System and Method for Directed Self-Assembly Technique for the Creation of Carbon Nanotube Sensors and Bio-Fuel Cells on Single Plane
First Claim
1. A bio-fuel cell comprising:
- a substrate having positioned thereon a first conductive member and a second conductive member with an insulating layer positioned over the substrate and the first and second conductive members, the insulating layer;
(i) having a first aperture formed therein exposing a first region of the first conductive member, with an electrophoretically deposited first nanotube having a first end in contact with the exposed first region of the first conductive member, and (ii) having a second aperture formed therein exposing a second region of the second conductive member, with an electrophoretically deposited second nanotube having a first end in contact with the exposed second region of the second conductive member;
the first nanotube electrically coupled to the second nanotube, the first nanotube configured to be a cathode and the second nanotube configured to be an anode; and
an electrolyte in electrical communication with the cathode and the anode.
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Accused Products
Abstract
Improved nanotube devices and systems/methods for fabrication thereof are provided. The present disclosure provides systems/methods for depositing controlled numbers of nanotubes with specific properties at predefined locations for the fabrication of nanotube devices. The nanotube devices may be utilized in a range of applications. A bio-fuel cell system that does not require a proton exchange membrane separator and does not need a mediator to transfer charge is provided. This exemplary bio-fuel cell uses enzyme functionalized SWNTs for the anode/cathode. The absence of a membrane in the bio-fuel cell configuration opens up the possibility of other configurations that would otherwise be unfeasible. This includes a bio-fuel cell where the anode/cathode are on the same substrate. Since the electrodes can share the same substrate, the configuration may be integrated with a circuit device on the same substrate. An IC and its power source may be fabricated on the same silicon wafer.
43 Citations
35 Claims
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1. A bio-fuel cell comprising:
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a substrate having positioned thereon a first conductive member and a second conductive member with an insulating layer positioned over the substrate and the first and second conductive members, the insulating layer;
(i) having a first aperture formed therein exposing a first region of the first conductive member, with an electrophoretically deposited first nanotube having a first end in contact with the exposed first region of the first conductive member, and (ii) having a second aperture formed therein exposing a second region of the second conductive member, with an electrophoretically deposited second nanotube having a first end in contact with the exposed second region of the second conductive member;the first nanotube electrically coupled to the second nanotube, the first nanotube configured to be a cathode and the second nanotube configured to be an anode; and an electrolyte in electrical communication with the cathode and the anode. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17)
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18. A method of fabricating a bio-fuel cell comprising:
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providing a substrate having positioned thereon a first conductive member and a second conductive member with an insulating layer positioned over the substrate and the first and second conductive members; forming a first aperture in the insulating layer to expose a first region of the first conductive member; forming a second aperture in the insulating layer to expose a second region of the second conductive member; generating an electric field proximate to the first and second apertures, the electric field configured to direct a plurality of nanotubes towards the first and second exposed regions of the first and second conductive members; depositing a first nanotube on the first exposed region of the first conductive member and a second nanotube on the second exposed region of the second conductive member by electrophoresis, the deposited first nanotube having one end contacting the first exposed region of the first conductive member and the deposited second nanotube having one end contacting the second exposed region of the second conductive member; configuring the first nanotube to be a cathode and the second nanotube to be an anode; electrically coupling the cathode to the anode; and providing an electrolyte in electrical communication with the cathode and anode. - View Dependent Claims (19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33)
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34. A method of fabricating a bio-fuel cell comprising:
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providing a substrate having positioned thereon a first conductive member and a second conductive member with an insulating layer positioned over the substrate and the first and second conductive members; forming a first elongated aperture in the insulating layer to expose a first region of the first conductive member, the first elongated aperture having a first width and a first length larger than the first width; forming a second elongated aperture in the insulating layer to expose a second region of the second conductive member, the second elongated aperture having a second width and a second length larger than the second width; generating an electric field proximate to the first and second apertures, the electric field configured to direct a first plurality of nanotubes towards the first and second exposed regions of the first and second conductive members; depositing;
(i) a second plurality of nanotubes in a first line pattern on the first exposed region of the first conductive member, and (ii) a third plurality of nanotubes in a second line pattern on the second exposed region of the second conductive member, by electrophoresis;configuring at least a first nanotube from the second plurality to be a cathode and configuring at least a second nanotube from the third plurality to be an anode; electrically coupling the cathode to the anode; providing an electrolyte in electrical communication with the cathode and anode; wherein the width of the first aperture is sufficiently small to restrict deposition of the second plurality of nanotubes to the first line pattern and the number of nanotubes in the second plurality is determined at least in part by the length of the aperture; wherein the width of the second aperture is sufficiently small to restrict deposition of the third plurality of nanotubes to the second line pattern and the number of nanotubes in the second plurality is determined at least in part by the length of the aperture; wherein the number of nanotubes in the first plurality of nanotubes is greater than the number of nanotubes in the second plurality of nanotubes, and wherein the number of nanotubes in the first plurality of nanotubes is greater than the number of nanotubes in the third plurality of nanotubes. - View Dependent Claims (35)
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Specification