PROCESSES FOR DISPERSING SUBSTANCES AND PREPARING COMPOSITE MATERIALS

• US 20100152326A1
• Filed: 07/12/2007
• Published: 06/17/2010
• Est. Priority Date: 07/12/2006
• Status: Active Grant

• Current Assignee: MinusNine Technologies, Inc. (Innovative Chemical Products Group LLC)
• Original Assignee: MinusNine Technologies, Inc. (Innovative Chemical Products Group LLC)
• Inventors: Kurz, David W.
• Granted Patent: US 8,030,376 B2
• Time in Patent Office: Days
• US Class Current: 523/339
• CPC Class Codes: C08J 3/2053 the additives only being premixed with a liquid phase
• CPC Class Codes: C08K 3/013 Fillers, pigments or reinforcing additives
• CPC Class Codes: C08L 21/00 Compositions of unspecified rubbers

Abstract

Disclosed herein are processes for dispersing a plurality of unaggregated particles, such as nanoparticles and microparticles, in a viscous medium. The dispersions can be used for making a variety of useful materials, such as carbon nanotube composites.

Claims

1. A process, comprising:

providing a nanocarrier dispersion comprising a dilute concentration of individual nanoparticles dispersed or dissolved in a nanocarrier solvent, the nanocarrier solvent characterized as being soluble in a viscous medium, the nanocarrier dispersion having a viscosity substantially lower than the viscosity of the viscous medium;

contacting the nanocarrier dispersion within the viscous medium, at least a portion of the nanocarrier solvent diffusing out of the nanocarrier dispersion and into the viscous medium; and

continuously removing the nanocarrier solvent from the viscous medium to give rise to a plurality of nanoparticles dispersed or dissolved in the viscous medium.

3. The process of claim 1, wherein said process does not require a dispersing aid.

7. The process of claim 1, wherein the nanocarrier dispersion comprises one or more additives.

8. The process of claim 1, wherein the nanocarrier dispersion is free, or substantially free, of dispersing aid.

11. The process of claim 1, wherein the step of contacting comprises contacting a plurality of droplets, or a stream of the nanocarrier dispersion within the viscous medium.

14. The process of claim 1, wherein the nanocarrier solvent is continuously removed from the viscous medium by extracting the nanocarrier solvent with an aqueous phase.

18. A viscous medium made according to the process of claim 1.

19. A composite made by hardening the viscous medium of claim 18.

2. (canceled)

4-6. -6. (canceled)

9-10. -10. (canceled)

12-13. -13. (canceled)

15-17. -17. (canceled)

20. A method of dispersing particles in a viscous fluid, comprising:

providing an particle solution comprising solvent, particles, and polymer, the particle solution being characterized as comprising well dispersed individual particles and said solvent characterized as being more soluble in water than in the viscous fluid;

continuously contacting droplets of the particle solution with the viscous fluid in a droplet contact zone to form a mixture comprising the particles, the solvent, and the viscous fluid;

transporting the droplets of the particle solution away from the droplet contact zone, the transported droplets being richer in solvent exterior to the droplet zone, the particles and polymer entering the viscous fluid; and

contacting the viscous fluid with an aqueous phase at an interface zone located exterior to the droplet contact zone while simultaneously extracting at least a portion of the solvent out of the viscous fluid.

25. The method of claim 20, wherein said viscous medium comprises curable polymer resin, non-curable polymer resin, monomer, or any combination thereof.

40. The method of claim 20, wherein at least a portion of said mixture is sonicated during all or part of the method at a frequency in the range of from about 1 Hz to about 10,000 KHz.

62. The method of claim 20, wherein said first particle dispersion is added to within said viscous medium drop-wise, stream-wise, pulsed, by use of gravity, syringe pumps, fluid pumps, peristaltic pumps, vacuum pumps, or any combination thereof.

75. The method of claim 20, wherein said particles comprise carbon nanotubes comprising SWNTs, DWNTs, MWNTs, carbon nanofibers, graphite fibers, or any combination thereof.

79. The method of claim 20, wherein said solvent is characterized as being miscible with said viscous medium.

81. The method of claim 20, wherein said solvent comprises a water miscible highly polar solvent.

83. The method of claim 20, wherein said solvent comprises a water immiscible solvent.

85. The method of claim 20, wherein the particles comprise individual particles smaller than about 125 microns in diameter, aggregates of individual particles smaller than about 125 microns in diameter, or any combination thereof.

86. The method of claim 20, wherein the first particle dispersion is substantially free of particle aggregates.

96. The method of claim 20, wherein the particles comprise insoluble materials comprising one or more of the following:

aluminum, gallium, indium, tin, thallium, lead, bismuth, metalloids, halogens, noble gases, rare earth elements, pigments, catalysts, silica, hollow glass spheres, zinc oxide particles, aerogels, thermoplastic powders, thermoset powders, metals, non-metals, an alkali metal comprising lithium, sodium, potassium, rubidium, cesium, or francium, an alkaline earth metal comprising beryllium, magnesium, calcium, strontium, barium, or radium, a transition metal comprising scandium, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, zinc, yttrium, zirconium, niobium, molybdenum, technetium, ruthenium, rhodium, rhodium, palladium, silver, cadmium, hafnium, tantalum, tungsten, rhenium, osmium, iridium, platinum, gold, mercury, or rutherfordium, and liquid crystalline compounds.

107. The method of claim 20, wherein the particles comprise ceramic precursor powder, superconducting ceramic precursor powder, superhard ceramic precursor powder, or any combination thereof.

112. The method of claim 20, wherein the particles comprise powdered pigments.

126. The method of claim 20, wherein the particles comprise in natural or modified natural fibers, synthetic in fibers, or any combination thereof.

130. A viscous fluid made according to the method of claim 20.

131. A composite made by hardening the viscous fluid of claim 130.

21-24. -24. (canceled)

26-39. -39. (canceled)

41-61. -61. (canceled)

63-74. -74. (canceled)

76-78. -78. (canceled)

80. (canceled)

82. (canceled)

84. (canceled)

87-95. -95. (canceled)

97-106. -106. (canceled)

108-111. -111. (canceled)

113-125. -125. (canceled)

127-129. -129. (canceled)

132. A method of dispersing particles in a viscous medium, comprising:

providing an particle solution comprising a plurality of particles and a solvent, the particle solution being characterized as comprising essentially well dispersed individual particles, and said solvent characterized as being more soluble in water than in the viscous medium;

contacting the particle solution with the fluid medium in a dispersion zone to form a one-phase mixture comprising the particles, the solvent, and the fluid medium; and

contacting said one-phase mixture with an aqueous phase at an interface zone located exterior to the dispersion zone while simultaneously extracting at least a portion of the solvent out of the one-phase mixture and into the aqueous phase.

133. A viscous medium made according to the process of claim 132.

134. A composite made by hardening the viscous medium of claim 133.

135. A method of dispersing particles in an fluid medium, comprising:

providing an particle solution comprising a plurality of particles and a solvent, the particle solution being characterized as comprising essentially well dispersed individual particles, and said solvent characterized as being more soluble in water than in the fluid medium;

contacting the particle solution with the fluid medium in a dispersion zone to form a one-phase mixture comprising the particles, the solvent, and the fluid medium, said contacting occurring while simultaneously sonicating both the particle solution and the fluid medium in the dispersion zone; and

contacting said one-phase mixture with an aqueous phase at an interface zone located exterior to the dispersion zone while simultaneously extracting at least a portion of the solvent out of the one-phase mixture and into the aqueous phase.

136. A fluid medium made according to the method of claim 135.

137. A composite made by hardening the fluid medium of claim 136.

138-140. -140. (canceled)