DUAL STAGE ION EXCHANGE FOR CHEMICAL STRENGTHENING OF GLASS
First Claim
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1. A method of strengthening a glass, the method comprising:
- creating a compressive stress in an outer region of the glass, the region extending from a surface of the glass to a depth-of-layer, the compressive stress being sufficient to arrest flaws within the glass and to arrest flaws at the surface introduced by contact forces at the surface, and wherein the compressive stress is created by;
a. providing a glass, the glass having a plurality of first metal ions within the outer region;
b. ion exchanging a first portion of the plurality of first metal ions in the glass with a plurality of second metal ions in a first salt bath, wherein the first salt bath is diluted with a first concentration of the first metal ions; and
c. ion exchanging a second portion of the plurality of the first metal ions in the glass with a plurality of the second metal ions in a second salt bath, wherein the second salt bath has a second concentration of the first metal that is less than the first concentration.
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Abstract
A method of chemically strengthening a glass. The method includes ion exchange of the glass in a first bath, followed by immersion in the second bath. The first bath is diluted with an effluent ion. The second bath has a smaller concentration of the effluent ion than the first bath. The method provides a compressive stress at the surface of the glass that is sufficient to arrest flaws introduced by contact forces at the surface of the glass while having sufficiently deep compressive depth-of-layer for high reliability.
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Citations
20 Claims
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1. A method of strengthening a glass, the method comprising:
- creating a compressive stress in an outer region of the glass, the region extending from a surface of the glass to a depth-of-layer, the compressive stress being sufficient to arrest flaws within the glass and to arrest flaws at the surface introduced by contact forces at the surface, and wherein the compressive stress is created by;
a. providing a glass, the glass having a plurality of first metal ions within the outer region; b. ion exchanging a first portion of the plurality of first metal ions in the glass with a plurality of second metal ions in a first salt bath, wherein the first salt bath is diluted with a first concentration of the first metal ions; and c. ion exchanging a second portion of the plurality of the first metal ions in the glass with a plurality of the second metal ions in a second salt bath, wherein the second salt bath has a second concentration of the first metal that is less than the first concentration. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 14, 16, 18, 20)
- creating a compressive stress in an outer region of the glass, the region extending from a surface of the glass to a depth-of-layer, the compressive stress being sufficient to arrest flaws within the glass and to arrest flaws at the surface introduced by contact forces at the surface, and wherein the compressive stress is created by;
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13. A method of strengthening a glass, the method comprising the steps of:
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a. providing a glass, the glass comprising a plurality of ions of a first metal, each of the ions having a first ionic radius; b. immersing the glass in a first ion exchange bath, the first ion exchange bath comprising a plurality of ions of a second metal and a first concentration of ions of the first metal, wherein each of the ions of the second metal has a second ionic radius, the second ionic radius being greater than the first ionic radius; and c. immersing the glass in a second ion exchange bath after immersing the glass in the first ion exchange bath, the second ion exchange bath comprising a plurality of ions of the second metal and a second concentration of ions of the first metal, wherein the second concentration is less than the first concentration, wherein a portion of the plurality of ions of the first metal in the glass are replaced by ions of the second metal to create a compressive stress in a surface region of the glass. - View Dependent Claims (15)
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17. A method of reducing variability of compressive stress in chemically strengthened glass articles;
- the method comprising the steps of;
a. providing a glass article, the glass comprising a plurality of ions of a first metal, each of the ions having a first ionic radius; b. immersing the glass article in a first ion exchange bath, the first ion exchange bath comprising a plurality of ions of a second metal and a first concentration of ions of the first metal, wherein each of the ions of the second metal has a second ionic radius, the second ionic radius being greater than the first ionic radius; and c. immersing the glass article in a second ion exchange bath after immersing the glass in the first ion exchange bath, the second ion exchange bath comprising a plurality of ions of the second metal and a second concentration of ions of the first metal, wherein the second concentration is less than the first concentration, wherein a portion of the plurality of ions of the first metal in the glass are replaced by ions of the second metal to create a compressive stress in a surface region of the glass, wherein the compressive stress is greater than a predetermined value of compressive stress. - View Dependent Claims (19)
- the method comprising the steps of;
Specification