SPIN-COATED POLYMER MICROCAVITY FOR LIGHT EMITTERS AND LASERS

• US 20100097691A1
• Filed: 09/28/2007
• Published: 04/22/2010
• Est. Priority Date: 09/28/2006
• Status: Abandoned Application

• Current Assignee: City College of New York
• Original Assignee: City College of New York
• Inventors: Memon, Vinod M., Valappil, Nikesh V.
• Application Number:
  US12/443,284
• Publication Number:
  US 20100097691A1
• Time in Patent Office: Days
• US Class Current: 359/346
• CPC Class Codes: C09K 11/02 Use of particular materials as binders, particle coatings or suspension media therefor
• CPC Class Codes: C09K 11/565 with zinc cadmium
• CPC Class Codes: C09K 11/88 containing selenium, tellurium or unspecified chalcogen elements
• CPC Class Codes: C09K 11/883 with zinc or cadmium
• CPC Class Codes: H01S 3/0612 Non-homogeneous structure H01S3/07 takes precedence
• CPC Class Codes: H01S 3/0621 Coatings on the end-faces, e.g. input/output surfaces of the laser light
• CPC Class Codes: H01S 3/0627 the resonator being monolithic, e.g. microlaser
• CPC Class Codes: H01S 3/169 Nanoparticles, e.g. doped nanoparticles acting as a gain material
• CPC Class Codes: H01S 3/178 plastic

Abstract

A spin-coated polymer microcavity for light emitters and lasers producing enhancement of spontaneous emission rate from colloidal CdSe/ZnS core/shell quantum dots embedded in a one dimensional polymer microcavity structure at room temperature. The polymer microcavity structures are fabricated using spin coating. Alternating layers of polymers of two different refractive indices were stacked to form the Distributed Bragg reflectors (DBRs). To achieve high reflectivity, the polymers for the DBR structures were chosen so that they have a relatively high refractive index ratio. The high and low refractive index polymers chosen were poly-N(vinylcarbazole) (PVK) and poly acrylic acid (PAA), with refractive indices of 1.683 and 1.420 at 600 nm, respectively. Thin films of quarter wavelength thickness of the two polymers are alternately spin coated on a glass substrate to make the DBR structures. Greater than 90% reflectivity is obtained using ten periods of the structure. A PVK cavity layer of λ thickness embedded with CdSe/ZnS core/shell quantum dots is sandwiched between two of these DBRs to form the entire microcavity structure. The bottom and top DBRs comprise ten and five periods, respectively.

Claims

1. A spin-coated polymer microcavity for light emitters and lasers, comprising:

a) a pair of distributed Bragg reflectors; and

b) a microcavity structure;

wherein said microcavity structure is sandwiched between said pair of distributed Bragg reflectors;

wherein said pair of distributed Bragg reflectors comprise alternating layers of polymers of two different refractive indices;

wherein said polymers have a relatively high refractive index ratio for achieving high reflectivity; and

wherein said microcavity structure Comprises a layer of said polymer having a higher refractive index than that of the other polymer and being embedded with quantum dots.