication of the presence of an explosive material in the target material.

25. A method comprising

providing a removable sample gathering unit configured to obtain a portion of a target material;

providing a sample holding unit configured to form a housing that retains at least the obtained portion of the target material, wherein the removable sample gathering unit includes a receptor for receiving the removable sample unit;

providing a reagent holding unit configured to

retain a reagent,

interface with the sample holding unit, and

introduces the retained reagent into the formed housing of the sample holding unit when the sample holding unit receives the removable sample gathering unit;

measuring an electrical signal associated with contents of the formed housing of the sample holding unit; and

processing the measured electrical signal to detect a presence of an explosive material in the target material.