Apparatus and Method for Solar Cells with Laser Fired Contacts in Thermally Diffused Doped Regions

• US 20100243041A1
• Filed: 03/18/2010
• Published: 09/30/2010
• Est. Priority Date: 03/26/2009
• Status: Abandoned Application

• Current Assignee: BP Corporation North America Incorporated (BP PLC)
• Original Assignee: BP Corporation North America Incorporated (BP PLC)
• Inventors: Zou, Lian, Hmung, George, Carlson, David E., Bennett, Murray S.
• Application Number:
  US12/726,600
• Publication Number:
  US 20100243041A1
• Time in Patent Office: Days
• US Class Current: 136/255
• CPC Class Codes: H01L 31/022441 Electrode arrangements specially adapted for back-contact solar cells
• CPC Class Codes: H01L 31/0682 back-junction, i.e. rearside emitter, solar cells, e.g. interdigitated base-emitter regions back-junction cells
• CPC Class Codes: H01L 31/0747 comprising a heterojunction of crystalline and amorphous materials, e.g. heterojunction with intrinsic thin layer
• CPC Class Codes: H01L 31/1804 comprising only elements of Group IV of the Periodic Table
• CPC Class Codes: H01L 31/1868 Passivation
• CPC Class Codes: Y02E 10/547 Monocrystalline silicon PV cells
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

This invention relates to an apparatus and a method for solar cells with laser fired contacts in thermally diffused doped regions. The cell includes a doped wafer and a plurality of first highly doped regions having a first conductivity type. The cell also includes a plurality of second highly doped regions having an opposite conductivity type from the first conductivity type and a passivation layer disposed over at least a portion of each the plurality of first highly doped regions and the plurality of second highly doped regions. The cell also includes a network of conductors having a first conductor and a second conductor, and a plurality of contacts electrically connecting the first highly doped regions with the first conductor and electrically connecting the second highly doped regions with the second conductor.

Claims

1. A back-contact photovoltaic cell, the cell comprising:

a doped wafer of semiconductor material having a front surface and a back surface;

a plurality of first highly doped regions disposed with respect to the back surface and having a first conductivity type;

a plurality of second highly doped regions disposed with respect to the back surface and having an opposite conductivity type from the first conductivity type;

a passivation layer disposed over at least a portion of each of the plurality of first highly doped regions, the plurality of second highly doped regions, and the back surface;

a network of conductors disposed with respect to the passivation layer and having a first conductor and a second conductor; and

a plurality of contacts electrically connecting the first highly doped regions with the first conductor and electrically connecting the second highly doped regions with the second conductor.

2. The cell of claim 1, wherein the first highly doped regions and the second highly doped regions were formed by non-contact printing.

3. The cell of claim 2, wherein the non-contact printing comprises inkjet printing, aerosol jet printing, or jet dispensing.

4. The cell of claim 1, wherein the first highly doped regions and the second highly doped regions comprise thermally diffused regions.

5. The cell of claim 1, wherein the passivation layer was formed by plasma enhanced chemical vapor deposition, magnetron sputtering, or hot-wire chemical vapor deposition.

6. The cell of claim 1, wherein the network of conductors comprises interdigitated fingers.

7. The cell of claim 1, wherein the plurality of contacts comprises laser fired contacts.

8. The cell of claim 7, wherein the laser fired contacts comprise parallel laser fired contacts.

9. The cell of claim 1, further comprising a shallow emitter just beneath the back surface and the passivation layer, and the shallow emitter disposed between the plurality of the first highly doped regions and the plurality of the second highly doped regions.

10. The cell of claim 9, wherein the shallow emitter comprises the conductivity type opposite the doped wafer.

11. The cell of claim 9, further comprising an isolation layer or an isolation gap between the shallow emitter and highly doped regions of opposite conductivity type from the shallow emitter.

12. The cell of claim 1, wherein the passivation layer comprises at least two layers.

14. The cell of claim 1, further comprising an inversion layer just beneath the back surface and the passivation layer.

15. The cell of claim 14, wherein the inversion layer is induced by an undoped layer of an amorphous silicon alloy and a highly doped layer having a conductivity type opposite the doped wafer.

13. The cell of claim 13, wherein the passivation layer comprises a layer of amorphous silicon and a layer of silicon nitride.

16. A photovoltaic cell, the cell comprising:

a doped wafer of semiconductor material having a front surface and a back surface;

a plurality of highly doped regions disposed with respect to the front surface and having a conductivity type opposite the doped wafer;

a shallow emitter disposed between the plurality of highly doped regions and having a same conductivity type as the highly doped regions;

a back surface field region just beneath the back surface, the back surface field region is formed either by a highly doped region having a same conductivity type as the doped wafer, or by an undoped layer of an amorphous silicon alloy and a highly doped layer of a same conductivity type as the doped wafer;

a front passivation layer disposed with respect to the highly doped regions and the shallow emitter;

a back passivation layer disposed with respect to the back surface field region;

a current collection grid disposed with respect to the front passivation layer and electrically connected to the highly doped regions;

a conductor disposed with respect to the back passivation layer; and

a plurality of contacts electrically connecting the back surface field region with the conductor.

17. The cell of claim 16, wherein the plurality of contacts comprises laser fired contacts.

18. The cell of claim 17, wherein the laser fired contacts were made by:

passing a laser beam through a diffractive optic or a microlens array to form multiple beams; and

optionally passing the multiple beams through an imaging system.

19. The cell of claim 18, wherein the multiple beams are reshaped by the diffractive optic, the microlens array, or the imaging system.

20. The cell of claim 16, further comprising a grid of selective emitter regions and current collection fingers disposed with respect to the front surface.

21. The cell of claim 16, wherein the highly doped regions are formed by laser firing a doping ink from on top of and through the front passivation layer into the doped wafer.

22. A process of manufacturing back-contact photovoltaic cells, the process comprising:

applying a first dopant source to a portion of a back surface of a doped wafer of semiconductor material, the first dopant source having a first conductivity type;

applying a second dopant source to a different portion of the back surface of the doped wafer of semiconductor material, the second dopant source having an opposite conductivity type from the first conductivity type;

diffusing the first dopant source and the second dopant source into the doped wafer to form a plurality of first highly doped regions and a plurality of second highly doped regions;

cleaning the back surface;

laying a passivation layer over the back surface, the plurality of first highly doped regions, and the plurality of second highly doped regions;

applying a network of conductors to a portion of the passivation layer; and

forming contacts between the network of conductors and both the first highly doped regions and the second highly doped regions.

23. The process of claim 22, wherein the step of applying the first dopant source and the step of applying the second dopant source comprise inkjet printing, aerosol jet printing, or jet dispensing.

24. The process of claim 22, wherein the step of diffusing the first dopant source and the second dopant source comprises thermal diffusion.

25. The process of claim 24, wherein the thermal diffusion comprises rapid thermal processing.

26. The process of claim 22, wherein the step of laying the passivation layer comprises plasma enhanced chemical vapor deposition, magnetron sputter deposition, or hot-wire chemical vapor deposition.

27. The process of claim 22, wherein the step of applying the network of conductors comprises forming interdigitated fingers.

28. The process of claim 22, wherein the step of forming contacts comprises laser firing contacts.

29. The process of claim 22, wherein the step of laser firing contacts comprises:

passing a laser beam through a diffractive optic or a microlens array to form multiple beams; and

optionally passing the multiple beams through an imaging system.

30. The process of claim 29, wherein the multiple beams are reshaped by the diffractive optic, the microlens array, or the imaging system.

31. The process of claim 22, further comprising:

applying a dilute dopant source of an opposite conductivity type to the doped wafer on the back surface between the plurality of the first highly doped regions and the plurality of the second highly doped regions; and

diffusing the dilute dopant source into the doped wafer to form a shallow emitter.

32. The process of claim 31, further comprising applying an isolation layer or assuring an isolation gap between the shallow emitter and highly doped regions of opposite conductivity type from the shallow emitter.

33. The process of claim 22, wherein the step of laying the passivation layer comprises forming a layer of amorphous silicon and forming a layer of silicon nitride.

34. The process of claim 22, further comprising forming an inversion layer just beneath the back surface and the passivation layer.

35. The process of claim 22, wherein the step of forming an inversion layer comprises:

depositing an undoped layer of an amorphous silicon alloy on the back surface; and

depositing a highly doped layer having a conductivity type opposite the doped wafer on the undoped layer.

36. A process of manufacturing photovoltaic cells, the process comprising:

applying a dopant source to a portion of a front surface of a doped wafer of semiconductor material, the dopant source having a conductivity type opposite the doped wafer;

applying a dilute dopant source having a conductivity type opposite the doped wafer to the remainder of the front surface of the doped wafer;

applying a dopant source to a portion of a back surface of a doped wafer;

the dopant source having the same conductivity type as the doped wafer;

diffusing the dopant sources and the dilute dopant source into the doped wafer to form highly doped regions, a shallow emitter, and a back surface field region;

laying a passivation layer over the highly doped regions, the shallow emitter, the back surface and the back surface field region to form a front passivation layer and a back passivation layer;

applying a current collection grid on the front passivation layer;

applying a conductor on the back passivation layer;

forming front-contacts between the highly doped regions and the current collection grid; and

forming back-contacts between the back surface field region and the conductor.

37. The process of claim 36, wherein the steps of forming the front-contacts or forming the back-contacts comprise laser firing contacts.

38. The process of claim 37, wherein the steps of forming the front-contacts or forming the back-contacts comprise parallel laser firing contacts.

39. The process of claim 36, further comprising the step of forming a grid of selective emitter regions and current collection fingers disposed with respect to the front surface.

40. The process of claim 36, wherein:

the step of applying a dopant source to a portion of a front surface of the doped wafer comprises applying a doping ink over the front passivation layer; and

the step of diffusing the dopant sources comprises laser firing the doping ink through the front passivation layer while optionally performing the step of forming front-contacts between the highly doped regions and the current collection grid.