MULTIPLE GASIFIERS MANIFOLDED TO MULTIPLE FISCHER-TROPSCH REACTORS WITH OPTIONAL RECYCLE TO THE REACTORS

• US 20100125107A1
• Filed: 11/11/2009
• Published: 05/20/2010
• Est. Priority Date: 11/17/2008
• Status: Abandoned Application

• Current Assignee: Res Usa, Llc (Rentech, Inc.)
• Original Assignee: Rentech, Inc.
• Inventors: HOGSETT, Robert F., LEE, Joshua G., IBSEN, Mark, WRIGHT, Harold A.
• Application Number:
  US12/616,255
• Publication Number:
  US 20100125107A1
• Time in Patent Office: Days
• US Class Current: 518/702
• CPC Class Codes: C10G 2/32 with the use of catalysts
• CPC Class Codes: C10J 2300/1659 to liquid hydrocarbons Fischer-Tropsch process C10G2/00
• CPC Class Codes: C10J 3/721 Multistage gasification, e.g. plural parallel or serial gasification stages
• CPC Class Codes: C10J 3/723 Controlling or regulating the gasification process
• CPC Class Codes: C10K 1/004 Sulfur containing contaminants, e.g. hydrogen sulfide
• CPC Class Codes: Y02E 60/32 Hydrogen storage

Abstract

A method of producing synthesis gas via gasification in a Fischer-Tropsch plant, the method including providing a number of gasifiers, the number of gasifiers provided being at least one more than the base number required to provide 100% plant capacity of synthesis gas when each gasifier is operated at 100% gasifier capacity. A method of continually producing synthesis gas via gasification of a carbonaceous feed in a Fischer-Tropsch plant by providing a number of gasifiers, the number of gasifiers provided being at least one more than the base number required to provide 100% plant capacity of synthesis gas when each gasifier is operated at 100% gasifier capacity; and adjusting the amount of synthesis gas produced by adjusting the number of online gasifiers, the flow rate of carbonaceous feed to each gasifier, or a combination thereof. A system for carrying out the method is also provided.

Claims

1. A method of producing synthesis gas via gasification in a Fischer-Tropsch plant, the method comprising:

providing a number of gasifiers, the number of gasifiers provided being at least one more than the base number required to provide 100% plant capacity of synthesis gas when each gasifier is operated at 100% gasifier capacity.

2. The method of claim 1 further comprising normally operating all of the number of gasifiers at a capacity whereby greater than 100% of the synthesis gas required by the plant is produced.

3. The method of claim 2 further comprising storing the surplus synthesis gas in a tank.

4. The method of claim 2 further comprising storing the surplus synthesis gas in a salt dome.

5. The method of claim 1 further comprising normally operating each of the number of gasifiers at less than 100% gasifier capacity while maintaining 100% Fischer-Tropsch plant capacity.

6. A method of continually producing synthesis gas via gasification of a carbonaceous feed in a Fischer-Tropsch plant, the method comprising:

providing a number of gasifiers, the number of gasifiers provided being at least one more than the base number required to provide 100% plant capacity of synthesis gas when each gasifier is operated at 100% gasifier capacity; and

adjusting the amount of synthesis gas produced by adjusting the number of online gasifiers, the flow rate of carbonaceous feed to each gasifier, or a combination thereof.

7. The method of claim 6 wherein adjusting the amount of synthesis gas produced further comprises taking at least one gasifier offline and increasing the amount of synthesis gas produced by the remaining online gasifiers such that 100% Fischer-Tropsch plant capacity is maintained.

8. A method of maintaining full production of product in a Fischer-Tropsch process, the method comprising:

manifolding a plurality of Fischer-Tropsch reactors to a plurality of gasifiers in a Fischer-Tropsch process having a required synthesis gas production flow rate for full capacity, whereby the plurality of gasifiers minus one is capable of producing the required synthesis gas flow rate, and wherein the plurality of Fischer-Tropsch reactors minus one is capable of producing full capacity of product.

9. The method of claim 8 wherein the turndown capacity of each of the plurality of Fischer-Tropsch reactors is such that a single Fischer-Tropsch reactor is capable of being operated with an amount of synthesis gas produced by one of the plurality of gasifiers during startup.

10. The method of claim 8 further comprising recycling at least a portion of a Fischer-Tropsch tail gas produced in the Fischer-Tropsch reactors to at least one of the Fischer-Tropsch reactors via at least one recycle compressor.

11. The method of claim 10 wherein the number of recycle compressors is less than the number of Fischer-Tropsch reactors.

12. The method of claim 8 wherein, during startup, a single gasifier and a single Fischer-Tropsch reactor may be brought online prior to the remaining Fischer-Tropsch reactors and the remaining gasifiers being brought online.

13. The method of claim 8 further comprising:

introducing the synthesis gas produced in the gasifiers to at least one acid gas removal unit upstream of the plurality of Fischer-Tropsch reactors; and

introducing at least a portion of the Fischer-Tropsch product from the plurality of Fischer-Tropsch reactors into at least one product upgrading unit.

14. The method of claim 13 wherein, during startup, a single gasifier, a single acid gas removal unit, a single Fischer-Tropsch reactor, and a single product upgrading unit may be brought online prior to the remaining units being brought online.

15. The method of claim 13 wherein introducing the synthesis gas produced in the gasifiers to at least one acid gas removal unit comprises introducing the synthesis gas produced in the gasifiers into a plurality of acid gas removal units, wherein at least one Fischer-Tropsch reactor, at least one gasifier, and at least one acid gas removal unit may be taken offline while maintaining full plant capacity.

16. The method of claim 13 further comprising introducing at least a portion of the Fischer-Tropsch product into a storage unit if the amount of Fischer-Tropsch product produced in the plurality of Fischer-Tropsch reactors is greater than the capacity of the online product upgrading units.

17. The method of claim 8 comprising utilization of at least 6 Fischer-Tropsch reactors and at least 5 gasifiers.

18. The method of claim 17 further comprising utilization of at least two product upgrading units.

19. The method of claim 18 further comprising utilization of at least two acid gas removal units.

20. A Fischer-Tropsch system comprising:

a plurality of gasifiers manifolded together, wherein the plurality of gasifiers have a synthesis gas production capacity greater than the required synthesis gas for operation of the Fischer-Tropsch system at full capacity, whereby at least one of the plurality of gasifiers may be taken offline and the remaining gasifiers ramped up to maintain full plant production.

21. The system of claim 20 further comprising at least one of acid gas removal unit downstream of the plurality of gasifiers for the removal of sulfur.

22. The system of claim 21 comprising a plurality of acid gas removal units.

23. The Fischer-Tropsch system of claim 20 further comprising a plurality of Fischer-Tropsch reactors manifolded to the plurality of gasifiers, whereby at least one of the plurality of reactors may be taken offline and the remaining reactors ramped up to maintain full plant production.

24. The system of claim 23 further comprising a number of recycle compressors adapted to return Fischer-Tropsch tail gas to at least one of the Fischer-Tropsch reactors, wherein the number of recycle compressors is at least one less than the number of Fischer-Tropsch reactors.

25. The system of claim 24 wherein the system comprises at least 4 Fischer-Tropsch reactors and at least two recycle compressors.

26. The system of claim 23 further comprising at least one product upgrading unit downstream of the plurality of Fischer-Tropsch reactors.

27. The system of claim 26 further comprising storage for Fischer-Tropsch product should at least one product upgrading unit be taken offline.

28. The system of claim 26 comprising a single product upgrading unit and storage for Fischer-Tropsch product should the single product upgrading unit be taken offline

29. The system of claim 26 further comprising at least 2 acid gas removal units and comprising at least 5 gasifiers, at least 4 Fischer-Tropsch reactors, and at least one product upgrading unit.