PESTICIDAL COMPOSITIONS

• US 20100292253A1
• Filed: 05/04/2010
• Published: 11/18/2010
• Est. Priority Date: 05/05/2009
• Status: Active Grant

• Current Assignee: Corteva Agriscience LLC (Corteva, Inc.)
• Original Assignee: Dow Agrosciences LLC (Corteva, Inc.)
• Inventors: Zhang, Yu, Parker, Marshall H., Garizi, Negar, Buysse, Ann M., Pernich, Dan, Ross, Ronald JR., Johnson, Timothy C., Bryan, Kristy, Deamicis, Carl, Zhu, Yuanming, Johnson, Peter L., Trullinger, Tony K., Yap, Maurice C. H., Hunter, Ricky, Niyaz, Noormohamed M., Eckelbarger, Joseph D., McLeod, CaSandra L.
• Granted Patent: US 8,350,044 B2
• Time in Patent Office: Days
• US Class Current: 514/256
• CPC Class Codes: A01N 43/40 six-membered rings
• CPC Class Codes: A01N 43/78 1,3-Thiazoles; Hydrogenated 1,3-thiazoles
• CPC Class Codes: C07D 417/04 directly linked by a ring-member-to-ring-member bond
• CPC Class Codes: C07D 417/14 containing three or more hetero rings

Abstract

This document discloses molecules having the following formula (“Formula I”):

Claims

1. A molecule having the following formula (“

Formula I”

);

16. A process comprising reacting molecule VIIIb with molecule IXb to form molecule Xb

17. A process comprising reacting molecule VXb with t-butanol to form molecule XVIIc.

18. A process comprising reacting molecule XIIIg to form molecule VIIIk

19. A process comprising reacting a molecule selected from molecules VIIa-k with molecule XXd to form molecule Iv

20. A process comprising reacting molecule XVIIb (where R4 is H) to form molecule XXV, then reacting molecule XXV with XIXc to form molecule XXVI, then reacting molecule XXVI to form molecule XXVII.

2. A molecule having the following formula (“

Formula I”

);

3. A molecule according to claim 2 wherein

(a) X is CR8;

(b) R1 is H;

(c) R2 is H;

(d) R3 is H;

(e) R4 is C₁ or CH₃;

(f) R5 is H or unsubstituted C₁-C₆ alkyl;

(g) R6 is O;

(h) R7 is (unsubstituted C₁-C₆ alkyl)S(O)_n(unsubstituted C₁-C₆ alkyl), (unsubstituted C₁-C₆ alkyl)S(O)_n(unsubstituted C₁-C₆ alkenyl), O(unsubstituted C₁-C₆ alkyl), (C₁-C₆ alkyl);

(i) R8 is H or F; and

(k) n is 0, 1, or 2.

4. A molecule having the following formula (“

Formula I”

);

5. A molecule according to claim 4 having the following structure:

6. A molecule according to claim 4 having the following structure:

7. A molecule according to claim 4 having the following structure:

8. A molecule according to claim 4 in the form of a pesticidally acceptable acid addition salt, salt derivative, or solvate.

9. A molecule according to claim 4 having at least one ²H.

10. A molecule according to claim 4 having ay least one ¹⁴C.

11. A molecule according to claim 4 that is a resolved stereoisomer.

12. A composition comprising a molecule according to claim 4 and at least one member of the Insecticide Group, Acaricide Group, Nematicide Group, Fungicide Group, or Herbicide Group.

13. A composition comprising a molecule according to claim 4 and at least one biopesticide.

14. A composition comprising a molecule according to claim 4 and at least one of the following compounds:

(a) 3-(4-chloro-2,6-dimethylphenyl)-4-hydroxy-8-oxa-1-azaspiro[4,5]dec-3-en-2-one;

(b) 3-(4′

-chloro-2,4-dimethyl[1,1′

-biphenyl]-3-yl)-4-hydroxy-8-oxa-1-azaspiro[4,5]dec-3-en-2-one;

(c) 4-[[(6-chloro-3-pyridinyl)methyl]methylamino]-1-2(5H)-furanone;

(d) 4-[[(6-chloro-3-pyridinyl)methyl]cyclopropylamino]-2(5H)-furanone;

(e) 3-chloro-N2-1(1S)-1-methyl-2-(methylsulfonyl)ethyl)-N1-[2-methyl-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]phenyl]-1,2-benzenedicarboxamide;

(f) 2-cyano-N-ethyl-4-fluoro-3-methoxy-benenesulfonamide;

(g) 2-cyano-N-ethyl-3-methoxy-benzenesulfonamide;

(h) 2-cyano-3-difluoromethoxy-N-ethyl-4-fluoro-benzenesulfonamide;

(i) 2-cyano-3-fluoromethoxy-N-ethyl-benzenesulfonamide;

(j) 2-cyano-6-fluoro-3-methoxy-N,N-dimethyl-benzenesulfonamide;

(k) 2-cyano-N-ethyl-6-fluoro-3-methoxy-N-methyl-benzenesulfonamide;

(l) 2-cyano-3-difluoromethoxy-N,N-dimethylbenzenesulfon-amide;

(m) 3-(difluoromethyl)-N-[2-(3,3-dimethylbutyl)phenyl]-1-methyl-1H-pyrazole-4-carboxamide;

(n) N-ethyl-2,2-dimethylpropionamide-2-(2,6-dichloro-α

,α

,α

-trifluoro-p-tolyl) hydrazone;

(o) N-ethyl-2,2-dichloro-1-methylcyclopropane-carboxamide-2-(2,6-dichloro-α

,α

,α

-trifluoro-p-tolyl)hydrazone nicotine;

(p) O-{(E-)-[2-(4-chloro-phenyl)-2-cyano-1-(2-trifluoromethylphenyl)-vinyl]}S-methyl thiocarbonate;

(q) (E)-N1-[(2-chloro-1,3-thiazol-5-ylmethyl)]-N2-cyano-N1-methylacetamidine;

(r) 1-(6-chloropyridin-3-ylmethyl)-7-methyl-8-nitro-1,2,3,5,6,7-hexahydro-imidazo[1,2-a]pyridin-5-ol;

(s) 4-[4-chlorophenyl-(2-butylidine-hydrazono)methye]phenyl mesylate;

or

(t) N-Ethyl-2,2-dichloro-1-methylcyclopropanecarboxamide-2-(2,6-dichloro-alpha,alpha,alpha-trifluoro-p-tolyl)hydrazone.

15. A process comprising applying to an area a molecule according to claim 4 in an amount sufficient to control pests.