SINGLE STEP PROCESS FOR SEPARATING BIOMASS COMPONENTS

• US 20100190973A1
• Filed: 06/19/2008
• Published: 07/29/2010
• Est. Priority Date: 06/20/2007
• Status: Abandoned Application

• Current Assignee: Nagarjuna Energy Private Limited
• Original Assignee: Nagarjuna Energy Private Limited
• Inventors: Srivastava, Suresh Chandra, Pandey, Banibrata, Sarkar, Manoj Kumar, Pechimuthu, Sakthi Priya, Sudhakaran, Dinakaran Samuel
• Application Number:
  US12/450,594
• Publication Number:
  US 20100190973A1
• Time in Patent Office: Days
• US Class Current: 536/56
• CPC Class Codes: C13K 1/02 obtained by saccharification of cellulosic materials manufacture of fodder A23K10/32
• CPC Class Codes: D21C 1/04 with acid reacting compounds
• CPC Class Codes: D21C 3/20 with organic solvents or in solvent environment
• CPC Class Codes: D21C 3/222 Use of compounds accelerating the pulping processes
• CPC Class Codes: D21C 5/005 Treatment of cellulose-containing material with microorganisms or enzymes
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel

Abstract

The invention is directed towards a method of pretreatment of a lignocellulose containing biomass so as to make the biomass amenable to enzymatic digestion. More particularly, the instant application discloses a single step separation of biomass into individual components such as cellulose, hemicellulose and lignin without losing chemical nature and with high purity at a time.

Claims

1. A process for obtaining cellulose from biomass in a form amenable to complete enzymatic hydrolysis, said process comprising contacting the biomass with a mixture of an organic solvent immiscible in water, an acid and a metal salt catalyst dissolved in the acidic water solution under predetermined temperature and pressure and filtering the reaction mixture under pressure to separate the dissolved lignin, hemciellulose in the solvent and aqueous phase respectively and leaving behind pure cellulose.

2. A process as claimed in claim 1, wherein the water immiscible solvent is selected from a group comprising higher alcohols.

3. A process as claimed in claim 2, wherein the higher alcohols is selected from the group comprising butanol, iso-amyl alcohol.

4. A process as claimed in claim 1, wherein the solvent to acidic water ratio is in the range of 40:

60 to 80;

20.

5. A process as claimed in claim 1, wherein the acid is mineral acid.

6. A process as claimed in claim 1, wherein the metal salt catalyst selected from a group comprising copper sulphate, ferrous sulphate, Ferrous ammonium sulphate, Nickel sulphate, Sodium sulphate, ferric chloride.

7. A process as claimed in claim 5, wherein the acid concentration is about 1% (v/v) of water.

8. A process as claimed in claim 1, wherein the catalyst concentration is in the range of 0.1% to 3% (w/v) of acidic water.

9. A process as claimed in claim 1, wherein the predetermined temperature is in the range of 120°

-220°

C.

10. A process as claimed in claim 1, wherein the predetermined pressure is in the range of 1.5-20 Bar.

11. A process as claimed in claim 1, wherein the process is carried out for a period of time of 10 to 30 min.

12. A system for obtaining cellulose from biomass comprising:

a) a reactor chamber for containing biomass, having (i) a first inlet for supplying mixture of an organic solvent, (ii) a second inlet and (iii) at least one outlet;

b) a boiler in fluid flow communication with the second inlet of the reactor chamber for supplying steam to the reactor chamber,

c) a receiver coupled to the outlet of the reactor chamber for receiving hydrolysate from reactor chamber;

d) a steam distillation assembly for the removing traces of solvent in the aqueous fraction and precipitating the lignin in the solvent fraction.

13. A system for obtaining cellulose from biomass as claimed in claim 12, wherein the first inlet of the reactor chamber is in fluid flow communication with a vessel which contains mixture of an organic solvent.

14. A system for obtaining cellulose from biomass as claimed in claim 12, wherein the receiver is in fluid flow communication with the boiler.

15. A system for obtaining cellulose from biomass as claimed in claim 12, wherein the steam distillation assembly comprises a condenser and a receiver for collecting the condensate from the condenser.