Smooth surface ceramic composites

• US 20100081350A1
• Filed: 09/30/2008
• Published: 04/01/2010
• Est. Priority Date: 09/30/2008
• Status: Abandoned Application

• Current Assignee: Teledyne Scientific & Imaging, LLC (Teledyne Technologies Incorporated)
• Original Assignee: Teledyne Scientific & Imaging, LLC (Teledyne Technologies Incorporated)
• Inventors: McCabe, Brock S., Marshall, David B.
• Application Number:
  US12/286,660
• Publication Number:
  US 20100081350A1
• Time in Patent Office: Days
• US Class Current: 442/127
• CPC Class Codes: C04B 2235/5224 Alumina or aluminates
• CPC Class Codes: C04B 2235/5228 Silica and alumina, including aluminosilicates, e.g. mullite
• CPC Class Codes: C04B 2235/5244 Silicon carbide
• CPC Class Codes: C04B 2235/5248 Carbon, e.g. graphite
• CPC Class Codes: C04B 2235/5256 Two-dimensional, e.g. woven structures
• CPC Class Codes: C04B 2235/5272 Fibers of the same material with different length or diameter
• CPC Class Codes: C04B 2235/5276 Whiskers, spindles, needles or pins
• CPC Class Codes: C04B 2235/614 Gas infiltration of green bodies or pre-forms
• CPC Class Codes: C04B 2235/616 Liquid infiltration of green bodies or pre-forms
• CPC Class Codes: C04B 35/565 based on silicon carbide
• CPC Class Codes: C04B 35/62868 Boron nitride
• CPC Class Codes: C04B 35/62873 Carbon
• CPC Class Codes: C04B 35/62881 with metal salts, e.g. phosphates
• CPC Class Codes: C04B 35/80 Fibres, filaments, whiskers, platelets, or the like
• CPC Class Codes: Y10T 442/2557 Oxygen or ozone resistant
• CPC Class Codes: Y10T 442/2975 Coated or impregnated ceramic fiber fabric
• CPC Class Codes: Y10T 442/2984 Coated or impregnated carbon or carbonaceous fiber fabric

Abstract

A method of making a smooth surfaced, fiber reinforced ceramic matrix composite includes the steps of providing a fiber preform, the preform having a surface containing voids; placing fibers into the voids; coating the preform fibers and the void fibers with a coating material to create a weak interface; and infiltrating the coated fibers with a matrix material to infill the voids and preform, and form strongly bonded networks within the voids. Alternatively, the resulting smooth surfaced, fiber reinforced ceramic matrix composite may include, in addition to the first coating material on the preform fibers and the void fibers and the matrix material within the coated fibers and the preform to infill the voids and preform, a second coating material on the preform fibers and the void fibers, creating a second coating of substantially uniform thickness on the fibers and forming strongly bonded networks within the voids.

Claims

1. A method of making a smooth surfaced, fiber reinforced ceramic matrix composite, comprising:

providing a fiber preform, the preform having a surface containing voids;

placing fibers into the voids;

coating the preform fibers and the void fibers with a coating material to create a weak interface; and

infiltrating the coated fibers with a matrix material to infill the voids and preform, and form strongly bonded networks within the voids.

2. The method of claim 1, wherein the fiber preform includes interlaced bundles of fiber tows, with the voids between the interlaced bundles.

3. The method of claim 2, wherein the fiber preform is a woven preform.

4. The method of claim 2, wherein the fiber preform is a braided preform.

5. The method of claim 2, wherein the fiber preform is a sewn preform.

6. The method of claim 1, wherein the preform fibers are selected to be chemically compatible with the coating material and the matrix material.

7. The method of claim 6, wherein the preform fibers are selected from the group consisting of carbon, silicon carbide, aluminum oxide, and mullite.

8. The method of claim 1, wherein the dimensions of the void fibers are selected to divide the voids into volumes sufficiently small to inhibit cracking and debonding within the composite.

9. The method of claim 8, wherein the void fibers are chopped fibers.

10. The method of claim 8, wherein the void fibers are whiskers.

11. The method of claim 8, wherein the step of placing fibers into the voids comprises growing void fibers directly on the fiber preform.

12. The method of claim 1, wherein the void fibers are selected to be chemically compatible with the coating material and the matrix material.

13. The method of claim 1, wherein the void fibers are selected from the group consisting of carbon, silicon carbide, aluminum oxide, and mullite.

14. The method of claim 1, wherein the coating material is a weak coating material.

15. The method of claim 14, wherein the coating material is selected to weakly bond with the preform fibers and with the void fibers.

16. The method of claim 14, wherein the coating material is selected to weakly bond with the matrix material.

17. The method of claim 1, wherein the coating material is selected to avoid reacting with the preform fibers, with the void fibers, and with the matrix material.

18. The method of claim 1, wherein the coating material is selected from the group consisting of pyrolytic carbon, boron nitride, monazites, and xenotime.

19. The method of claim 1, wherein the matrix material is selected from the group consisting of refractory carbides, borides and oxides.

20. The method of claim 1, wherein the step of infiltrating the coated fibers further comprises infiltrating the coated fibers via chemical vapor infiltration.

21. The method of claim 1, wherein the step of infiltrating the coated fibers further comprises infiltrating the coated fibers via infiltration of a slurry comprising particles in a liquid precursor.

22. The method of claim 1, wherein the step of infiltrating the coated fibers further comprises infiltrating the coated fibers via an in situ reaction of molten silicon with carbon to form SiC.

23. The method of claim 1, wherein the matrix material is selected from the group consisting of SiC, carbides, borides, oxides, and silicides.

24. The method of claim 23, wherein constituents are added to the matrix material to improve oxidation resistance.

25. The method of claim 24, wherein the added constituents are selected from the group consisting of carbides, B-containing compounds, silicides, and glasses.

26. The method of claim 1, further comprising the step of removing material from the surface of the ceramic matrix composite to smooth the surface.

27. The method of claim 26, wherein the step of removing material comprises grinding the surface.

28. The method of claim 26, wherein the step of removing material comprises chemically polishing the surface.

29. The method of claim 1, further comprising, after the step of placing fibers into the voids, the step of defining the boundaries of the void fibers to further ensure a smooth surfaced composite.

30. A method of making a smooth surfaced, fiber reinforced ceramic matrix composite, comprising:

providing a fiber preform, the preform having a surface containing voids;

placing fibers into the voids;

coating the preform fibers and the void fibers with a first coating material to create a weak interface;

coating the preform fibers and the void fibers with a second coating material to create a second coating of substantially uniform thickness on the fibers and form strongly bonded networks within the voids; and

infiltrating the networks and coated fibers with a matrix material to infill the voids and preform.

31. A smooth surfaced, fiber reinforced ceramic matrix composite, comprising:

a fiber preform, the preform having a surface containing voids;

void fibers in the voids;

a coating material on the preform fibers and the void fibers creating a weak interface; and

a matrix material within the coated fibers and the preform to infill the voids and preform, and form strongly bonded networks within the voids.

32. The composite of claim 31, wherein the fiber preform includes interlaced bundles of fiber tows, with the voids between the interlaced bundles.

33. The composite of claim 32, wherein the fiber preform is a woven preform.

34. The composite of claim 32, wherein the fiber preform is a braided preform.

35. The composite of claim 32, wherein the fiber preform is a sewn preform.

36. The composite of claim 31, wherein the preform fibers are selected to be chemically compatible with the coating material and the matrix material.

37. The composite of claim 36, wherein the preform fibers are selected from the group consisting of carbon, silicon carbide, aluminum oxide, and mullite.

38. The composite of claim 31, wherein the dimensions of the void fibers are selected to divide the voids into volumes sufficiently small to inhibit cracking and debonding within the composite.

39. The composite of claim 38, wherein the void fibers are chopped fibers.

40. The composite of claim 38, wherein the void fibers are whiskers.

41. The composite of claim 38, wherein the void fibers are grown directly on the fiber preform.

42. The composite of claim 31, wherein the void fibers are selected to be chemically compatible with the coating material and the matrix material.

43. The composite of claim 31, wherein the void fibers are selected from the group consisting of carbon, silicon carbide, aluminum oxide, and mullite.

44. The composite of claim 31, wherein the coating material is a weak coating material.

45. The composite of claim 44, wherein the coating material is selected to weakly bond with the preform fibers and with the void fibers.

46. The composite of claim 44, wherein the coating material is selected to weakly bond with the matrix material.

47. The composite of claim 31, wherein the coating material is selected to avoid reacting with the preform fibers, with the void fibers, and with the matrix material.

48. The composite of claim 31, wherein the coating material is selected from the group consisting of pyrolytic carbon, boron nitride, monazites, and xenotime.

49. The composite of claim 31, wherein the matrix material is selected from the group consisting of refractory carbides, borides and oxides.

50. The composite of claim 31, wherein the matrix material is selected from the group consisting of SiC, carbides, borides, oxides, and silicides.

51. The composite of claim 50, wherein constituents are added to the matrix material to improve oxidation resistance.

52. The composite of claim 51, wherein the added constituents are selected from the group consisting of carbides, B-containing compounds, silicides, and glasses.

53. A smooth surfaced, fiber reinforced ceramic matrix composite, comprising:

a fiber preform, the preform having a surface containing voids;

void fibers in the voids;

a first coating material on the preform fibers and the void fibers, creating a weak interface;

a second coating material on the preform fibers and the void fibers, creating a second coating of substantially uniform thickness on the fibers and forming strongly bonded networks within the voids; and

a matrix material within the coated fibers and the preform to infill the voids and preform.