POROUS BATTERY ELECTRODE FOR A RECHARGEABLE BATTERY AND METHOD OF MAKING THE ELECTRODE

• US 20100068623A1
• Filed: 10/07/2009
• Published: 03/18/2010
• Est. Priority Date: 04/09/2007
• Status: Active Grant

• Current Assignee: Board of Trustees of The University of Illinois
• Original Assignee: Board of Trustees of The University of Illinois
• Inventors: Yu, Xindi, Zhang, Hui Gang, Braun, Paul V.
• Granted Patent: US 8,237,538 B2
• Time in Patent Office: Days
• US Class Current: 429/219
• CPC Class Codes: C25F 3/02 Etching
• CPC Class Codes: H01M 10/345 Gastight metal hydride accumulators
• CPC Class Codes: H01M 4/0452 from solutions
• CPC Class Codes: H01M 4/131 Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
• CPC Class Codes: H01M 4/32 Nickel oxide or hydroxide electrodes
• CPC Class Codes: H01M 4/505 of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
• CPC Class Codes: H01M 4/66 Selection of materials
• CPC Class Codes: H01M 4/80 Porous plates, e.g. sintered carriers
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

A porous battery electrode for a rechargeable battery includes a monolithic porous structure having a porosity in the range of from about 74% to about 99% and comprising a conductive material. An active material layer is deposited on the monolithic porous structure. The pores of the monolithic porous structure have a size in the range of from about 0.2 micron to about 10 microns. A method of making the porous battery electrode is also described.

Claims

1. A highly porous battery electrode for a rechargeable battery, the battery electrode comprising:

a monolithic porous structure having a porosity in the range of from about 74% to about 99% and comprising a conductive material; and

an active material layer on the monolithic porous structure, wherein pores of the monolithic porous structure have a size in the range of from about 0.2 micron to about 10 microns.

2. The battery electrode of claim 1, wherein the conductive material comprises at least one of nickel, tungsten, aluminum, copper, gold, platinum, silver, cobalt, chromium, titanium, iron, molybdenum, hafnium, HfB₂, TiB₂, nickel silicide, manganese silicide, titanium silicide, cobalt silicide, tungsten silicide, titanium nitride, and zirconium nitride.

3. The battery electrode of claim 1, wherein the porosity is in the range of from about 80% to about 99%.

4. The battery electrode of claim 1, wherein the pores of the monolithic porous structure are interconnected.

5. The battery electrode of claim 1, wherein the pores of the monolithic porous structure have an aperiodic arrangement.

6. The battery electrode of claim 1, wherein the pores of the monolithic porous structure have a periodic arrangement.

7. The battery electrode of claim 6, wherein the periodic arrangement is a face centered cubic structure.

8. The battery electrode of claim 7, wherein a D/a ratio of the monolithic porous structure is in the range of from about 0.71 to about 0.82, D being the size of the pores and a being a periodic spacing of the face centered cubic arrangement.

9. The battery electrode of claim 1, wherein the pores are substantially spherical in shape and the size of the pores is a diameter of the pores.

10. The battery electrode of claim 1, wherein the size of the pores varies across the monolithic porous structure by no more than a factor of 10%.

11. The battery electrode of claim 1, wherein the active material layer comprises at least one of NiOOH, lithiated MnO₂, Si, and a Ni—

Sn alloy.

12. The battery electrode of claim 1, wherein the active material layer comprises a thickness of about 28% or less of the size of the pores.

13. The battery electrode of claim 12, wherein the active material layer comprises a thickness of about 10% or less of the size of the pores.

14. The battery electrode of claim 12, wherein the active material layer comprises a thickness of between about 5 nm and about 2 microns.

15. The battery electrode of claim 1, wherein ligaments of the monolithic porous structure between the pores have a width of between about 10 nm and about 700 nm.

16. A method of making a battery electrode, the method comprising:

providing a scaffold of interconnected elements separated by voids;

depositing a conductive material through the voids and onto the interconnected elements of the scaffold;

removing the scaffold to obtain a monolithic porous structure comprising the conductive material and including pores defined by the interconnected elements of the scaffold;

etching the monolithic porous structure to have a porosity in the range of from about 74% to about 97% and a pore size in the range of from about 0.2 micron to about 10 microns;

depositing an electrochemically active material on the monolithic porous structure, thereby forming a battery electrode.

17. The method of claim 16, wherein etching the monolithic porous structure comprises electrochemical etching.

18. The method of claim 16, wherein each of depositing the conductive material and depositing the electrochemically active material comprises sol-gel processing.

19. The method of claim 16, wherein each of depositing the conductive material and depositing the electrochemically active material comprises electrodeposition.

20. The method of claim 19, wherein electrodeposition of the electrochemically active material comprises immersion of the monolithic porous structure in a solution including at least one of nickel sulfate and manganese sulfate.

21. The method of claim 19, wherein electrodeposition of the electrochemically active material is carried out using one of galvanostatic pulses and potential pulses.

22. The method of claim 21, wherein electrodeposition of the electrochemically active material is carried out using potential pulses ranging from 0.7 volts to 1.2 volts.

23. The method of claim 22, wherein the potential pulses range in duration from about 100 ms to 20 s, and an interval between pulses ranges from about 0.5 s to about 200 s.

24. A method of making a battery electrode, the method comprising:

providing a scaffold of interconnected elements separated by voids;

depositing a conformal material through the voids onto the interconnected elements of the scaffold;

depositing a conductive material through the voids and onto the conformal material;

removing the scaffold and the conformal material to obtain a monolithic porous structure comprising the conductive material and including pores defined by the interconnected elements of the scaffold and the overlying conformal material, the monolithic porous structure having a porosity in the range of from about 74% to about 99% and a pore size in the range of from about 0.2 micron to about 10 microns;

depositing an electrochemically active material on the monolithic porous structure, thereby forming a battery electrode.

25. The method of claim 24, wherein the depositing of the conformal material, the conductive material, and the electrochemically active material comprise at least one of atomic layer deposition and chemical vapor deposition.

26. The method of claim 24, wherein the conformal material comprises one of SiO₂ and Al₂O₃.