Processes for Preparing a Catalyzed Coal Particulate

• US 20100168494A1
• Filed: 12/29/2009
• Published: 07/01/2010
• Est. Priority Date: 12/30/2008
• Status: Active Grant

• Current Assignee: Sure Champion Investments Limited
• Original Assignee: GreatPoint Energy, Inc.
• Inventors: Salem, George Frederick, Rappas, Alkis S., Spitz, Robert A.
• Granted Patent: US 8,734,548 B2
• Time in Patent Office: Days
• US Class Current: 585/704
• CPC Class Codes: C10J 2300/0903 Feed preparation
• CPC Class Codes: C10J 2300/093 Coal
• CPC Class Codes: C10J 2300/0973 Water
• CPC Class Codes: C10J 2300/0986 Catalysts
• CPC Class Codes: C10J 2300/1853 Steam reforming, i.e. injection of steam only
• CPC Class Codes: C10J 3/00 Production of combustible gases containing carbon monoxide from solid carbonaceous fuels destructive distillation processes C10B
• CPC Class Codes: C10J 3/482 Gasifiers with stationary fluidised bed
• CPC Class Codes: C10L 3/08 Production of synthetic natural gas
• CPC Class Codes: C10L 9/02 by chemical means
• CPC Class Codes: Y02P 20/52 using catalysts, e.g. selective catalysts

Abstract

Processes are provided for preparing a substantially free-flowing alkali metal gasification catalyst-loaded coal particulate suitable for use as a feedstock for the production of gaseous products, and in particular methane, via the catalytic gasification of the catalyst-loaded coal particulate in the presence of steam.

Claims

1. A process for preparing a substantially free-flowing alkali metal gasification catalyst-loaded coal particulate from a coal feedstock, the process comprising the steps of:

(A) providing a coal feedstock having an initial moisture content and an initial concentration of acidic functional groups;

(B) grinding the coal feedstock;

(C) classifying the coal feedstock from step (B) to a specified particle size profile to produce a coal particulate having a matrix, and comprising a second concentration of acidic functional groups;

(D) contacting the coal particulate with an amount of an aqueous solution comprising a concentration of an alkali metal gasification catalyst, to form an alkali metal gasification catalyst-loaded coal particulate wet cake having a specified ratio of alkali metal atoms to carbon atoms and a second moisture content; and

(E) thermally treating the alkali metal gasification catalyst-loaded coal particulate wet cake as required to reduce the second moisture content to produce the alkali metal gasification catalyst-loaded coal particulate as a substantially free-flowing particulate,

wherein;

(a) the second concentration of acidic functional groups is at least about 50% of the initial concentration;

(b) the specified particle size profile has a d5 particle size of at least about 20 microns, a d95 particle size of about 1000 microns or less, and a d50 particle size ranging from about 75 to about 350 microns;

(c) the specified ratio of alkali metal atoms to carbon atoms of step (D) is sufficient to provide an alkali metal atoms to carbon atoms ratio in the substantially free-flowing alkali metal gasification catalyst-loaded coal particulate of from about 0.01 to about 0.10;

(d) the alkali metal gasification catalyst-loaded coal particulate wet cake from step (D) is substantially non-draining;

(e) the amount of aqueous solution and the concentration of the alkali metal gasification catalyst in step (D) are sufficient to provide the specified ratio of alkali metal atoms to carbon atoms in the alkali metal gasification catalyst-loaded coal particulate wet cake;

(f) the contacting in step (D) takes place at substantially atmospheric pressure, and at an elevated temperature substantially at or below the boiling point of the aqueous solution, under agitation and for a specified amount of time, each which is in an amount sufficient in combination to allow substantially even distribution of the alkali metal gasification catalyst within the non-draining alkali metal gasification catalyst-loaded coal particulate wet cake;

(g) the non-draining alkali metal gasification catalyst loaded carbonaceous particulate wet cake exits step (D) at a first temperature, and is passed into the thermal treating step (E) at substantially the same temperature; and

(h) the substantially free-flowing alkali metal gasification catalyst-loaded coal particulate comprises a content of alkali metal atoms, wherein greater than about 50% of the content of alkali metal atoms are associated with the coal particulate matrix by ion exchange on acidic functional groups.

2. The process according to claim 1, wherein the grinding step (B) is a dry grinding step.

3. The process according to claim 2, wherein the initial moisture content of the carbonaceous feedstock is reduced so that, when taking into account the amount of aqueous solution used in step (D), the wet cake resulting from step (D) is substantially non-draining

4. The process according to claim 3, wherein the carbonaceous feedstock is dried concurrently with dry grinding.

5. The process according to claim 1, wherein the grinding step (B) is a wet grinding step that results in a wet ground coal feedstock.

6. The process of claim 5, where the moisture content of the wet ground coal feedstock is reduced so that, when taking into account the amount of aqueous solution used in step (D), the wet cake resulting from step (D) is substantially non-draining

7. The process according to any claim 1, wherein the coal comprises one or more of anthracite, bituminous coal, sub-bituminous coal or lignite.

8. The process according to claim 1, wherein the alkali metal comprises potassium, sodium, or both.

9. The process according to claim 1, wherein the wet cake is non-draining

10. The process according to claim 1, wherein the contacting of step (D) is performed at a temperature of from about 80°

C. and about 100°

C.

11. The process according to claim 1, wherein the contacting of step (D) takes place for a period of time ranging from about 5 minutes to about 60 minutes.

12. A process for converting a particulate composition into a plurality of gaseous products comprising the steps of:

(a) supplying a carbonaceous particulate composition to a gasifying reactor;

(b) reacting the particulate composition in the gasifying reactor in the presence of steam and under suitable temperature and pressure to form a plurality of gaseous including methane and at least one or more of hydrogen, carbon monoxide, carbon dioxide, hydrogen sulfide, ammonia and other higher hydrocarbons; and

(c) at least partially separating the plurality of gaseous products to produce a stream comprising a predominant amount of one of the gaseous products,

wherein the carbonaceous particulate is as prepared according to the process of claim 1.

13. The process according to claim 12, wherein the stream comprises a predominant amount of methane.

14. The process according to claim 12, wherein a solid char product containing entrained catalyst is formed in step (b), the solid char product is passed to a catalyst recovery unit, and catalyst is recovered and recycled for the aqueous solution used in step (D).