Composition Including Carbon Nanotubes and Transparent and Conductive Film

• US 20100136343A1
• Filed: 05/11/2009
• Published: 06/03/2010
• Est. Priority Date: 11/09/2006
• Status: Abandoned Application

• Current Assignee: Cheil Industries Incorporated (Samsung Group)
• Original Assignee: Cheil Industries Incorporated (Samsung Group)
• Inventors: LEE, Young Hee, LEE, Young Jun, CHANG, Youngkyu, LEE, Young Sil
• Application Number:
  US12/463,531
• Publication Number:
  US 20100136343A1
• Time in Patent Office: Days
• US Class Current: 428/412
• CPC Class Codes: C08K 2201/001 Conductive additives
• CPC Class Codes: C08K 3/041 Carbon nanotubes
• CPC Class Codes: C09D 127/18 Homopolymers or copolymers of tetrafluoroethene
• CPC Class Codes: C09D 5/24 Electrically-conducting paints conductive materials H01B1/00
• CPC Class Codes: C09D 7/61 inorganic
• CPC Class Codes: Y10T 428/31507 Of polycarbonate
• CPC Class Codes: Y10T 428/31855 Of addition polymer from unsaturated monomers

Abstract

Disclosed are a composite composition comprising carbon nanotubes and a transparent conductive film using the composite composition. The composite composition comprises a solution of an ion conductive polymeric binder in a solvent and carbon nanotubes dispersed in the solution. The transparent conductive film is formed by coating a dispersion of carbon nanotubes in an ion conductive polymeric binder on a base film to allow the transparent conductive film to be electrically conductive as a whole. The composite composition can be used to form a transparent conductive film with excellent bending properties as well as high electrical conductivity and high transparency. Therefore, the composite composition can be applied to transparent electrodes for use in foldable flat panel displays.

Claims

1. A composite composition comprising a solution of an ion conductive polymeric binder in a solvent and carbon nanotubes dispersed in the solution.

2. The composite composition according to claim 1, wherein the ion conductive polymeric binder is hydrophobic.

3. The composite composition according to claim 1, wherein the ion conductive polymeric binder comprises a fluorinated polyethylene having sulfonyl groups introduced therein, a thermoplastic polymer having an alkyl or allyl moiety as a main chain and having one or more carboxyl, sulfonyl, phosphonyl or sulfonimide groups introduced therein, or a combination thereof.

4. The composite composition according to claim 3, wherein said thermoplastic polymer comprises polyester, polyethersulfone, polyetherketone, polyurethane, polyphosphagen, or a combination thereof.

5. The composite composition according to claim 4, wherein said thermoplastic polymer further comprises one or more fluoro groups.

6. The composite composition according to claim 1, wherein the carbon nanotubes include about 90% by weight or more of single-walled or double-walled carbon nanotubes, and have an outer diameter of about 1 to about 4 nm and a length of about 10 to about 1,000 nm.

7. The composite composition according to claim 1, wherein the solvent comprises water, an alcohol, or a combination thereof.

8. The composite composition according to claim 1, wherein the solvent is a mixed solution of water and isopropyl alcohol.

9. The composite composition according to claim 1, wherein the solvent is a mixed solution of water and isopropyl alcohol in a volume ratio (vol %) of about 20-80:

80-20.

10. A transparent conductive film formed by coating a dispersion of carbon nanotubes in an ion conductive polymeric binder on a base film.

11. The transparent conductive film according to claim 10, wherein said film is substantially uniformly electrically conductive.

12. The transparent conductive film according to claim 10, wherein the ion conductive polymeric binder is hydrophobic.

13. The transparent conductive film according to claim 10, wherein the ion conductive polymeric binder comprises a fluorinated polyethylene having sulfonyl groups introduced therein, a thermoplastic polymer having an alkyl or allyl moiety as a main chain and having one or more carboxyl, sulfonyl, phosphonyl or sulfonimide groups introduced therein, or a combination thereof.

14. The transparent conductive film according to claim 13, wherein said thermoplastic polymer comprises polyester, polyethersulfone, polyetherketone, polyurethane, polyphosphagen, or a combination thereof.

15. The transparent conductive film according to claim 14, wherein said thermoplastic polymer further comprises one or more fluoro groups.

16. The transparent conductive film according to claim 10, wherein the carbon nanotubes include about 90% by weight or more of single-walled or double-walled carbon nanotubes.

17. The transparent conductive film according to claim 10, wherein the transparent conductive film has a transparency of about 80% or more and a surface resistance of about 1,000 Ω

/sq. or less.

18. The transparent conductive film according to claim 10, wherein the base film comprises a polyester polymer film, a polycarbonate polymer film, a polyethersulfone polymer film, an acrylic polymer film, or a combination thereof.

19. The transparent conductive film according to claim 10, wherein the base film is a glass film.

20. A transparent electrode comprising the transparent conductive film according to claim 10.