Molecular Healing of Polymeric Materials, Coatings, Plastics, Elastomers, Composites, Laminates, Adhesives, and Sealants by Active Enzymes
First Claim
1. A composition, comprising a thermoplastic polymeric material, a thermoset polymeric material, an elastomer, a foamed solid polymeric material, a reinforced polymeric material, a composite, a laminate, an engineering polymeric material;
- a high-performance polymeric material, a honeycomb, a coated fabric, a polymeric fiber, an adhesive, a sealant, a wax, a textile finish, a filler, a coating, or a combination thereof;
wherein the coating comprises an architectural coating, an automotive coating, a can coating, a sealant coating, a chemical agent resistant coating, a camouflage coating, a pipeline coating, a traffic marker coating, an aircraft coating, a nuclear power plant coating, or a combination thereof;
wherein the composition comprises an active enzyme and a substrate of the active enzyme, wherein the active enzyme comprises an esterase, a hydrolase, a urease, or a combination thereof;
wherein the substrate of the active enzyme comprises a monomer, a polymer, a crosslinking agent, an anti-crosslinking agent, a coupling agent, or a combination thereof;
wherein the active enzyme catalyzes a chemical reaction on the substrate of the active enzyme that alters a property of the composition;
wherein the property of the composition that is altered comprises glass transition temperature, brittleness, flexibility, scrub resistance, toughness, impact resistance, color retention, self cleaning, gloss, solvent resistance, service life, adhesion, or a combination thereof.
1 Assignment
0 Petitions
Accused Products
Abstract
Disclosed herein are polymeric materials such as a coating, a plastic, a laminate, a composite, an elastomer, an adhesive, or a sealant; a surface treatment such as a textile finish or a wax; a filler for such a polymeric material or a surface treatment that includes an enzyme such as an esterase (e.g., a lipolytic enzyme, a sulfuric ester hydrolase, an organophosphorus compound degradation enzyme), an enzyme (e.g., a lysozyme, a lytic transglycosylase) that degrades a cell wall and/or a cell membrane component, a biocidal or biostatic peotide, and/or a peptidase. Also disclosed herein are methods of altering a material'"'"'s property such as service life, flexability, or rigidity, by incorporation of an enzyme into a material capable of being chemically crosslinked by the activity of a lipolytic enzyme, a hydrolase, and/or a urease.
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Citations
108 Claims
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1. A composition, comprising a thermoplastic polymeric material, a thermoset polymeric material, an elastomer, a foamed solid polymeric material, a reinforced polymeric material, a composite, a laminate, an engineering polymeric material;
- a high-performance polymeric material, a honeycomb, a coated fabric, a polymeric fiber, an adhesive, a sealant, a wax, a textile finish, a filler, a coating, or a combination thereof;
wherein the coating comprises an architectural coating, an automotive coating, a can coating, a sealant coating, a chemical agent resistant coating, a camouflage coating, a pipeline coating, a traffic marker coating, an aircraft coating, a nuclear power plant coating, or a combination thereof;
wherein the composition comprises an active enzyme and a substrate of the active enzyme, wherein the active enzyme comprises an esterase, a hydrolase, a urease, or a combination thereof;
wherein the substrate of the active enzyme comprises a monomer, a polymer, a crosslinking agent, an anti-crosslinking agent, a coupling agent, or a combination thereof;
wherein the active enzyme catalyzes a chemical reaction on the substrate of the active enzyme that alters a property of the composition;
wherein the property of the composition that is altered comprises glass transition temperature, brittleness, flexibility, scrub resistance, toughness, impact resistance, color retention, self cleaning, gloss, solvent resistance, service life, adhesion, or a combination thereof. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74, 75)
- a high-performance polymeric material, a honeycomb, a coated fabric, a polymeric fiber, an adhesive, a sealant, a wax, a textile finish, a filler, a coating, or a combination thereof;
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76. A polymeric material composition, comprising a polymeric material, an active enzyme, and a substrate of the active enzyme;
- wherein the polymeric material comprises a thermoplastic polymeric material, a thermoset polymeric material, an elastomer, a foamed solid polymeric material, a reinforced polymeric material, a composite, a laminate, an engineering polymeric material;
a high-performance polymeric material, a honeycomb, a coated fabric, a polymeric fiber, an adhesive, a sealant, a coating, or a combination thereof;
wherein the active enzyme comprises an esterase, a urease, a hydrolase, or a combination thereof;
wherein the substrate of the active enzyme comprises a monomer, a polymer, a crosslinking agent, an anti-crosslinking agent, a coupling agent, or a combination thereof;
wherein the active enzyme catalyzes a chemical reaction on the substrate of the active enzyme that alters a property of the polymeric material;
wherein the property of the polymeric material that is altered comprises glass transition temperature, brittleness, flexibility, scrub resistance, toughness, impact resistance, color retention, self cleaning, gloss, solvent resistance, service life, or a combination thereof. - View Dependent Claims (77)
- wherein the polymeric material comprises a thermoplastic polymeric material, a thermoset polymeric material, an elastomer, a foamed solid polymeric material, a reinforced polymeric material, a composite, a laminate, an engineering polymeric material;
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78. A plastic composition, comprising a plastic, an active enzyme and a substrate of the active enzyme;
- wherein the plastic comprises thermoplastic, a thermoset, or a combination thereof;
wherein the active enzyme comprises an esterase, a hydrolase, a urease, or a combination thereof;
wherein the substrate of the active enzyme comprises a monomer, a polymer, a crosslinking agent, an anti-crosslinking agent, a coupling agent, or a combination thereof;
wherein the active enzyme catalyzes a chemical reaction on the substrate of the active enzyme that alters a property of the plastic;
wherein the property of the plastic that is altered comprises glass transition temperature, brittleness, flexibility, scrub resistance, toughness, impact resistance, color retention, self cleaning, gloss, solvent resistance, service life, or a combination thereof.
- wherein the plastic comprises thermoplastic, a thermoset, or a combination thereof;
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79. A coating composition, comprising a coating, an active enzyme, and a substrate of the active enzyme;
- wherein the coating comprises an architectural coating, an automotive coating, a can coating, a sealant coating, a chemical agent resistant coating, a camouflage coating, a pipeline coating, a traffic marker coating, an aircraft coating, a nuclear power plant coating, or a combination thereof;
wherein the active enzyme comprises an esterase, a hydrolase, a urease, or a combination thereof;
wherein the substrate of the active enzyme comprises a monomer, a polymer, a crosslinking agent, an anti-crosslinking agent, a coupling agent, or a combination thereof;
wherein the active enzyme catalyzes a chemical reaction on the substrate of the active enzyme that alters a property of the coating;
wherein the property of the coating that is altered comprises glass transition temperature, brittleness, flexibility, scrub resistance, toughness, impact resistance, color retention, self cleaning, gloss, solvent resistance, service life, adhesion, or a combination thereof.
- wherein the coating comprises an architectural coating, an automotive coating, a can coating, a sealant coating, a chemical agent resistant coating, a camouflage coating, a pipeline coating, a traffic marker coating, an aircraft coating, a nuclear power plant coating, or a combination thereof;
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80. An adhesive composition, comprising an adhesive, an active enzyme, and a substrate of the active enzyme;
- wherein the active enzyme comprises an esterase, a hydrolase, a urease, or a combination thereof;
wherein the composition comprises a substrate of the active enzyme, wherein the substrate of the active enzyme comprises a monomer, a polymer, a crosslinking agent, an anti-crosslinking agent, a coupling agent, or a combination thereof;
wherein the active enzyme catalyzes a chemical reaction on the substrate of the active enzyme that alters a property of the adhesive;
wherein the property of the adhesive that is altered comprises glass transition temperature, brittleness, flexibility, scrub resistance, toughness, impact resistance, color retention, self cleaning, gloss, solvent resistance, service life, adhesion, or a combination thereof.
- wherein the active enzyme comprises an esterase, a hydrolase, a urease, or a combination thereof;
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81. A sealant composition, comprising a sealant, an active enzyme, and a substrate of the active enzyme;
- wherein the active enzyme comprises an esterase, a hydrolase, a urease, or a combination thereof;
wherein the substrate of the active enzyme comprises a monomer, a polymer, a crosslinking agent, an anti-crosslinking agent, a coupling agent, or a combination thereof;
wherein the active enzyme catalyzes a chemical reaction on the substrate of the active enzyme that alters a property of the sealant;
wherein the property of the sealant that is altered comprises glass transition temperature, brittleness, flexibility, scrub resistance, toughness, impact resistance, color retention, self cleaning, gloss, solvent resistance, service life, adhesion, or a combination thereof.
- wherein the active enzyme comprises an esterase, a hydrolase, a urease, or a combination thereof;
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82. An elastomer composition, comprising an elastomer, an active enzyme, and a substrate of the active enzyme;
- wherein the active enzyme comprises an esterase, a hydrolase, a urease, or a combination thereof;
wherein the substrate of the active enzyme comprises a monomer, a polymer, a crosslinking agent, an anti-crosslinking agent, a coupling agent, or a combination thereof;
wherein the active enzyme catalyzes a chemical reaction on the substrate of the active enzyme that alters a property of the elastomer;
wherein the property of the elastomer that is altered comprises glass transition temperature, brittleness, flexibility, scrub resistance, toughness, impact resistance, color retention, self cleaning, gloss, solvent resistance, service life, or a combination thereof.
- wherein the active enzyme comprises an esterase, a hydrolase, a urease, or a combination thereof;
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83. A reinforced polymeric material composition, comprising a reinforced polymeric material, an active enzyme, and a substrate of the active enzyme;
- wherein the active enzyme comprises an esterase, a hydrolase, a urease, or a combination thereof;
wherein the substrate of the active enzyme comprises a monomer, a polymer, a crosslinking agent, an anti-crosslinking agent, a coupling agent, or a combination thereof;
wherein the active enzyme catalyzes a chemical reaction on the substrate of the active enzyme that alters a property of the reinforced polymeric material;
wherein the property of the reinforced polymeric material that is altered comprises glass transition temperature, brittleness, flexibility, scrub resistance, toughness, impact resistance, color retention, self cleaning, gloss, solvent resistance, service life, or a combination thereof.
- wherein the active enzyme comprises an esterase, a hydrolase, a urease, or a combination thereof;
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84. A composite composition, comprising a composite, an active enzyme, and a substrate of the active enzyme;
- wherein the active enzyme comprises an esterase, a hydrolase, a urease, or a combination thereof;
wherein the substrate of the active enzyme comprises a monomer, a polymer, a crosslinking agent, an anti-crosslinking agent, a coupling agent, or a combination thereof;
wherein the active enzyme catalyzes a chemical reaction on the substrate of the active enzyme that alters a property of the composite;
wherein the property of the composite that is altered comprises glass transition temperature, brittleness, flexibility, scrub resistance, toughness, impact resistance, color retention, self cleaning, gloss, solvent resistance, service life, or a combination thereof.
- wherein the active enzyme comprises an esterase, a hydrolase, a urease, or a combination thereof;
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85. A laminate composition, comprising a laminate, an active enzyme, and a substrate of the active enzyme;
- wherein the active enzyme comprises an esterase, a hydrolase, a urease, or a combination thereof;
wherein the substrate of the active enzyme comprises a monomer, a polymer, a crosslinking agent, an anti-crosslinking agent, a coupling agent, or a combination thereof;
wherein the active enzyme catalyzes a chemical reaction on the substrate of the active enzyme that alters a property of the laminate;
wherein the property of the laminate that is altered comprises glass transition temperature, brittleness, flexibility, scrub resistance, toughness, impact resistance, color retention, self cleaning, gloss, solvent resistance, service life, or a combination thereof.
- wherein the active enzyme comprises an esterase, a hydrolase, a urease, or a combination thereof;
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86. A polymeric material composition, comprising a polymeric material, an active enzyme, and a substrate;
- wherein the polymeric material comprises an engineering polymeric material;
a high-performance polymeric material, or a combination thereof;
wherein the active enzyme comprises an esterase, a hydrolase, a urease, or a combination thereof;
wherein the substrate of the active enzyme comprises a monomer, a polymer, a crosslinking agent, an anti-crosslinking agent, a coupling agent, or a combination thereof;
wherein the active enzyme catalyzes a chemical reaction on the substrate of the active enzyme that alters a property of the polymeric material;
wherein the property of the polymeric material that is altered comprises glass transition temperature, brittleness, flexibility, scrub resistance, toughness, impact resistance, color retention, self cleaning, gloss, solvent resistance, service life, or a combination thereof.
- wherein the polymeric material comprises an engineering polymeric material;
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87. A polymeric material composition, comprising polymeric material that comprises a polyurethane polymer and an active enzyme;
- wherein the active enzyme comprises an esterase, a urease, a hydrolase, or a combination thereof;
wherein the polyurethane polymer comprises an acidic moiety, a basic moiety, or a combination thereof is capable of undergoing a chemical reaction catalyzed by the active enzyme;
wherein the active enzyme catalyzes a chemical reaction on the polyurethane polymer that alters a property of the polymeric material;
wherein the property of the polymeric material that is altered comprises glass transition temperature, brittleness, flexibility, scrub resistance, toughness, impact resistance, color retention, self cleaning, gloss, solvent resistance, service life, or a combination thereof. - View Dependent Claims (88)
- wherein the active enzyme comprises an esterase, a urease, a hydrolase, or a combination thereof;
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89. A polymeric material composition, comprising a polymeric material that comprises a polymer comprising a vegetable oil-based macromonomer as a monomer of the polymer;
- wherein the polymeric material comprise an active enzyme, wherein the active enzyme comprises an esterase, a urease, a hydrolase, or a combination thereof;
wherein the active enzyme catalyzes a chemical reaction on the vegetable oil-based macromonomer that alters a property of the polymeric material;
wherein the property of the polymeric material that is altered comprises glass transition temperature, brittleness, flexibility, scrub resistance, toughness, impact resistance, color retention, self cleaning, gloss, solvent resistance, service life, or a combination thereof. - View Dependent Claims (90, 91, 92, 93)
- wherein the polymeric material comprise an active enzyme, wherein the active enzyme comprises an esterase, a urease, a hydrolase, or a combination thereof;
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94. A biomedical composition, comprising a biomedical material, an active enzyme, and a substrate of the active enzyme;
- wherein the active enzyme comprises an esterase, a urease, a hydrolase, or a combination thereof;
wherein the active enzyme catalyzes a chemical reaction on the substrate of the biomedical material that alters a property of the biomedical material;
wherein the property of the biomedical material that is altered comprises glass transition temperature, brittleness, flexibility, scrub resistance, toughness, impact resistance, color retention, self cleaning, gloss, solvent resistance, service life, or a combination thereof. - View Dependent Claims (95, 96)
- wherein the active enzyme comprises an esterase, a urease, a hydrolase, or a combination thereof;
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97. An article of manufacture, comprising a thermoplastic polymeric material, a thermoset polymeric material, an elastomer, a foamed solid polymeric material, a reinforced polymeric material, a composite, a laminate, an engineering polymeric material;
- a high-performance polymeric material, a honeycomb, a coated fabric, a polymeric fiber, an adhesive, a sealant, a wax, a textile finish, a filler, a coating, or a combination thereof;
wherein the coating comprises an architectural coating, an automotive coating, a can coating, a sealant coating, a chemical agent resistant coating, a camouflage coating, a pipeline coating, a traffic marker coating, an aircraft coating, a nuclear power plant coating, or a combination thereof;
wherein the article of manufacture comprises an active enzyme and a substrate of the active enzyme;
wherein the active enzyme comprises an esterase, a hydrolase, a urease, or a combination thereof;
wherein the substrate of the active enzyme comprises a monomer, a polymer, a crosslinking agent, an anti-crosslinking agent, a coupling agent, or a combination thereof;
wherein the active enzyme catalyzes a chemical reaction on the substrate of the active enzyme that alters a property of the article of manufacture;
wherein the property of the article of manufacture that is altered comprises glass transition temperature, brittleness, flexibility, scrub resistance, toughness, impact resistance, color retention, self cleaning, gloss, solvent resistance, service life, adhesion, or a combination thereof.
- a high-performance polymeric material, a honeycomb, a coated fabric, a polymeric fiber, an adhesive, a sealant, a wax, a textile finish, a filler, a coating, or a combination thereof;
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98. A kit having component parts capable of being assembled comprising a container comprising an active enzyme, a substrate of the active enzyme, an inhibitor of the active enzyme, or a combination thereof;
- and a container comprising at least one component of a thermoplastic polymeric material, a thermoset polymeric material, an elastomer, a foamed solid polymeric material, a reinforced polymeric material, a composite, a laminate, an engineering polymeric material;
a high-performance polymeric material, a honeycomb, a coated fabric, a polymeric fiber, an adhesive, a sealant, a wax, a textile finish, a filler, a coating, or a combination thereof;
wherein the coating comprises an architectural coating, an automotive coating, a can coating, a sealant coating, a chemical agent resistant coating, a camouflage coating, a pipeline coating, a traffic marker coating, an aircraft coating, a nuclear power plant coating, or a combination thereof;
wherein the composition comprises an active enzyme and a substrate of the active enzyme, wherein the active enzyme comprises an esterase, a hydrolase, a urease, or a combination thereof;
wherein the substrate of the active enzyme comprises a monomer, a polymer, a crosslinking agent, an anti-crosslinking agent, a coupling agent, or a combination thereof.
- and a container comprising at least one component of a thermoplastic polymeric material, a thermoset polymeric material, an elastomer, a foamed solid polymeric material, a reinforced polymeric material, a composite, a laminate, an engineering polymeric material;
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99. A method of altering a property in a polymeric material, comprising:
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obtaining an active enzyme, wherein the active enzyme comprises an esterase, a urease, a hydrolase, or a combination thereof; obtaining a component of a polymeric material, wherein the component of the polymeric material is capable of acting as a substrate for the active enzyme; and preparing a polymeric material comprising the active enzyme and the component of the polymeric material, wherein the active enzyme and the component of the polymeric material are in a sufficient amount to alter a property of the polymeric material by the component undergoing a chemical reaction catalyzed by the active enzyme. - View Dependent Claims (100, 101, 102, 103, 104, 105, 106, 107, 108)
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Specification