PDLC FILMS

• US 20100060826A1
• Filed: 05/05/2006
• Published: 03/11/2010
• Est. Priority Date: 04/13/2006
• Status: Active Grant

• Current Assignee: Université du Littoral Côte d'Opale
• Original Assignee: Materia Nova Asbl, Universite De Mons Hainaut, Université du Littoral Côte d'Opale
• Inventors: Boussoualem, Mourad, De Coninck, Joel, Coquelet, Mickael, Buisine, Jean-Marc, Vaillant, Alexandre, Ledauphin, Valerie Celine, Elass, Abdelaziz, Duponchel, Benoit
• Granted Patent: US 8,187,493 B2
• Time in Patent Office: Days
• US Class Current: 349/89
• CPC Class Codes: C08F 265/02 on to polymers of acids, salts or anhydrides
• CPC Class Codes: C08F 265/10 on to polymers of amides or imides
• CPC Class Codes: C08F 267/02 on to polymers of acids or salts
• CPC Class Codes: C08F 267/10 on to polymers of amides or imides
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 51/003 grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds C08L51/04, C08L51/06 take precedence

Abstract

A grafted polymer and its use in polymer/liquid crystal composite films, and more particularly in PDLC films, is disclosed. The grafted polymer includes (alkyl)acrylic acid or (alkyl)acrylamide moieties. At least one of the moieties is grafted with an alkylphenol or with an alkoxylated alkylphenol.

Claims

1. A grafted polymer comprising the following moiety

wherein:

p represents an integer greater than 0,

each R¹, identical or different, represents a hydrogen atom or a C_1-4 alkyl group,

each R², identical or different, represents a OH or NH₂ group,

each R³, identical or different, represents a C_2-180 alkyl group, optionally substituted with one or more C_1-4 alkyl substituents,

L represents a C_1-6 alkylene group, and

n and m each independently represent an integer between 0 and 3200, m+n is between 1 and 3500, the ratio between m and n being between 0.01/1 and 0.1/1.

2. A composition suitable for the preparation of liquid crystal films, said composition comprising a liquid crystal dispersed in a grafted polymer according to claim 1.

3. The composition according to claim 2, comprising at least one solvent and optionally at least one surfactant.

4. The composition according to claim 3, wherein said solvent is water.

5. The composition according to claim 2, wherein the liquid crystal is selected from the substituted biphenyls or triphenyls compounds family.

6. The composition according to claim 2, wherein the liquid crystal is in proportion of from 20 to 60% by weight of the composition.

7. The composition according to claim 2, wherein the grafted polymer is in proportion of from 10 to 40% by weight of the composition.

8. The composition according to claim 3, wherein the solvent is in proportion of from 10 to 40% by weight of the composition.

9. The composition according to claim 3, wherein the surfactant is in proportion of from 0 to 10% by weight of the composition.

10. A film formed from the composition according to claim 2.

11. A liquid crystal device comprising a film according to claim 10, said film being provided on a substrate.

12. The device according to claim 11, further comprising a second substrate, wherein the film is provided between both substrates.

13. The device according to claim 11, wherein the substrate is made of glass or plastic.

14. The device according to claim 12, further comprising an electrode layer on each substrate, in an adjacent position to the film.

15. An electro-optical system comprising a PDLC film provided between two electrode layers, said PDLC film comprising one or more liquid crystals forming microdroplets in a polymer matrix, said polymer matrix comprising a grafted polymer according to claim 1.

16. An electro-optical glazing comprising

a PDLC film provided between two transparent plates, said PDLC film comprising one or more liquid crystals forming microdroplets in a polymer matrix, said polymer matrix comprising a grafted polymer according to claim 1.

17. The electro-optical glazing according to claim 16, further comprising an electrode layer on each plate, in an adjacent position to said PDLC film.

18. The electro-optical glazing according to claim 16, wherein said plates are made of glass or plastic.

19. A window comprising a glazing according to claim 16.

20. A door comprising a glazing according to claim 16.

21. A roof comprising a glazing according to claim 16.

22. Glass comprising a glazing according to claim 16.

23. A method for the preparation of a product usually opaque that becomes transparent under the application of an electric field, comprising the steps of:

dispersing at least one liquid crystal in a grafted polymer according to claim 1.

24. The grafted polymer according to claim 1, wherein each R³, identical or different, represents a C_4-50 alkyl group, optionally substituted with one or more C_1-4 alkyl substituents.

25. The grafted polymer according to claim 1, wherein each R³, identical or different, represents a C_6-20 alkyl, optionally substituted with one or more C_1-4 alkyl substituents.

26. The grafted polymer according to claim 1, wherein m+n is between 1 and 150.

27. The grafted polymer according to claim 1, wherein the ratio between m and n is between 0.01/1 and 0.05/1.

28. The composition according to claim 6, wherein the liquid crystal is in proportion of from 20 to 40% by weight of the composition.