Biological Water Treatment by Alternating Continuous and Sequential Aeration

• US 20100065494A1
• Filed: 12/07/2007
• Published: 03/18/2010
• Est. Priority Date: 12/08/2006
• Status: Active Grant

• Current Assignee: Veolia Water Solutions & Technologies Support
• Original Assignee: Veolia Water Solutions & Technologies Support
• Inventors: Lemoine, Cyrille, Grelier, Patricia
• Granted Patent: US 8,110,109 B2
• Time in Patent Office: Days
• US Class Current: 210/614
• CPC Class Codes: C02F 2209/001 Upstream control, i.e. monitoring for predictive control
• CPC Class Codes: C02F 2209/14 NH3-N
• CPC Class Codes: C02F 2209/15 N03-N
• CPC Class Codes: C02F 2209/38 Gas flow rate
• CPC Class Codes: C02F 3/006 Regulation methods for biological treatment
• CPC Class Codes: Y02W 10/10 Biological treatment of water, waste water, or sewage
• CPC Class Codes: Y10S 210/903 Nitrogenous

Abstract

A water treatment method using a biological reactor to break down the nitrogen-based pollution contained in said water, said reactor comprising a biomass aerated by aeration means, said treatment comprising simultaneous nitrification/denitrification phases, characterized in that said treatment implements two aeration modes: a continuous aeration mode; a sequential aeration mode in which the aeration interruption is triggered when the ammonia concentration reaches a low predetermined threshold while the aeration is activated when the ammonia concentration reaches a high predetermined threshold, the switching from one aeration mode to the other being activated according to the nitrate concentration in said water, said continuous aeration mode being activated when said nitrate concentration reaches a low predetermined threshold, and said sequential aeration mode being activated when said nitrate concentration reaches a high predetermined threshold.

Claims

1-10. -10. (canceled)

11. A method for removing nitrogen from water comprising:

predetermining a high and a low threshold value for nitrate concentration in water;

predetermining a high and a low threshold value for ammoniac concentration in water;

measuring the nitrate concentration in the water;

activating a continuous aeration mode if the nitrate concentration reaches the predetermined low threshold value for the nitrate concentration, wherein the continuous aeration mode comprises;

aerating the water such that nitrification and denitrification reactions occur simultaneously in the water;

activating a sequential aeration mode if the nitrate concentration reaches the predetermined high threshold value for the nitrate concentration, wherein in the sequential aeration mode comprises;

measuring the ammoniac concentration in the water;

stopping aeration when the ammoniac concentration reaches the predetermined low threshold value for the ammoniac concentration;

initiating aeration when the ammoniac concentration reaches the predetermined high threshold high for the ammoniac concentration; and

maintaining the sequential aeration mode until the nitrate concentration reaches the predetermined low threshold value for the nitrate concentration and then activating the continuous aeration mode.

12. The method of claim 11 further comprising:

during the continuous aeration mode, stopping aeration when the nitrate concentration reaches the predetermined high threshold value for the nitrate concentration and activating the sequential aeration mode.

13. The method of claim 11 further comprising automatically switching between the continuous aeration mode and the sequential aeration mode.

14. The method of claim 11 wherein the continuous aeration mode is activated when the nitrate concentration is approximately 4 mg/L.

15. The method of claim 11 wherein the sequential aeration mode is activated when the nitrate concentration is approximately 10 mg/L.

16. The method of claim 11 wherein during the continuous aeration mode the method further comprises:

determining a first nitrate set point;

calculating a first ammoniac set point based on the first nitrate set point;

calculating a first dissolved oxygen set point based on the calculated first ammoniac set point; and

wherein when the nitrate concentration in the water reaches the first nitrate set point the amount of dissolved oxygen in the water is adjusted to the first dissolved oxygen set point to restore equilibrium between the nitrification and denitrification reactions.

17. The method of claim 16 wherein after the amount of dissolved oxygen is adjusted to the first dissolved oxygen set point, the method further comprises maintaining the first ammoniac set point for a first period of time.

18. The method of claim 17 further comprising maintaining the first dissolved oxygen set point for a second period of time.

19. The method of claim 18 wherein the first period of time is not equal to the second period of time.

20. The method of claim 16 further comprises:

determining a second nitrate set point that is higher than the first nitrate set point;

calculating a second ammoniac set point based on the second nitrate set point, the second ammoniac set point being higher than the first ammoniac set point;

calculating a second dissolved oxygen set point based on the calculated second ammoniac set point; and

wherein when the nitrate concentration in the water reaches the second nitrate set point, the amount of dissolved oxygen in the water is reduced to the second dissolved oxygen set point to restore equilibrium between the nitrification and denitrification reactions.

21. The method of claim 11 wherein during the sequential aeration mode, stopping of aeration occurs if the ammoniac concentration is below the predetermined low threshold value for the ammoniac concentration and the water has been aerated for a predetermined amount of time.

22. The method of claim 11 wherein during the sequential aeration mode, aeration occurs if the ammoniac concentration is above the predetermined high threshold high for the ammoniac concentration and the water has not been aerated for a predetermined amount of time.

23. The method of claim 16 further comprising:

directing water into a bioreactor;

directing water from the bioreactor to a membrane filtration zone; and

wherein measuring the nitrate concentration in the water occurs after the water has been treated in the membrane filtration zone.

24. The method of claim 11 further comprising:

directing water into a bioreactor;

directing water from the bioreactor to a membrane filtration zone;

wherein measuring the nitrate concentration in the water occurs after the water has been treated in the membrane filtration zone;

wherein during the continuous aeration mode the method further comprises;

determining first and second nitrate set points, the second nitrate set point being higher than the first nitrate set point;

calculating first and second ammoniac set points based on the first and second nitrate set points respectively, the second ammoniac set point being higher than the first ammoniac set point;

calculating first and second dissolved oxygen set points based on the calculated first and second ammoniac set points respectively; and

wherein when the nitrate concentration in the water reaches the first nitrate set point, the amount of dissolved oxygen in the water is increased to the first dissolved oxygen set point and when the nitrate concentration in the water reaches the second nitrate set point, the amount of dissolved oxygen in the water is reduced to the second dissolved oxygen set point.

25. The method of claim 24 wherein:

during the sequential aeration mode, stopping of aeration occurs if the ammoniac concentration is below the predetermined low threshold value for the ammoniac concentration and the water has been aerated for a predetermined amount of time;

during the sequential aeration mode, aeration occurs if the ammoniac concentration is above the predetermined high threshold high for the ammoniac concentration and the water has not been aerated for a predetermined amount of time.

26. A method of biologically removing nitrogen from water by nitrifying and denitrifying the water, the method comprising:

employing a continuous aeration mode and a sequential aeration mode wherein in the continuous aeration mode nitrifying and denitrifying reactions occur simultaneously in the water and wherein in the sequential aeration mode aeration is activated and deactivated;

activating the continuous aeration mode when the nitrate concentration in the water reaches a predetermined low threshold;

activating the sequential aeration mode when the nitrate concentration in the water reaches a predetermined high threshold; and

wherein when in the sequential aeration mode, aeration is deactivated when the ammoniac concentration reaches a predetermined low threshold and aeration is activated when the ammoniac concentration reaches a predetermined high threshold.

27. The method of claim 26 including activating the continuous aeration mode when the nitrate concentration decreases to a threshold of approximately 4 mg/l.

28. The method of claim 27 including activating the sequential aeration mode when the nitrate concentration in the water increases to a threshold of approximately 10 mg/l.

29. The method of claim 26 including limiting the time period of aeration during the sequential aeration mode.

30. The method of claim 26 wherein the continuous aeration mode involves a method of predictive control of the nitrate and ammoniac concentrations in the water.

31. The method of claim 30 wherein the predictive control method includes successive steps of regulating an ammoniac set point to be reached according to a nitrate set point to be reached.

32. The method of claim 31 wherein said predictive control method includes successive steps of regulating an aeration set point when said nitrate concentration reaches a predetermined high threshold.

33. The method of claim 32 wherein the steps of regulating the ammoniac set point and the step of regulating the aeration set point are timed.

34. The method of claim 33 wherein the steps of regulating the ammoniac set point and regulating the aeration set points are timed and staggered in time with respect to one another.

35. The method of claim 26 including calculating a first ammoniac set point based on a first nitrate set point;

calculating a first aeration set point based on the calculated ammoniac set point; and

wherein when the nitrate concentration in the water reaches the first nitrate set point, the aeration in the water is adjusted to the first aeration set point to restore equilibrium between the nitrification and denitrification reactions.

36. The method of claim 35 wherein after the aeration is adjusted to the first aeration set point, the method further includes maintaining the first ammoniac set point for a first period of time.

37. The method of claim 36 further including maintaining the first aeration set point for a second period of time.

38. The method of claim 35 further including:

calculating a second set ammoniac set point based on a second nitrate set point, the second ammoniac set point being higher than the first ammoniac set point;

calculating a second aeration set point based on the calculated second ammoniac set point; and

wherein when the nitrate concentration in the water reaches the second nitrate set point, the amount of aeration in the water is reduced to the second aertaion set point to generally restore equilibrium between the nitrification and denitrification reactions.

39. The method of claim 26 wherein during the continuous aeration mode the method includes:

determining first and second nitrate set points where the second nitrate set point is higher than the first nitrate set point;

calculating first and second ammoniac set points based on the first and second nitrate set points, respectively, the second ammoniac set point being higher than the first ammoniac set point;

calculating first and second aeration set points based on the calculated first and second ammoniac set points, respectively; and

wherein when the nitrate concentration in the water reaches the first nitrate set point, the amount of aeration in the water is increased to the first aeration set point and wherein when the nitrate concentration in the water reaches the second nitrate set point, the amount of aeration in the water is reduced to the second aeration set point.

40. The method of claim 39 wherein:

during the sequential aeration mode, ceasing aeration if the ammoniac concentration is below the predetermined low threshold value for the ammoniac concentration and the water has been aerated for a predetermined amount of time; and

during the sequential aeration mode, activating aeration if the ammoniac concentration is above the predetermined high threshold value for the ammoniac concentration and the water has been aerated for a predetermined amount of time.