Dual component (aqueous) hybrid reactive resin system, method for production and use thereof
1 Assignment
0 Petitions
Accused Products
Abstract
A dual component (aqueous) hybrid reactive system obtained by a) the production of an epoxy-functional (aqueous) binding agent component (I) with an epoxide equivalent of 100 to 12,500 g/eq, and average molecular mass of 200 to 25,000 Daltons and a viscosity of 1,000 to 15,000 mPas 920° C., Brookfield) and b) the production of a (latent) amino-functional hardener component (II).
23 Citations
73 Claims
-
1-38. -38. (canceled)
-
39. A two-component, aqueous hybrid reactive resin system prepared by the process of:
-
a) preparing an epoxyfunctional aqueous binder component (I) having an epoxide equivalent of 100 to 12,500 g/eq, an average molecular mass of 200 to 25,000 dalton and a viscosity of 1,000 to 150,000 mPa·
s as measured at 20°
C. with a Brookfield viscometer;a1) 5 to 300 parts by weight of a functionalized low molecular weight polyol component (A)(i), comprising at least one of an hydroxyfunctional epoxy-alcohol, a glycidyl ether having at last one hydroxyl group that reacts with an isocyanate group and one or more epoxide group substantially inert to isocyanate groups, having an epoxide equivalent of 100 to 500 g/eq and a molecular mass of 50 to 1,000 dalton;
with0 to 300 parts by weight of a functionalized higher molecular weight polymeric polyol component (A)(ii) having at least one hydroxyl group reactive with an isocyanate group and one or more epoxide group substantially inert to an isocyanate group, having an epoxide equivalent of 130 to 3,000 g/eq and a molecular mass of 250 to 2,500 dalton; and reacting with 5 to 500 parts by weight of a polyisocyanate component (B) comprising at least one diisocyanate, polyisocyanate, polyisocyanate derivative or polyisocyanate homologue having two or more (cyclo)aliphatic or aromatic isocyanate groups and a molecular mass of 100 to 2,500 dalton, optionally in the presence of 0.01 to 0.5 part by weight of a catalyst component (K)(i) suitable for polyaddition a reaction with a polyisocyanate, wherein the mixture of the components (A)(i) and (B) are reacted either simultaneously or stepwise with the component (A)(ii), and optionally 0 to 200 parts by weight of a low molecular weight polyol component (A)(iii) having at least one hydroxyl group reactive towards an isocyanate group and a molecular weight of 50 to 500 dalton; 0 to 500 parts by weight of a functionalized low molecular weight polyol component (A)(iv) having at least one hydroxyl group reactive with an isocyanate group and one or more carboxyl, phosphonate, or sulfonate groups inert to an isocyanate group or polyalkylene oxide, or perfluoroalkyl group and having a molecular mass of 50 to 2500 dalton, and 0 to 800 parts by weight of a higher molecular weight polymeric polyol component (A)(v) having at least one hydroxyl groups reactive with an isocyanate group and a molecular mass of from 500 to 5,000 dalton, 0 to 600 parts by weight of a reactive diluent component (C), comprising at least one aqueous epoxy resin having at least one epoxide group substantially inert to an isocyanate group, an epoxide equivalent of 130 to 400 g/eq and a molecular mass of 50 to 1,000 dalton, and 0 to 50 parts by weight of a coalescence auxiliary component (D), or 5 to 900 parts by weight of a formulation component (F)(i), comprising a reactive filler, an inert filler, a pigment, a carrier material, a nanomaterial, a nanocomposite, a plasticizer, a solvent and water to form a prepolymer; a2) optionally emulsifying or dispersing the prepolymer from stage a1) in 0 to 900 parts by weight of water and optionally adding formulation component (F)(i) being added, and b) preparing a latently aminofunctional curing component (II) by combining; 10 to 900 parts by weight of a polymeric polyamine component (E), comprising one or more polymeric polyamines having one or more (cyclo)aliphatic, aromatic primary or secondary amino group reactive with an epoxide group and optionally at least one hydroxyl group and having a molecular mass of 60 to 5000 dalton, in the form of a pure polymeric polyamine, polyaspartic acid ester, a latent curing agent or a reactive diluent based on an aldimine, a ketimine, an enamine, or an oxazolidine, a latent curing agent free of cleavage products and based on an azetidine, a diazepine, or an ammonium salt, a liquid amine curing formulation or a combinations thereof, 10 to 900 parts by weight of a formulation component (F)(ii), comprising a reactive or an inert filler, pigment, a carrier material, a nanomaterial, an other additive, a plasticizer, a solvent and water, and 0.01 to 0.5 part by weight of an accelerator component (K)(ii) for a polyaddition reaction with an epoxy resin are combined. - View Dependent Claims (40, 41, 42, 43, 44, 45, 46, 47, 48, 49, 50, 51, 52, 53, 54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73)
-
Specification