METHODS AND APPARATUS FOR STIMULATING AND MANAGING POWER FROM MICROBIAL FUEL CELLS

• US 20100119879A1
• Filed: 09/20/2007
• Published: 05/13/2010
• Est. Priority Date: 09/20/2006
• Status: Abandoned Application

• Current Assignee: President and Fellows of Harvard College (Harvard Corporation)
• Original Assignee: President and Fellows of Harvard College (Harvard Corporation)
• Inventors: Kauffman, Peter Carr, Girguis, Peter Riad
• Application Number:
  US12/311,165
• Publication Number:
  US 20100119879A1
• Time in Patent Office: Days
• US Class Current: 429/2
• CPC Class Codes: H01M 16/006 of fuel cells with rechargeable batteries
• CPC Class Codes: H01M 2300/0071 Oxides
• CPC Class Codes: H01M 4/8605 Porous electrodes
• CPC Class Codes: H01M 4/8839 Painting
• CPC Class Codes: H01M 4/8878 Treatment steps after deposition of the catalytic active composition or after shaping of the electrode being free-standing body
• CPC Class Codes: H01M 4/96 Carbon-based electrodes
• CPC Class Codes: H01M 8/0234 Carbonaceous material
• CPC Class Codes: H01M 8/0245 in the form of layered or coated products
• CPC Class Codes: H01M 8/04007 related to heat exchange
• CPC Class Codes: H01M 8/04201 Reactant storage and supply, e.g. means for feeding, pipes
• CPC Class Codes: H01M 8/04544 Voltage
• CPC Class Codes: H01M 8/04559 of fuel cell stacks
• CPC Class Codes: H01M 8/04567 of auxiliary devices, e.g. batteries, capacitors
• CPC Class Codes: H01M 8/0488 of fuel cell stacks
• CPC Class Codes: H01M 8/1016 characterised by the electrolyte material H01M8/12 takes precedence
• CPC Class Codes: H01M 8/16 Biochemical fuel cells, i.e. cells in which microorganisms function as catalysts
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

Inventive aspects of the present disclosure generally relates to fuel cells and, in particular, to fuel cells that can use microorganisms (microbes) to oxidize fuel. Certain aspects are directed to fuel cells that operate at relatively elevated temperatures. Such temperatures, for example, can increase the metabolisms of the microorganisms within the fuel cell. The elevated temperatures may be achieved, for instance, by using a thermal insulator, such as a vacuum jacket. Microorganism metabolism may also be improved, in some aspects of the invention, by exposing the microorganisms to growth promoters such as fertilizer, nitrogen sources, biomass, etc. The microorganisms, in some embodiments of the invention, may be anaerobic or microaerophilic and can be obtained, for example, from the soil, compost, peat, sewage, bogs, wastewater, or other organic-rich matrices. Another inventive aspect relates to novel electrodes for use in fuel cells, such as microbial fuel cells. The electrode, in some cases, may be flexible and/or porous. In certain embodiments, the electrode may be treated, e.g., with acid and/or biomass, to improve performance. Such treatments may facilitate microorganism metabolism. Yet another inventive aspect relates to a proton exchange interface between an anode and a cathode in a fuel cell, such as a microbial fuel cell. The proton exchange interface may be designed to allow protons and/or gases to pass through, but, in some cases, minimizes or eliminates mixing between the anode and the cathode. Still another inventive aspect generally relates to an energy management system for use with such fuel cells, including microbial fuel cells. Yet another aspect relates to switching systems that allow a plurality of fuel cells (which may be housed in one vessel or separate vessels) to sustain net power output that is greater than the sum of the individual microbial fuel cells under constant load. In some cases, the energy management system can store and manage energy from the fuel cell such that conventional operating voltages may be provided to a variety of loads having various instantaneous and average power requirements. Other inventive aspects relate to techniques for forming such fuel cells and fuel cell components, techniques for using such fuel cells, systems involving such fuel cells, and the like:

Claims

1-169. -169. (canceled)

170. An energy management apparatus for at least one microbial fuel cell, the apparatus comprising:

at least one first energy storage component or load to store first energy provided by the at least one microbial fuel cell; and

a comparator circuit, coupled to the at least one first energy storage component or load, to compare a first voltage across the at least one first energy storage component or load to a first set point, the comparator circuit configured to implement a hysteresis window defined by a first predetermined level above the first set point and a second predetermined level below the first set point, such that an output of the comparator circuit changes from a first logic state to a second logic state when the first voltage is at or above the first predetermined level, and the output of the comparator circuit changes from the second logic state to the first logic state when the first voltage is at or below the second predetermined level.

171. The energy management apparatus of claim 170, further comprising:

a voltage conversion circuit, coupled to the comparator circuit, to convert the first voltage to a second voltage higher than the first voltage, the voltage conversion circuit being activated in response to the second logic state and deactivated in response to the first logic state.

172. The energy management apparatus of claim 170, further comprising:

at least one second energy storage component or load, coupled to the voltage conversion circuit, to store second energy provided by the second voltage, wherein the at least one second energy storage component or load provides output power.

173. The apparatus of claim 172, further comprising:

a power supply circuit, coupled to the at least one first energy storage component or load, to provide operating power for at least the comparator circuit and the voltage conversion circuit based only upon the first voltage when the second voltage is insufficient to provide the operating power for at least the comparator circuit and the voltage conversion circuit, wherein the power supply circuit comprises at least one zero-threshold component.

174. The apparatus of claim 172, further comprising at least one battery to provide operating power for at least the comparator circuit and the voltage conversion circuit when the second voltage is insufficient to provide the operating power for at least the comparator circuit and the voltage conversion circuit.

175. The apparatus of claim 171, wherein the voltage conversion circuit comprises:

a step-up transformer including a primary winding and a secondary winding;

a rectifier having a rectifier input coupled to the secondary winding and a rectifier output to provide the second voltage;

an oscillator circuit, coupled to the comparator circuit, to provide an oscillating signal only in response to the second logic state so as to activate the voltage conversion circuit; and

a switching circuit coupled to the oscillator circuit, the at least one first energy storage component or load, and the primary winding of the step-up transformer, the switching circuit applying to the primary winding, in response to the oscillating signal, alternating polarities of the first voltage across the at least one first energy storage component or load.

176. The apparatus of claim 172, further comprising a voltage cutout circuit coupled to the at least one second energy storage component or load to disconnect the at least one second energy storage component or load from out-putting power when the second voltage is at or below a second set point.

177. The apparatus of claim 172, further comprising a voltage feedback circuit coupled to the at least one second energy storage component or load to deactivate the voltage conversion circuit when the second voltage is at or above a third set point.

178. The apparatus of claim 172, wherein the at least one microbial fuel cell includes a plurality of microbial fuel cells, and wherein the apparatus further comprises:

a timing circuit to sequentially couple the plurality of microbial fuel cells to the at least one first energy storage component or load.

179. The apparatus of claim 172, further comprising a microprocessor or microcontroller to monitor the first voltage and/or the second voltage.

180. The apparatus of claim 179, wherein the microprocessor further monitors a reference voltage provided by a reference electrode, makes a comparison of the reference voltage and an anode potential and/or a cathode potential associated with the first voltage, and controls the anode potential and/or the cathode potential based at least in part on the comparison.

181. The apparatus of claim 179, wherein the at least one microbial fuel cell includes a plurality of microbial fuel cells, and wherein the apparatus further comprises:

a coupling circuit to couple the plurality of microbial fuel cells to the at least one first energy storage component or load,

wherein the microprocessor controls the coupling circuit so as to sequentially couple the plurality of microbial fuel cells to the at least one first energy storage component or load.

182. The apparatus of claim 181, wherein the microprocessor controls the coupling circuit to couple each microbial fuel cell of the plurality of microbial fuel cells to the at least one first energy storage component or load for a first time period.

183. An energy management method for at least one microbial fuel cell, comprising:

A) intermittently coupling the at least one microbial fuel cell to a load that draws current from the at least one microbial fuel cell.

184. The method of claim 183, wherein A) comprises:

B) coupling the at least one microbial fuel cell to the load for a first time period; and

C) decoupling the at least one microbial fuel cell from the load for a second time period.

185. The method of claim 184, wherein B) comprises:

determining the first time period based at least in part on an instantaneous power output of the at least one microbial fuel cell and a charging rate of at least one first energy storage component of the load to which the at least one microbial fuel cell is coupled in B).

186. The method of claim 184, wherein the at least one microbial fuel cell includes at least a first microbial fuel cell and a second microbial fuel cell, and wherein A) further comprises:

sequentially coupling the first microbial fuel cell and the second microbial fuel cell to the load.

187. The method of claim 186, wherein:

B) comprises coupling the first microbial fuel cell to the load at a first time for the first time period;

C) comprises decoupling the first microbial fuel cell from the load for the second time period, and wherein the method further comprises;

D) coupling the second microbial fuel cell to the load, at a second time different from the first time, for the first time period; and

E) decoupling the second microbial fuel cell from the load for the second time period.

188. An energy management apparatus for at least one microbial fuel cell, the apparatus comprising:

at least one input energy storage device to receive first energy from a cathode and an anode of the at least one microbial fuel cell; and

a switching circuit to intermittently couple the anode and/or the cathode of the at least one microbial fuel cell to a load based at least in part on a voltage potential between the anode and the cathode of the at least one microbial fuel cell.

189. The power management apparatus of claim 188, further comprising at least one output energy storage device to receive second energy from an output of the switching circuit, wherein the at least one output energy storage device provides output power to the load.